Investigation of Biofuel as a Potential Renewable Energy Source
Open accessAbstract
An accelerating global energy demand, paired with the harmful environmental effects of fossil fuels, has triggered the search for alternative, renewable energy sources. Biofuels are arguably a potential renewable energy source in the transportation industry as they can be used within current infrastructures and require less technological advances than other renewable alternatives, such as electric vehicles and nuclear power. The literature suggests biofuels can negatively impact food security and production; however, this is dependent on the type of feedstock used in biofuel production. Advanced biofuels, derived from inedible biomass, are heavily favoured but require further research and development to reach their full commercial potential. Replacing fossil fuels by biofuels can substantially reduce particulate matter (PM), carbon monoxide (CO) emissions, but simultaneously increase emissions of nitrogen oxides (NOx), acetaldehyde (CH3CHO) and peroxyacetyl nitrate (PAN), resulting in debates concerning the way biofuels should be implemented. The potential biofuel blends (FT-SPK, HEFA-SPK, ATJ-SPK and HFS-SIP) and their use as an alternative to kerosene-type fuels in the aviation industry have also been assessed. Although these fuels are currently more costly than conventional aviation fuels, possible reduction in production costs has been reported as a potential solution. A preliminary study shows that i-butanol emissions (1.8 Tg/year) as a biofuel can increase ozone levels by up to 6% in the upper troposphere, highlighting a potential climate impact. However, a larger number of studies will be needed to assess the practicalities and associated cost of using the biofuel in existing vehicles, particularly in terms of identifying any modifications to existing engine infrastructure, the impact of biofuel emissions, and their chemistry on the climate and human health, to fully determine their suitability as a potential renewable energy source.
AI snapshot
Written from the paper’s full text.
TL;DR
This review assesses biofuels as a renewable transport energy source, weighing their emission trade-offs, feedstock generations, and aviation-fuel pathways against food-security, land-use, and atmospheric-chemistry concerns. It concludes that biofuels can help decarbonise transport but that a shift to advanced (non-edible) feedstocks and further research on air quality and climate impacts are needed.
Key findings
- Replacing fossil fuels with biofuels reduces particulate matter (PM), CO and unburned VOC emissions (attributed to higher oxygen content and more complete combustion), but generally increases NOx, acetaldehyde (CH3CHO) and peroxyacetyl nitrate (PAN) emissions — a trade-off the paper states explicitly.
- Biofuel production and consumption grew ~3% and ~6% respectively in 2019; the US was the largest consumer, followed by Brazil, Indonesia, China and France. Ethanol accounts for ~80% of all liquid biofuel production, with global production predicted to exceed 135 billion L by 2024 (USA 42%, Brazil 31%).
- EROEI for US bioethanol and biodiesel is "slightly higher than 1," whereas Brazilian sugarcane ethanol is 5–10, indicating regional variability in energy balance.
- A modelling study (STOCHEM-CRI) found that adding 1.8 Tg/year of i-butanol emissions as biofuel increased upper-tropospheric ozone and PAN by up to 6% and 4.5%, respectively; a separate study found ~11.5 Tg/year ethanol emission flux raised acetaldehyde by up to 30% and PAN by up to 3%.
- Aviation biofuels (FT-SPK, HEFA-SPK, ATJ-SPK, HFS-SIP) are currently more costly than conventional aviation fuel and must be blended with kerosene (e.g., FT-SPK and HEFA-SPK at 50:50; HFS-SIP at 10 vol%; ATJ-SPK ~15 vol%).
Methods
- Narrative literature review; no new data were created or analysed (stated in the Data Availability section).
- Synthesises prior studies on biofuel generations (first to fourth), production/consumption statistics (BP, USEIA data), emission and air-quality literature, and aviation-fuel conversion chemistry.
- Includes discussion of global 3-D chemistry transport modelling results (STOCHEM-CRI with the CRI mechanism) drawn from the authors' and others' prior work, plus reaction schemes for ethanol/acetaldehyde and i-butanol degradation.
Limitations
- Stated: research on biofuels is "inconclusive and contradictory," partly due to differing biofuel generations and geographic regions studied; most studies focus on first-generation biofuels and on single countries without global comparison; transport of biofuel emission products was not analysed; few studies examine impacts on O3 and SOA formation; projections of advanced-biofuel environmental impact are difficult due to limited industrial application.
