The DOI matches its Crossref record.
Production of Hydrogen from Biomass by Catalytic Steam Reforming of Fast Pyrolysis Oils
Abstract
Hydrogen is of great interest as the cleanest fuel for power generation using fuel cells and for transportation. Biomass can be thermochemically converted to hydrogen via two distinct strategies: (1) gasification followed by shift conversion, and (2) fast pyrolysis of biomass followed by catalytic steam reforming and shift conversion of specific fractions. This paper presents the latter route. The process begins with fast pyrolysis of biomass to produce bio-oil, which (as a whole or its selected fractions) can be converted to hydrogen via catalytic steam reforming followed by a shift conversion step. Such a process has been demonstrated at the bench scale using model compounds and the aqueous fraction of poplar oil with commercial nickel-based steam-reforming catalysts. Hydrogen yields as high as 85% of the stoichiometric value have been obtained. Initial catalyst activity can be maintained through periodic regeneration via steam or carbon dioxide (CO 2 ) gasification of the carbonaceous deposits.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
A review of catalytic upgrading of bio-oil to engine fuels
Mortensen, P. M., Grunwaldt, J.-D., Jensen, P. A., Knudsen, K. G., & Jensen, A. D. (2011) · Applied Catalysis A: General · doi:10.1016/j.apcata.2011.08.046 · Cited by 1,768
A comprehensive review on the pyrolysis of lignocellulosic biomass
Dhyani, V., & Bhaskar, T. (2018) · Renewable Energy · doi:10.1016/j.renene.2017.04.035 · Cited by 1,545
Bio-oil production and upgrading research: A review
Xiu, S., & Shahbazi, A. (2012) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2012.04.028 · Cited by 1,127
Catalytic fast pyrolysis of lignocellulosic biomass
Liu, C., Wang, H., Karim, A. M., Sun, J., & Wang, Y. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60414d · Cited by 1,117
Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems
Balat, M., Balat, M., Kırtay, E., & Balat, H. (2009) · Energy Conversion and Management · doi:10.1016/j.enconman.2009.08.014 · Cited by 738
(2008) · doi:10.1007/978-1-84628-995-8 · Cited by 707
Biomass Gasification in Supercritical Water
Antal, M. J., Allen, S. G., Schulman, D., Xu, X., & Divilio, R. J. (2000) · Industrial & Engineering Chemistry Research · doi:10.1021/ie0003436 · Cited by 610
Biorefineries: Current activities and future developments
Demirbas, A. (2009) · Energy Conversion and Management · doi:10.1016/j.enconman.2009.06.035 · Cited by 512
Hydrogen by Catalytic Steam Reforming of Liquid Byproducts from Biomass Thermoconversion Processes
Czernik, S., French, R., Feik, C., & Chornet, E. (2002) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020107q · Cited by 458
Self-citationCatalytic steam reforming of bio-oil
Trane, R., Dahl, S., Skjøth-Rasmussen, M. S., & Jensen, A. D. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.01.023 · Cited by 401
Hydrogen from biomass-production by steam reforming of biomass pyrolysis oil☆
CZERNIK, S., EVANS, R., & FRENCH, R. (2007) · Catalysis Today · doi:10.1016/j.cattod.2006.08.071 · Cited by 295
Self-citationBiomass pyrolysis technologies for value-added products: a state-of-the-art review
Amenaghawon, A. N., Anyalewechi, C. L., Okieimen, C. O., & Kusuma, H. S. (2021) · Environment, Development and Sustainability · doi:10.1007/s10668-021-01276-5 · Cited by 260
Co-liquefaction of Micro Algae with Coal Using Coal Liquefaction Catalysts
Ikenaga, N.-O., Ueda, C., Matsui, T., Ohtsuki, M., & Suzuki, T. (2001) · Energy & Fuels · doi:10.1021/ef000129u · Cited by 49
Metadata
- Authors
- Wang, D., Czernik, S., & Chornet, E.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-01-01
- Volume
- 12
- Issue
- 1
- Pages
- 19-24
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W2094385607
- Cited by
- 303
- References
- 0
- FWCI
- 5.43
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
