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X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M2P and M3P (M = Cr−Ni)
Abstract
The electronic structures of metal-rich binary phosphides M 2 P and M 3 P ( M = Cr−Ni) have been examined by means of X-ray photoelectron and absorption spectroscopy and compared with those of the monophosphides M P. The P 2p 3/2 binding and P K-edge absorption energies decrease with greater ionic character of the M −P bonding and indicate the presence of anionic phosphorus, contrary to previous theoretical assertions but consistent with our previous results. Interatomic effects play a more important role in affecting the energy shifts in these metal-rich phosphides than in the monophosphides, becoming more pronounced with higher metal concentration. Although the M 2p 3/2 XPS spectra show no discernible shifts in binding energies, they reveal satellite features whose intensity can be related to metal charge in the Co- and Ni-containing phosphides. In these cases, the metal charge becomes less positive with higher metal concentration. For Ni 2 P and Ni 3 P, this trend was confirmed from an analysis of the Ni L-edge and M-edge XANES spectra.
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Cites
Desulfurization Reactions on Ni2P(001) and α-Mo2C(001) Surfaces: Complex Role of P and C Sites
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Metadata
- Authors
- Blanchard, P. E. R., Grosvenor, A. P., Cavell, R. G., & Mar, A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-28
- Volume
- 20
- Issue
- 22
- Pages
- 7081-7088
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1993847684
- Cited by
- 261
- References
- 1
- FWCI
- 2.04
- Type
- journal article
- Language
- en
- Open access
- closed
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