- Evident from the text: this is a review without primary data or new modelling, so its quantitative claims rest on cited studies; the i-butanol and ethanol ozone/PAN figures come from model simulations rather than measurements, and the paper itself notes a larger number of studies is needed to assess practicalities and costs of using biofuels in existing vehicles.
Model-written summary. Check it against the paper before relying on it.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
0 of 182 cited sources checked · 0 supported · 0 flagged
- Findingnone given
Unfavourable increases in NOx, aldehyde, and PAN emissions are seen when using biofuel.
“However, unfavourable increases in NO x , aldehyde and PAN emissions were also seen when using biofuel.”
Quote in the paperSubstantial claim - Findingreasoning
In general, PM, CO, and VOC emissions from biofuels are lower than from petrol and diesel, mainly due to the higher oxygen content of biofuels.
“In general, PM, CO and VOC emissions from biofuels were lower than that of petrol and diesel, with the higher oxygen content of biofuels being the main reason for this finding.”
Quote in the paperSubstantial claim - Findingown data
In the STOCHEM-CRI model, incorporation of 1.8 Tg/year of i-butanol emissions and associated oxidation products increases ozone and PAN by up to 6% and 4.5%, respectively, in the upper troposphere.
“The incorporation of 1.8 Tg/year of i-butanol emissions and associated oxidation products in the model, STOCHEM-CRI increase the level of ozone and PAN by up to 6 and 4.5%, respectively, in the upper troposphere (see Figure 7).”
Quote in the paperSubstantial claim - Premisecitation
The high water content of algae compared with terrestrial crops means that the drying process is highly energy intensive.
“The high water content of algae compared with terrestrial crops [33], means that this process is highly energy intensive [34].”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [33] McLaren, J. (2009). Sugarcane as a Feedstock for Biofuels: An Analytical White Paper, National Corn Growers Association.
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- cites [34] Milledge, 2014, Methods of energy extraction from microalgal biomass: A review, Rev. Environ. Sci. Biotechnol. source
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- Premisecitation
Algae have great potential as biofuel feedstocks due to their capabilities of producing much higher yields with reduced resource inputs.
“Algae have been shown to have great potential as biofuel feedstocks, due to their capabilities of producing much higher yields with reduced resource inputs [26][27][28].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [26][27][28]
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- Premisecitation
Liquid biofuels have the greatest potential to help decarbonise the transport sector due to easier integration with existing technology.
“They can exist in solid, liquid, and gaseous forms; however, considerable research focuses on liquid biofuels as they have the greatest potential to help decarbonise the transport sector due to easier integration with existing technology [14].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [14] Guo, 2015, Bioenergy and biofuels: History, status and prespective. Renew, Sustain. Energy Rev. source
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- Premisenone given
The impact of biofuels on food security and production depends on the type of feedstock used in biofuel production.
“The literature suggests biofuels can negatively impact food security and production; however, this is dependent on the type of feedstock used in biofuel production.”
Quote in the paperNot a substantial claim - Interpretationreasoning
Biofuels are a potential renewable energy source in the transportation industry.
“Biofuels are arguably a potential renewable energy source in the transportation industry as they can be used within current infrastructures and require less technological advances than other renewable alternatives, such as electric vehicles and nuclear power.”
- Also stated in: § 2. Suitability of Biofuel as a Potential Renewable Energy Source · hedged
“Considering the different renewable energies, biofuels are arguably a potential renewable energy source in the transportation industry.”
Quote in the paperSubstantial claim- Rests on an assumption: Biofuels can be used within current infrastructures.
- Rests on an assumption: Biofuels require less technological advances compared with other energy sources.
- Also stated in: § 2. Suitability of Biofuel as a Potential Renewable Energy Source · hedged
- Premisenone given
Potential biofuel blends (FT-SPK, HEFA-SPK, ATJ-SPK and HFS-SIP) are currently more costly than conventional aviation fuels.
“Although these fuels are currently more costly than conventional aviation fuels, possible reduction in production costs has been reported as a potential solution.”
Quote in the paperNot a substantial claim - Premisenone given
Replacing fossil fuels by biofuels can simultaneously increase emissions of nitrogen oxides (NOx), acetaldehyde (CH3CHO) and peroxyacetyl nitrate (PAN).
“Replacing fossil fuels by biofuels can substantially reduce particulate matter (PM), carbon monoxide (CO) emissions, but simultaneously increase emissions of nitrogen oxides (NO x ), acetaldehyde (CH 3 CHO) and peroxyacetyl nitrate (PAN), resulting in debates concerning the way biofuels should be implemented.”
