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Effects of Crystallinity on Dilute Acid Hydrolysis of Cellulose by Cellulose Ball-Milling Study
Abstract
The dilute acid (0.05 M H 2 SO 4 ) hydrolysis at 175 °C of samples comprised of varying fractions of crystalline (α-form) and amorphous cellulose was studied. The amorphous content, based on XRD and CP/MAS NMR, and the product (glucose) yield, based on HPLC, increased by as much as a factor of 3 upon ball milling. These results are interpreted in terms of a model involving mechanical disruption of crystallinity by breaking hydrogen bonds in α-cellulose, opening up the structure, and making more β-1,4 glycosidic bonds readily accessible to the dilute acid. However, in parallel with hydrolysis to form liquid-phase products, there are reactions of amorphous cellulose that form solid degradation products.
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Cited by
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Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., & Beltramini, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15124j · Cited by 1,420
Payne, C. M., Knott, B. C., Mayes, H. B., Hansson, H., Himmel, M. E., Sandgren, M., Ståhlberg, J., & Beckham, G. T. (2015) · Chemical Reviews · doi:10.1021/cr500351c · Cited by 855
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Selective extraction of hemicelluloses from spruce using switchable ionic liquids
Anugwom, I., Mäki-Arvela, P., Virtanen, P., Willför, S., Sjöholm, R., & Mikkola, J.-P. (2012) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2011.10.006 · Cited by 84
Metadata
- Authors
- Zhao, H., Kwak, J. H., Wang, Y., Franz, J. A., White, J. M., & Holladay, J. E.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-12-23
- Volume
- 20
- Issue
- 2
- Pages
- 807-811
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2064095336
- Cited by
- 309
- References
- 0
- FWCI
- 3.13
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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