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Adsorption Characteristics of Phenolic Compounds onto Coal-Reject-Derived Adsorbents
Abstract
Carbonaceous adsorbents were prepared by heat treatment of coal reject at 600 °C, after chemical treatment in HNO 3, H 2 SO 4, and NaOH at 25 and 75 °C. Pore structure characterization and the phenol adsorption capacities of the adsorbents showed that nitric acid pretreatment significantly enhanced the surface properties, consequently the adsorption capacities of the adsorbents. A number of samples were subsequently prepared by carbonizing coal reject at 600 °C, after pretreatment in HNO 3 under various conditions. The acid concentration, residence time, and reaction temperature were varied to obtain adsorbents with various pore structures. The adsorption capacities of the derived adsorbents for phenol, p -nitrophenol, and benzene were measured to gain further insights into the pore structure evolution. Adsorption isotherms of phenol, p -nitrophenol, and p -chlorophenol on the best adsorbent prepared were determined and correlated with theoretical isotherm equations, such as the Langmuir, Freundlich, and Redlich−Peterson equations.
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Metadata
- Authors
- Haghseresht, F., & Lu, G. Q.
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-09-12
- Volume
- 12
- Issue
- 6
- Pages
- 1100-1107
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W1969734784
- Cited by
- 610
- References
- 0
- FWCI
- 1.69
- Type
- journal article
- Language
- en
- Open access
- closed
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