Quote in the paperSubstantial claim - Premisenone given
i-butanol emissions (1.8 Tg/year) as a biofuel can increase ozone levels by up to 6% in the upper troposphere.
“A preliminary study shows that i-butanol emissions (1.8 Tg/year) as a biofuel can increase ozone levels by up to 6% in the upper troposphere, highlighting a potential climate impact.”
Quote in the paperNot a substantial claim - Premisereasoning
First generation biofuels only provide minimum benefit over fossil fuels in terms of greenhouse gas emissions because they require a large amount of fossil energy to grow, collect and process.
“First generation biofuels only provide minimum benefit over fossil fuels in terms of greenhouse gas emissions as they require a large amount of energy (from fossil fuels) to grow, collect and process.”
Quote in the paperNot a substantial claim - Interpretationcitation
The future applicability of algae as biofuel feedstocks is highly dependent on the development of biomass-to-fuel conversion technology that can work with wet feedstocks, or drying processes with much reduced energy requirements.
“These factors highlight the growing need for research into algae as biofuel feedstocks, with its future applicability being highly dependent on the development of biomass-to-fuel conversion technology which can work with wet feedstocks, or drying processes with much reduced energy requirements [32].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [32] Milledge, 2014, Macroalgae-Derived Biofuel: A Review of Methods of Energy Extraction from Seaweed Biomass, Energies source
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- Premisecitation
A key benefit associated with the replacement of fossil fuels for biofuels is the reduced air pollution from motor vehicles.
“A key benefit associated with the replacement of fossil fuels for biofuels is the reduced air pollution from motor vehicles [11,69].”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [11] Arutyunov, 2017, Energy resource of the 21st century: Problems and forecasts. Can renewable energy source replace fossil fuels?, Russ. Chem. Rev. source
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- cites [69] Larson, 2006, A review of life-cycle analysis studies on liquid biofuel systems for the transport sector, Energy Sustain. Develop. source
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- Premisereasoning
Increased biofuel production can simultaneously improve food production by reducing GHG emissions which could be a current threat to food security.
“The increased biofuel production can simultaneously improve food production by reducing GHG emissions which could be a current threat to food security.”
Quote in the paperNot a substantial claim - Interpretationcitation
Extraction of biofuels is far less damaging to the local environment than extraction of fossil fuels.
“Explosions are reported with the extraction of crude oil for fossil fuels and many aquatic reserves can be polluted during extraction, posing a damaging effect to sea-life [70], thus extraction of biofuels is far less damaging to the local environment.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [70] Zabbey, 2017, Conflicts-Oil exploration and water, Glob. Chall. source
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- Premisecitation
The EROEI for the production of ethanol from sugarcane in Brazil is 5 to 10.
“However, EROEI for the production of ethanol from sugarcane in Brazil is 5 to 10, suggesting sugarcane ethanol production in Brazil costs less than that in US [50,51] and Brazil would benefit with using biofuel as energy source.”
Quote in the paperSubstantial claim0 of 2 sources checked - Premisecitation
The EROEI for the production of bioethanol and biodiesel in the US is slightly higher than 1.
“The energy balance defined as EROEI (Energy Return On Energy Invested) for the production of bioethanol and biodiesel in the US is slightly higher than 1 [49].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [49] Murphy, 2010, Year in review-EROI or energy return on (energy) invested, Ann. N. Y. Acad. Sci. source
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- Premisecitation
The economic security of a country can be improved with a larger biofuel industry, especially through the creation of jobs in rural and under-developed areas.
“Firstly, the economic security of a country can be improved with a larger biofuel industry, especially through the creation of jobs in rural and under-developed areas [55,56].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [55] Rastegari, 2019, Global scenario of biofuel production: Past, present and future, Prospects of Renewable Bioprocessing in Future Energy Systems, Biofuel and Biorefinery Technologies source
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- cites [56] Subramaniam, 2020, Biofuels, environmental sustainability and food security: A review of 51 countries, Energy Res. Soc. Sci. source
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- Premisecitation
Studies in the US, Brazil, Japan and Europe suggest that the use of food crops in biofuel production has been important in explaining the steady increase in food prices since 2000.
