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Metal–Organic Frameworks for Light Harvesting and Photocatalysis
Abstract
Metal–organic frameworks (MOFs), a new class of crystalline molecular solids built from linking organic ligands with metal or metal-cluster connecting points, have recently emerged as a versatile platform for developing single-site solid catalysts. MOFs have been used to drive a range of reactions, including Lewis acid/base catalyzed reactions, redox reactions, asymmetric reactions, and photocatalysis. MOF catalysts are easily separated from the reaction mixtures for reuse, and yet their molecular nature introduces unprecedented chemical diversity and tunability to drive a large scope of catalytic reactions. This Perspective aims to summarize recent progress on light harvesting and photocatalysis with MOFs. The charge-separated excited states of the chromophoric building blocks created upon photon excitation can migrate over long distances to be harvested as redox equivalents at the MOF/liquid interfaces via electron transfer reactions or can directly activate the substrates that have diffused into the MOF channels for photocatalytic reactions. MOF-catalyzed and photodriven proton reduction, CO 2 reduction, and organic transformations will be discussed in this Perspective.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Heterogeneous photocatalyst materials for water splitting
Kudo, A., & Miseki, Y. (2009) · Chem. Soc. Rev. · doi:10.1039/b800489g · Cited by 10,585
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida, K., Rogow, D. L., Mason, J. A., McDonald, T. M., Bloch, E. D., Herm, Z. R., Bae, T.-H., & Long, J. R. (2012) · Chemical Reviews · doi:10.1021/cr2003272 · Cited by 6,408
Luminescent Functional Metal–Organic Frameworks
Cui, Y., Yue, Y., Qian, G., & Chen, B. (2012) · Chemical Reviews · doi:10.1021/cr200101d · Cited by 5,697
Visible light photoredox catalysis: applications in organic synthesis
Narayanam, J. M. R., & Stephenson, C. R. J. (2011) · Chem. Soc. Rev. · doi:10.1039/b913880n · Cited by 4,161
Enantioselective catalysis with homochiral metal–organic frameworks
Ma, L., Abney, C., & Lin, W. (2009) · Chemical Society Reviews · doi:10.1039/b807083k · Cited by 3,109
Self-citationHomochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
Yoon, M., Srirambalaji, R., & Kim, K. (2012) · Chemical Reviews · doi:10.1021/cr2003147 · Cited by 2,856
Photocatalyst releasing hydrogen from water
Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006) · Nature · doi:10.1038/440295a · Cited by 2,812
Cited by
Tu, W., Zhou, Y., & Zou, Z. (2014) · Advanced Materials · doi:10.1002/adma.201400087 · Cited by 1,635
Metal Organic Framework Catalysis: Quo vadis?
Gascon, J., Corma, A., Kapteijn, F., & Llabrés i Xamena, F. X. (2014) · ACS Catalysis · doi:10.1021/cs400959k · Cited by 960
Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks
Howarth, A. J., Peters, A. W., Vermeulen, N. A., Wang, T. C., Hupp, J. T., & Farha, O. K. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02626 · Cited by 746
Functional materials derived from open framework templates/precursors: synthesis and applications
Sun, J.-K., & Xu, Q. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00517a · Cited by 687
Sun, D., Fu, Y., Liu, W., Ye, L., Wang, D., Yang, L., Fu, X., & Li, Z. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201301728 · Cited by 667
Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review
Wang, C.-C., Du, X.-D., Li, J., Guo, X.-X., Wang, P., & Zhang, J. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.030 · Cited by 659
Self-citationPlasmon-Enhanced Photocatalytic CO2 Conversion within Metal–Organic Frameworks under Visible Light
Choi, K. M., Kim, D., Rungtaweevoranit, B., Trickett, C. A., Barmanbek, J. T. D., Alshammari, A. S., Yang, P., & Yaghi, O. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11027 · Cited by 632
Metal–Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting
Navalón, S., Dhakshinamoorthy, A., Álvaro, M., Ferrer, B., & García, H. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00460 · Cited by 538
Shi, L., Wang, T., Zhang, H., Chang, K., & Ye, J. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201502253 · Cited by 517
Modified metal-organic frameworks as photocatalysts
Qiu, J., Zhang, X., Feng, Y., Zhang, X., Wang, H., & Yao, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.03.039 · Cited by 499
Nanoscale metal–organic frameworks for phototherapy of cancer
Lan, G., Ni, K., & Lin, W. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.09.007 · Cited by 420
Self-citationLuo, H., Zeng, Y., He, D., & Pan, X. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.127191 · Cited by 409
MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts
García-García, P., Müller, M., & Corma, A. (2014) · Chemical Science · doi:10.1039/c4sc00265b · Cited by 355
Katz, M. J., Moon, S.-Y., Mondloch, J. E., Beyzavi, M. H., Stephenson, C. J., Hupp, J. T., & Farha, O. K. (2015) · Chemical Science · doi:10.1039/c4sc03613a · Cited by 334
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
Dhakshinamoorthy, A., Opanasenko, M., Čejka, J., & Garcia, H. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00350g · Cited by 296
Hod, I., Deria, P., Bury, W., Mondloch, J. E., Kung, C.-W., So, M., Sampson, M. D., Peters, A. W., Kubiak, C. P., Farha, O. K., et al. (2015) · Nature Communications · doi:10.1038/ncomms9304 · Cited by 290
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Application of aluminosilicate clay mineral-based composites in photocatalysis
Zou, Y., Hu, Y., Shen, Z., Yao, L., Tang, D., Zhang, S., Wang, S., Hu, B., Zhao, G., & Wang, X. (2022) · Journal of Environmental Sciences · doi:10.1016/j.jes.2021.07.015 · Cited by 117
Metadata
- Authors
- Wang, J.-L., Wang, C., & Lin, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-11-05
- Volume
- 2
- Issue
- 12
- Pages
- 2630-2640
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W1976269136
- Cited by
- 802
- References
- 76
- FWCI
- 28.14
- Type
- journal article
- Language
- en
- Open access
- closed
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