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Cited by 197

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ZnTe/ZnSe (Core/Shell) Type-II Quantum Dots: Their Optical and Photovoltaic Properties

Bang, Jiwon, Park, Juwon, Lee, Ji Hwang, Won, Nayoun, Nam, Jutaek, Lim, Jongwoo, Chang, Byoung Yong, Lee, Hyo Joong, Chon, Bonghwan, Shin, Junghan, Park, Jae Byung, Choi, Jong Hwa, Cho, Kilwon, Park, Su Moon, Joo, Taiha, Kim, Sungjee·2010·Chemistry of Materials

Abstract

Synthesis of a size series of colloidal ZnTe/ZnSe (core/shell) quantum dots (QDs) is reported. Because of the unique Type-II characters, their emission can range over an extended wavelength regime, showing photoluminescence (PL) from blue to amber. The PL lifetime measures as long as 77 ns, which clearly indicates the Type-II characteristics. ZnTe/ZnSe (Core/Shell) QDs can be further passivated by ZnS layers, rendered in water, while preserving the optical and chemical stabilities and thus proved their potentials toward “nontoxic” biological or medical applications that are free from concerns regarding heavy-metal leakage. ZnTe/ZnSe Type-II QD/polymer hybrid organic solar cells are also showcased, promising environmentally friendly photovoltaic devices. ZnTe/ZnSe Type-II QD incorporated photovoltaic devices show 11 times higher power conversion efficiency, when compared to that of the control ZnSe QD devices. This results from the Type-II characteristic broad QD absorption up to extended wavelengths and the spatially separated Type-II excitons, which can enhance the carrier extractions. We believe that ZnTe/ZnSe-based Type-II band engineering can open many new possibilities as exploiting the safe material choice.

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Crossref · 10.1021/cm9027995

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Metadata

Authors
Bang, J., Park, J., Lee, J. H., Won, N., Nam, J., Lim, J., Chang, B. Y., Lee, H. J., Chon, B., Shin, J., Park, J. B., Choi, J. H., Cho, K., Park, S. M., Joo, T., & Kim, S.
Venue
Chemistry of Materials
Published
2009-11-23
Volume
22
Issue
1
Pages
233-240
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2078667240
Cited by
197
References
2
FWCI
5.10
Type
journal article
Language
en
Open access
closed

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