Atmospheric chemistry of aldehydes: Enhanced peroxyacetyl nitrate formation from ethanol-fueled vehicular emissions
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAtmospheric chemistry of aldehydes: enhanced peroxyacetyl nitrate formation from ethanol-fueled vehicular emissionsRoger L. Tanner, Antonio H. Miguel, Jailson B. De Andrade, Jeffrey S. Gaffney, and Gerald E. StreitCite this: Environ. Sci. Technol. 1988, 22, 9, 1026–1034Publication Date (Print):September 1, 1988Publication History Published online1 May 2002Published inissue 1 September 1988https://pubs.acs.org/doi/10.1021/es00174a005https://doi.org/10.1021/es00174a005research-articleACS PublicationsRequest reuse permissionsArticle Views623Altmetric-Citations102LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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Reaction with OH involves H-abstraction from the carbonyl carbon to form a peroxyacetyl radical which can react with NO2 to produce PAN.
“Reaction with OH involves H-abstraction from the carbonyl carbon to form a peroxyacetyl radical which can go on to react with NO 2 and produce PAN [98,99].”
From Investigation of Biofuel as a Potential Renewable Energy Source (2021) · cites this paper as [98]
Once formed, acetaldehyde is rapidly removed from the atmosphere by reaction with OH and photolysis that enhances HOx levels.
“Once formed, acetaldehyde is rapidly removed from the atmosphere by reaction with OH and importantly photolysis that enhances HO x levels.”
From Investigation of Biofuel as a Potential Renewable Energy Source (2021) · cites this paper as [98]
Cites
Brookhaven National Lab., U., Leahy, D. F., USDOE, W., et al. (1995) · doi:10.2172/114550 · Cited by 44 · see citing works
An Overview of the Rio de Janeiro Aerosol Characterization Study
Daisey, J. M., Miguel, A. H., de Andrade, J. B., et al. (1987) · JAPCA · doi:10.1080/08940630.1987.10466194 · Cited by 31 · see citing works
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The atmospheric chemistry of organic nitrates
Roberts, J. M. (1990) · Atmospheric Environment. Part A. General Topics · doi:10.1016/0960-1686(90)90108-y · Cited by 470 · see citing works
The impacts of combustion emissions on air quality and climate – From coal to biofuels and beyond
Gaffney, J. S., & Marley, N. A. (2009) · Atmospheric Environment · doi:10.1016/j.atmosenv.2008.09.016 · Cited by 377 · see citing works
Self-citationInvestigation of Biofuel as a Potential Renewable Energy Source
Khan, M. A. H., Bonifacio, S., Clowes, J., Foulds, A., Holland, R., Matthews, J. C., Percival, C. J., & Shallcross, D. E. (2021) · Atmosphere · doi:10.3390/atmos12101289 · Cited by 140 · see citing works
Gaffney, J. S., Marley, N. A., Martin, R. S., Dixon, R. W., Reyes, L. G., & Popp, C. J. (1997) · Environmental Science & Technology · doi:10.1021/es9610388 · Cited by 97 · see citing works
Self-citationGaffney, J. S., & Marley, N. A. (2021) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.1c00143 · Cited by 29 · see citing works
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- Authors
- Tanner, R. L., Miguel, A. H., De Andrade, J. B., Gaffney, J. S., & Streit, G. E.
- ORCID
- Gaffney, Jeffrey S.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1988-09
- Volume
- 22
- Issue
- 9
- Pages
- 1026-1034
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2036724173
- Cited by
- 129
- References
- 2
- Citations by year
- 2024: 1 · 2023: 3 · 2022: 2 · 2021: 2 · 2020: 2 · 2019: 5 · 2018: 1 · 2017: 4 · 2016: 2 · 2015: 1 · 2013: 5 · 2012: 8
- FWCI
- 5.72
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Advanced Combustion Engine Technologies
- Physical Sciences › Engineering › Automotive Engineering › Vehicle emissions and performance
- Keywords
- aldehydes, peroxyacetyl nitrate, bioethanol, vehicle emissions, atmospheric chemistry, secondary organic aerosol, NOx formation
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