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Catalytic Chain Transfer in Free-Radical Polymerizations

Gridnev, Alexei A., Ittel, Steven D.·2001·Chemical Reviews

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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic Chain Transfer in Free-Radical PolymerizationsAlexei A. Gridnev and Steven D. IttelView Author Information DuPont Performance Coatings, 2401 Grays Ferry Avenue, Philadelphia, Pennsylvania 19146 DuPont Central Research and Development, Experimental Station, Wilmington, Delaware 19880-0328 Cite this: Chem. Rev. 2001, 101, 12, 3611–3660Publication Date (Web):November 15, 2001Publication History Received12 February 2001Published online15 November 2001Published inissue 1 December 2001https://pubs.acs.org/doi/10.1021/cr9901236https://doi.org/10.1021/cr9901236research-articleACS PublicationsCopyright © 2001 American Chemical SocietyRequest reuse permissionsArticle Views6756Altmetric-Citations344LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Catalysts,Cobalt,Monomers,Organic compounds,Polymerization Get e-Alerts

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Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
Principles of Polymerization
Odian, G. (2004) · doi:10.1002/047147875x · Cited by 7,158
Harmonic Vibrational Frequencies: An Evaluation of Hartree−Fock, Møller−Plesset, Quadratic Configuration Interaction, Density Functional Theory, and Semiempirical Scale Factors
Scott, A. P., & Radom, L. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp960976r · Cited by 6,729
Introduction to Computational Chemistry
Jensen, F. (1998) · Cited by 4,669
Metal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,275
Convergent Dendrons and Dendrimers: from Synthesis to Applications
Grayson, S. M., & Fréchet, J. M. J. (2001) · Chemical Reviews · doi:10.1021/cr990116h · Cited by 1,619
The manipulation of air-sensitive compounds
Smith, J. D. (1987) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(87)80317-0 · Cited by 1,422
The Persistent Radical Effect: A Principle for Selective Radical Reactions and Living Radical Polymerizations
Fischer, H. (2001) · Chemical Reviews · doi:10.1021/cr990124y · Cited by 1,344
KIRK-OTHMER ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY
(1979) · Chemical & Engineering News Archive · doi:10.1021/cen-v057n008.p001 · Cited by 1,080
Controlled Synthesis of Hyperbranched Polyglycerols by Ring-Opening Multibranching Polymerization
Sunder, A., Hanselmann, R., Frey, H., & Mülhaupt, R. (1999) · Macromolecules · doi:10.1021/ma990090w · Cited by 1,049
Investigation of the synthesis of ortho-substituted tetraphenylporphyrins
Lindsey, J. S., & Wagner, R. W. (1989) · The Journal of Organic Chemistry · doi:10.1021/jo00265a021 · Cited by 707
The chemistry of free radical polymerization
Moad, G., & Solomon, D. H. (1995) · Medical Entomology and Zoology · Cited by 643
Living Radical Polymerization of Acrylates by Organocobalt Porphyrin Complexes
Wayland, B. B., Poszmik, G., Mukerjee, S. L., & Fryd, M. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00096a080 · Cited by 528
Chain Transfer in the Polymerization of Styrene: The Reaction of Solvents with Free Radicals1
Mayo, F. R. (1943) · Journal of the American Chemical Society · doi:10.1021/ja01252a021 · Cited by 463
A model for living radical polymerization
Otsu, T., Yoshida, M., & Tazaki, T. (1982) · Die Makromolekulare Chemie, Rapid Communications · doi:10.1002/marc.1982.030030209 · Cited by 452
Controlled Radical Polymerization
(1998) · ACS Symposium Series · doi:10.1021/bk-1998-0685 · Cited by 412
Inorganic chemistry of vitamin B12.
Pratt, J. M. (1972) · Medical Entomology and Zoology · Cited by 395
Organocobalt B12 models: axial ligand effects on the structural and coordination chemistry of cobaloximes
Bresciani-Pahor, N., Forcolin, M., Marzilli, L. G., Randaccio, L., Summers, M. F., & Toscano, P. J. (1985) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(85)80021-7 · Cited by 357
The Persistent Radical Effect In “Living” Radical Polymerization
Fischer, H. (1997) · Macromolecules · doi:10.1021/ma970535l · Cited by 334
Reactions of cobalt(I) supernucleophiles. The alkylation of vitamin B12s, cobaloximes(I), and related compounds
