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Tandem Catalysis by Palladium Nanoclusters Encapsulated in Metal–Organic Frameworks
Open accessAbstract
A bifunctional Zr-MOF catalyst containing palladium nanoclusters (NCs) has been developed. The formation of Pd NCs was confirmed by transmission electron microscopy (TEM) and extended X-ray absorption fine structure (EXAFS). Combining the oxidation activity of Pd NCs and the acetalization activity of the Lewis acid sites in UiO-66-NH 2, this catalyst (Pd@UiO-66-NH 2 ) exhibits excellent catalytic activity and selectivity in a one-pot tandem oxidation-acetalization reaction. This catalyst shows 99.9% selectivity to benzaldehyde ethylene acetal in the tandem reaction of benzyl alcohol and ethylene glycol at 99.9% conversion of benzyl alcohol. We also examined various substituted benzyl alcohols and found that alcohols with electron-donating groups showed better conversion and selectivity compared to those with electron-withdrawing groups. We further proved that there was no leaching of active catalytic species during the reaction and the catalyst can be recycled at least five times without significant deactivation.
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Cited by
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions
Huang, Y.-B., Liang, J., Wang, X.-S., & Cao, R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00250a · Cited by 1,908
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Covalent Chemistry beyond Molecules
Jiang, J., Zhao, Y., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10666 · Cited by 448
Chen, Y.-Z., Zhou, Y.-X., Wang, H., Lu, J., Uchida, T., Xu, Q., Yu, S.-H., & Jiang, H.-L. (2015) · ACS Catalysis · doi:10.1021/cs501953d · Cited by 423
Engineering UiO‐66 Metal Organic Framework for Heterogeneous Catalysis
Dhakshinamoorthy, A., Santiago‐Portillo, A., Asiri, A. M., & Garcia, H. (2019) · ChemCatChem · doi:10.1002/cctc.201801452 · Cited by 298
Lu, J., Zhou, W., Wang, L., Jia, J., Ke, Y., Yang, L., Zhou, K., Liu, X., Tang, Z., Li, L., et al. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02302 · Cited by 159
Opportunities and Challenges of Metal–Organic Framework Micro/Nano Reactors for Cascade Reactions
Wu, P., Zhao, Y., Zhang, X., Fan, Y., Zhang, S., Zhang, W., & Huo, F. (2023) · JACS Au · doi:10.1021/jacsau.3c00344 · Cited by 48
Metadata
- Authors
- Li, X., Guo, Z., Xiao, C., Goh, T. W., Tesfagaber, D., & Huang, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-05
- Volume
- 4
- Issue
- 10
- Pages
- 3490-3497
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2087908412
- Cited by
- 209
- References
- 0
- FWCI
- 10.16
- Type
- journal article
- Language
- en
- Open access
- green
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