“Studies in the US, Brazil, Japan and Europe suggest that the use of food crops in biofuel production has been important in explaining the steady increase in food prices since 2000 [64].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [64] Renzaho, 2017, Biofuel production and its impact on food security in low and middle income countries: Implications for the post-2015 sustainable development goals, Renew. Sust. Energ. Rev. source
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- Premisecitation
Biofuels have higher production costs in the current market due to the requirement of more intensive processing procedures.
“Biofuels also have higher production costs in the current market due to requirement of more intensive processing procedures and, as with increased agriculture of any form, the production and end use of biofuels comes with concerns of deforestation, biodiversity loss and increased fertilizer and pesticide use [60].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [60] Webb, A., and Coates, D. (2012). Biofuels and Biodiversity. Secretariat of the Convention on Biological Diversity, Secretariat of the Convention on Biological Diversity.
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- Interpretationreasoning
To generate a certain amount of biofuel, it is necessary to spend almost the same amount of fossil fuel.
“Thus, in order to generate a certain amount of biofuel, it is necessary to spend almost the same amount of fossil fuel.”
Quote in the paperSubstantial claim - Premisecitation
The production of biofuel crops can lead to competition for natural resources, particularly land, food, and water.
“Although biofuels are renewably sourced, the production of biofuel crops can lead to competition for natural resources, particularly land, food, and water [61,62].”
Quote in the paperNot a substantial claim0 of 2 sources checked - Premisereasoning
The increased use of biodiesel and ethanol blends in vehicle engines causes a reduction in PM, CO and unburned VOC emissions than traditional fuels.
“Biofuels tend to burn cleaner, the increased use of biodiesel and ethanol blends in vehicle engines, causes a reduction in PM, CO and unburned VOC emissions than traditional fuels [53,54,71,72].”
Quote in the paperSubstantial claim0 of 4 sources checked- cites [53] AQEG (2021, August 30). Road Transport Biofuels: Impact on UK Air Quality, Available online: https://www.gov.uk/government/publications/road-transportbiofuels-impact-on-uk-air-quality.
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- cites [54] Dias, D., Antunes, A.P., and Tchepel, O. (2019). Modelling of emissions and energy use from biofuel fuelled vehicles at urban scale. Sustainability, 11. source
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- cites [71] Demirbas, 2009, Political, economic and environmental impacts of biofuels: A review, App. Energy source
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- cites [72] Shekofteh, 2020, Performance and emission characteristics of a diesel engine fueled with functionalized multiwall carbon nanotubes (MWCNTs-OH) and diesel-biodiesel-bioethanol blends, Energy Rep. source
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- Premisecitation
Increased biofuel consumption can cause existing food crops to move from food to biofuel markets.
“Alternatively, increased biofuel consumption can cause existing food crops to move from food to biofuel markets [63].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [63] Locke, A., and Henley, G. (2014). A Review of the Literature on Biofuels and Food Security at a Local Level: Assessing the State of the Evidence, Overseas Development Institute.
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- Premisecitation
Advanced fuels share many advantages over first-generation biofuels, such as reduced land requirements and minimal fertilizer, pesticide, and fossil energy input.
“Advanced fuels share many advantages over first-generation biofuels, such as reduced land requirements and minimal fertilizer, pesticide, and fossil energy input [66].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [66] Hill, 2006, Environmnetal, economic and energetic costs and benefits of biodiesel and ethanol biofuels, Proc. Nat. Acad. Sci. USA source
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- Premisereasoning
The general consensus across the literature is that the increased NOx emissions result from higher combustion temperatures produced by the slightly advanced injection of biofuels into the engine cycle, due to their different physical properties compared with diesel.
“The general consensus across the literature is that the increased NO x emissions result from higher combustion temperatures produced by the slightly advanced injection of biofuels into the engine cycle, due to their different physical properties compared with”
Quote in the paperNot a substantial claim - Premisecitation
Once formed, acetaldehyde is rapidly removed from the atmosphere by reaction with OH and photolysis that enhances HOx levels.
“Once formed, acetaldehyde is rapidly removed from the atmosphere by reaction with OH and importantly photolysis that enhances HO x levels.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [98] Tanner, 1988, Atmospheric chemistry of aldehydes: Enhanced peroxyacetyl nitrate formation from ethanol-fueled vehicular emissions, Environ. Sci. Technol. source
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- cites [99] Gaffney, 1997, Potential air quality effects of using ethanol-gasoline fuel blends: A field study in Albuquerque, New Mexico, Environ. Sci. Technol. source
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- Premisecitation
Biofuels also have the potential to be 'carbon negative' through strategic choices of producers and the use of applications such as carbon capture and storage.