Schrauzer, G. N., & Deutsch, E. (1969) · Journal of the American Chemical Society · doi:10.1021/ja01040a041 · Cited by 310
Narrow Polydispersity Block Copolymers by Free-Radical Polymerization in the Presence of Macromonomers
Krstina, J., Moad, G., Rizzardo, E., Winzor, C. L., Berge, C. T., & Fryd, M. (1995) · Macromolecules · doi:10.1021/ma00119a034 · Cited by 211
Nature of the bound oxygen in a series of cobalt dioxygen adducts
Tovrog, B. S., Kitko, D. J., & Drago, R. S. (1976) · Journal of the American Chemical Society · doi:10.1021/ja00433a016 · Cited by 197
A Decrease in Effective Acrylate Propagation Rate Constants Caused by Intramolecular Chain Transfer
Plessis, C., Arzamendi, G., Leiza, J. R., Schoonbrood, H. A. S., Charmot, D., & Asua, J. M. (2000) · Macromolecules · doi:10.1021/ma991205z · Cited by 185
Chain Transfer to Polymer: A Convenient Route to Macromonomers
Chiefari, J., Jeffery, J., Mayadunne, R. T. A., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma990488s · Cited by 178
The organic compounds of cobalt(III)
Dodd, D., & Johnson, M. D. (1973) · Journal of Organometallic Chemistry · doi:10.1016/s0022-328x(00)88806-3 · Cited by 174
Seeded Semibatch Emulsion Polymerization of n-Butyl Acrylate. Kinetics and Structural Properties
Plessis, C., Arzamendi, G., Leiza, J. R., Schoonbrood, H. A. S., Charmot, D., & Asua, J. M. (2000) · Macromolecules · doi:10.1021/ma992053a · Cited by 171
Ceiling temperature of α‐methylstyrene
McCormick, H. W. (1957) · Journal of Polymer Science · doi:10.1002/pol.1957.1202511112 · Cited by 166
Controlled Polymerization of Acrylates and Methacrylates1
Davis, T. P., Haddleton, D. M., & Richards, S. N. (1994) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15321799408009636 · Cited by 164
Chain Transfer Activity of ω-Unsaturated Methyl Methacrylate Oligomers
Moad, C. L., Moad, G., Rizzardo, E., & Thang, S. H. (1996) · Macromolecules · doi:10.1021/ma960852c · Cited by 149
Living Radical Polymerization of Acrylates Initiated and Controlled by Organocobalt Porphyrin Complexes
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Haddleton, D. M., Crossman, M. C., Hunt, K. H., Topping, C., Waterson, C., & Suddaby, K. G. (1997) · Macromolecules · doi:10.1021/ma970303m · Cited by 127
Handbook of Radical Vinyl Polymerization
Mishra, M., & Yağcı, Y. (1998) · Medical Entomology and Zoology · Cited by 122
Mechanism of hydrogen evolution from hydridocobaloxime
CHAO, T. ‐., & Espenson, J. H. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a022 · Cited by 119
Comprehensive chemical kinetics
Grassië, N. (1976) · Polymer · doi:10.1016/0032-3861(76)90116-6 · Cited by 117
Hydridocobaloximes
Schrauzer, G. N., & Holland, R. J. (1971) · Journal of the American Chemical Society · doi:10.1021/ja00735a040 · Cited by 107
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Meijs, G. F., Morton, T. C., Rizzardo, E., & Thang, S. H. (1991) · Macromolecules · doi:10.1021/ma00012a033 · Cited by 106
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Self-citation
Radical reaction kinetics during homolysis of N-alkoxyamines: verification of the persistent radical effect
Kothe, T., Marque, S. R. A., Martschke, R., et al. (1998) · Journal of the Chemical Society Perkin Transactions 2 · doi:10.1039/a802773k · Cited by 97
Polymerisationsauslösung mit substituierten ethanen, 6. Polymerisation von methylmethacrylat mit verschiedenen tetraphenylethanen
Błedzki, A., Braun, D., & Titzschkau, K. (1983) · Die Makromolekulare Chemie · doi:10.1002/macp.1983.021840409 · Cited by 93
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Oguni, N., Omi, T., Yamamoto, Y., & Nakamura, A. (1983) · Chemistry Letters · doi:10.1246/cl.1983.841 · Cited by 90
Cage effects in organotransition metal chemistry: Their importance in the kinetic estimation of bond dissociation energies in solution
Koenig, T. W., Hay, B. P., & Finke, R. G. (1988) · Polyhedron · doi:10.1016/s0277-5387(00)81778-7 · Cited by 88
The B12-dependent isomerase enzymes; how the protein controls the active site
Pratt, J. M. (1985) · Chemical Society Reviews · doi:10.1039/cs9851400161 · Cited by 82
Use of Chain Length Distributions in Determining Chain Transfer Constants and Termination Mechanisms
