The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Metal–Organic Frameworks for Light Harvesting and Photocatalysis
Abstract
Metal–organic frameworks (MOFs), a new class of crystalline molecular solids built from linking organic ligands with metal or metal-cluster connecting points, have recently emerged as a versatile platform for developing single-site solid catalysts. MOFs have been used to drive a range of reactions, including Lewis acid/base catalyzed reactions, redox reactions, asymmetric reactions, and photocatalysis. MOF catalysts are easily separated from the reaction mixtures for reuse, and yet their molecular nature introduces unprecedented chemical diversity and tunability to drive a large scope of catalytic reactions. This Perspective aims to summarize recent progress on light harvesting and photocatalysis with MOFs. The charge-separated excited states of the chromophoric building blocks created upon photon excitation can migrate over long distances to be harvested as redox equivalents at the MOF/liquid interfaces via electron transfer reactions or can directly activate the substrates that have diffused into the MOF channels for photocatalytic reactions. MOF-catalyzed and photodriven proton reduction, CO 2 reduction, and organic transformations will be discussed in this Perspective.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
Coherently wired light-harvesting in photosynthetic marine algae at ambient temperature
Collini, E., Wong, C. Y., Wilk, K. E., Curmi, P. M. G., Brumer, P., & Scholes, G. D. (2010) · Nature · doi:10.1038/nature08811 · Cited by 1,649
Cited by
Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review
Wang, C.-C., Du, X.-D., Li, J., Guo, X.-X., Wang, P., & Zhang, J. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.030 · Cited by 659
Self-citationShi, L., Wang, T., Zhang, H., Chang, K., & Ye, J. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201502253 · Cited by 517
Modified metal-organic frameworks as photocatalysts
Qiu, J., Zhang, X., Feng, Y., Zhang, X., Wang, H., & Yao, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.03.039 · Cited by 499
Hod, I., Deria, P., Bury, W., Mondloch, J. E., Kung, C.-W., So, M., Sampson, M. D., Peters, A. W., Kubiak, C. P., Farha, O. K., et al. (2015) · Nature Communications · doi:10.1038/ncomms9304 · Cited by 290
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Wang, J.-L., Wang, C., & Lin, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-05
- Volume
- 2
- Issue
- 12
- Pages
- 2630-2640
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W1976269136
- Cited by
- 802
- References
- 3
- FWCI
- 28.14
- Type
- journal article
- Language
- en
- Open access
- closed
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