“In addition, biofuels also have the potential to be 'carbon negative' through strategic choices of producers and the use of applications such as carbon capture and storage [77].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [77] Mathews, 2008, Carbon-negative biofuels, Energy Policy source
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- Premisecitation
Photolysis of acetaldehyde is an important loss process, contributing ~10% to the total loss rate for this compound.
“Photolysis of acetaldehyde is also an important loss process, contributing ~10% to the total loss rate for this compound [100-102].”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [100] Khan, 2015, The global atmospheric budget and distribution of acetone using the 3-D global model, STOCHEM-CRI, Atmos. Environ. source
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- cites [101] Khan, 2017, Global budget and distribution of peroxyacetyl nitrate (PAN) for present and preindustrial scenarios, Int. J. Earth Environ. Sci. source
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- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
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- Premisecitation
Short-term O3 exposure is significantly and sustainably linked to hospital admissions.
“Studies have demonstrated significant and sustained links between short-term O 3 exposure and hospital admissions [83][84][85]”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [83][84][85]
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- Premisenone given
Most investigations show a beneficial reduction in PM emissions with increased use of biofuel blends.
“However, as most investigations show a beneficial reduction in PM emissions with the increased use of biofuel blends, multiple suggestions have been made on how to mitigate the associated harmful NO x emissions.”
Quote in the paperSubstantial claim - Interpretationcitation
Wider application of biofuels within transportation could lead to an increase in VOCs and aerosol particles released into the atmosphere.
“As well as increased NO x emissions, the wider application of biofuels within transportation could lead to an increase in the VOCs and aerosol particles released into the atmosphere [92].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [92] Nogueira, 2014, Formaldehyde and acetaldehyde measurements in urban atmosphere impacted by the use of ethanol biofuel: Metropolitan area of Sao Paulo (MASP), 2012-2013, Fuel source
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- Premisecitation
Formaldehyde and acetaldehyde are the most abundant aldehydes due to the use of biofuels.
“Formaldehyde and acetaldehyde are the most abundant due to the use of biofuels [95]”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Zhu, 2013, Effects of ethanol-biodiesel blend and diesel oxidation catalyst (DOC) on particulate and unregulated emissions, Fuel source
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- Premisecitation
In some cases, biofuel blends reduced NOx and CO emissions due to greater resistance against knocking.
“There are some cases where biofuel blends reduced NO x and CO emissions, as a result of a greater resistance against knocking [89].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [89] Tan, 2017, Engine performance and emissions characteristics of a diesel engine fueled with diesel-biodiesel-bioethanol emulsions, Energy Convers. Manag. source
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- Premisecitation
Regions with high levels of bioethanol use have exhibited higher acetaldehyde concentrations, with urban levels estimated to increase by up to 650% when an 85% ethanol-petroleum blend is used.
“Regions with high levels of bioethanol use have exhibited higher acetaldehyde concentrations, with urban levels estimated to increase by up to 650% when an 85% ethanol-petroleum blend is used [94].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [94] Sundvor, 2014, Impact of bioethanol fuel implementation in transport based on modelled acetaldehyde concentration in the urban environment, Sci. Total Environ. source
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- Premisecitation
Formaldehyde in vehicle exhaust is mainly produced from the incomplete combustion of alcohols.
“Formaldehyde in vehicle exhaust is mainly produced from the incomplete combustion of alcohols.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Zhu, 2013, Effects of ethanol-biodiesel blend and diesel oxidation catalyst (DOC) on particulate and unregulated emissions, Fuel source
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- Premisecitation
The majority of the literature demonstrates that there is an unfavourable increase in NOx emissions when using biofuels as opposed to fossil fuels.
“Additionally, despite the favourable reduction in PM, CO and VOC emissions, the majority of the literature demonstrates that there is an unfavourable increase in NO x emissions when using biofuels as opposed to fossil fuels [39,53,54].”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [39] Coelho, 2017, History, evolution and environmental impact of biodiesel in Brazil: A review, Renew. Sust. Energ. Rev. source
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- cites [53] AQEG (2021, August 30). Road Transport Biofuels: Impact on UK Air Quality, Available online: https://www.gov.uk/government/publications/road-transportbiofuels-impact-on-uk-air-quality.