Moad, G., & Moad, C. L. (1996) · Macromolecules · doi:10.1021/ma960851k · Cited by 78
Neuere Entwicklungen auf dem Gebiet des Vitamins B12: Reaktionen des Cobaltatoms in Corrin‐Derivaten und Vitamin‐B12‐Modellverbindungen
Schrauzer, G. N. (1976) · Angewandte Chemie · doi:10.1002/ange.19760881403 · Cited by 72
Addition-fragmentation processes in free radical polymerization
Colombani, D., & Chaumont, P. R. (1996) · Progress in Polymer Science · doi:10.1016/0079-6700(95)00024-0 · Cited by 71
Free radical polymerisation. The synthesis of graft copolymers
Corner, T. (1984) · Advances in polymer science · doi:10.1007/bfb0024036 · Cited by 70
Absolute rate constants for radical-monomer reactions
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Christianson, D. W., & Lipscomb, W. N. (1985) · Journal of the American Chemical Society · doi:10.1021/ja00295a021 · Cited by 50
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Matsumoto, A., & Nakamura, S. (1999) · Journal of Applied Polymer Science · Cited by 46
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Marques, H. M., & Brown, K. L. (1995) · Journal of Molecular Structure THEOCHEM · doi:10.1016/0166-1280(95)04142-s · Cited by 44
Carbon-carbon bond formation in the reaction of aliphatic radicals with alkylcobaloximes
McHatton, R. C., Espenson, J. H., & Bakač, A. (1986) · Journal of the American Chemical Society · doi:10.1021/ja00279a037 · Cited by 37
α,ω-dicarboxyl telechelic poly(methyl methacrylate) via radical addition-fragmentation polymerization
Haddleton, D. M., Topping, C., Kukulj, D., & Irvine, D. J. (1998) · Polymer · doi:10.1016/s0032-3861(97)10116-1 · Cited by 36
Kobalt(I)‐phthalocyanin‐Salze, in neutralem Medium stabile „supernucleophile” Vitamin‐B12‐Modellsubstanzen
Eckert, H., & Ugi, I. (1975) · Angewandte Chemie · doi:10.1002/ange.19750872314 · Cited by 34
Regioselective hydroxylations of 1,3-dienes via hydrocobaltation reactions. Facile conversion of myrcene to geraniol and to (±)-linalool
Howell, A. R., & Pattenden, G. (1990) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39900000103 · Cited by 29
The structure of cobalt corrinoids based on molecular mechanics and NOE-restrained molecular mechanics and dynamics simulations
Marques, H. M., & Brown, K. L. (1999) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(99)00074-0 · Cited by 22
Transalkylation of Phosphotriesters Using Cob(I)alamin: Toward Specific Determination of DNA−Phosphate Adducts
Haglund, J., Rafiq, A., Ehrenberg, L. G., et al. (2000) · Chemical Research in Toxicology · doi:10.1021/tx990135m · Cited by 21
Reactions of ferrocene and acetylferrocene with carbon-centered free radicals
Baciocchi, E., Floris, B., & Muraglia, E. (1993) · The Journal of Organic Chemistry · doi:10.1021/jo00060a011 · Cited by 21
Methylcobalamin and methylcobalt complexes of vitamin B12 model compounds as substrates in nucleophilic displacement reactions
Stadlbauer, E. A., Holland, R. J., Lamm, F. P., et al. (1974) · Bioinorganic Chemistry · doi:10.1016/s0006-3061(00)80175-1 · Cited by 18
THE CHEMISTRY OF Co(I) DERIVATIVES OF VITAMIN B12 AND OF RELATED CHELATES
Schrauzer, G. N. (1969) · Annals of the New York Academy of Sciences · doi:10.1111/j.1749-6632.1969.tb56206.x · Cited by 18
A DUALITY OF MECHANISM IN THE HOMOLYTIC SUBSTITUTION REACTION OF ANTHRONE WITH 1-CYANO-1-METHYLETHYL RADICALS
Mitsuhashi, T., & Ōki, M. (1978) · Chemistry Letters · doi:10.1246/cl.1978.1089 · Cited by 7
Alternierende copolymerisation mit lewissäuren. Copolymerisation von p‐chlorstyrol und n‐butylmethacrylat mit ethylaluminiumsesquichlorid
Braun, D., & Manger, E. (1986) · Die Angewandte Makromolekulare Chemie · doi:10.1002/apmc.1986.051450106 · Cited by 2

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Authors: Gridnev, A. A., & Ittel, S. D.
Venue: Chemical Reviews
Publisher: American Chemical Society (ACS)
Published: 2001-11-15
Volume: 101
Issue: 12
Pages: 3611-3660
ISSN: 0009-2665 (ISSN-L)
1520-6890
DOI: 10.1021/cr9901236
OpenAlex: W2070330352
Cited by: 393
References: 64
FWCI: 0.92
Type: journal article
Language: en
Open access: closed

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Catalytic Chain Transfer in Free-Radical Polymerizations

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