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- cites [54] Dias, D., Antunes, A.P., and Tchepel, O. (2019). Modelling of emissions and energy use from biofuel fuelled vehicles at urban scale. Sustainability, 11. source
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- Premisecitation
The resultant hydroxy-ethyl radical reacts further with oxygen to produce acetaldehyde.
“The resultant hydroxy-ethyl radical then reacts further with oxygen to produce acetaldehyde [97].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [97] Grosjean, 1997, Atmospheric chemistry of alcohols, J. Braz. Chem. Soc. source
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- Premisecitation
Assuming carbon neutrality is problematic as biofuels produced in areas such as North America and Europe are often termed 'carbon positive' due to the large input of fossil fuel activities and fertilizer in their production.
“However, assuming carbon neutrality is problematic as biofuels produced in areas such as North America and Europe are often termed 'carbon positive' due to the large input of fossil fuel activities and fertilizer in their production [77].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [77] Mathews, 2008, Carbon-negative biofuels, Energy Policy source
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- Premisecitation
Adoption of biodiesel as a fractional component of diesel use, investigated using a global three-dimensional chemistry transport model STOCHEM-CRI, found an overall improvement in air quality with reductions in ozone, PM, aromatic species and peroxy acetyl nitrate (PAN).
“Adoption of biodiesel as a fractional component of diesel use was investigated using a global three-dimensional chemistry transport model, STOCHEM-CRI and found an overall improvement in air quality with reductions in ozone, PM, aromatic species and peroxy acetyl nitrate (PAN) [78].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [78] Cooke, 2010, On the effect of a global adoption of various fractions of biodiesel on key species in the troposphere, Int. J. Oil Gas. Coal Technol. source
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- Interpretationcitation
Increased NOx emissions from biofuels could lead to adverse impacts on both the environment and public health because of formation of additional ozone.
“The increased NO x emissions from biofuels could lead to adverse impacts on both the environment and public health because of formation of additional ozone, which is a component of photochemical smog and powerful oxidant [81,82].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [81] Ehhalt, D., Prather, M., Dentener, F., Derwent, R., Dlugokencky, E.J., Holland, E., Isaksen, I., Katima, J., Kirchhoff, V., and Matson, P. (2001). Atmospheric Chemistry and Greenhouse Gases, in Climate Change 2001: The Scientific Basis, Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press.
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- cites [82] Zhang, 2019, Ozone pollution: A Major health hazard worldwide, Front. Immun. source
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- Premisecitation
Oxidation of ethanol and biodiesel in an internal combustion engine can form high concentrations of aldehydes compared with fossil fuels due to the presence of the hydroxyl group.
“The oxidation of ethanol and biodiesel, within an internal combustion engine, can form high concentrations of aldehydes compared with fossil fuels due to the presence of the hydroxyl group [93].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [93] Zarante, 2016, Simulation of aldehyde emissions from an ethanol fueled spark ignition engine and comparison with FTIR measurements, J. Phys. Conf. Ser. source
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- Premisecitation
The combustion and exhaust emissions of a single cylinder diesel engine, with biodiesel blends, found that NOx emissions were significantly higher than diesel alone.
“The combustion and exhaust emissions of a single cylinder diesel engine, with biodiesel blends, found that NO x emissions were significantly higher than diesel alone [79,80].”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [79] Can, 2017, Combustion and exhaust emissions of canola biodiesel blends in a single cylinder DI diesel engine, Renew. Energy source
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- cites [80] Nabi, 2006, Improvement of engine emissions with conventional diesel fuel and diesel-biodiesel blends, Bioresour. Technol. source
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- Premisecitation
Acetaldehyde emissions from biofuels are mainly produced from vehicle exhaust, in the post flame oxidation of unburned ethanol with a hydroxyl radical (OH).
“Acetaldehyde emissions from biofuels are mainly produced from vehicle exhaust, in the post flame oxidation of unburned ethanol with a hydroxyl radical (OH) [95].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Zhu, 2013, Effects of ethanol-biodiesel blend and diesel oxidation catalyst (DOC) on particulate and unregulated emissions, Fuel source
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- Premisecitation
PAN can transport and release NOx to the remote troposphere, which is a major concern for global distribution of ozone and OH.
“PAN can also transport and release NO x to the remote troposphere which is a major concern when considering the global distribution of the two main tropospheric oxidants: ozone and OH [105].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [105] Fischer, 2014, Atmospheric peroxyacetyl nitrate (PAN): A global budget and source attribution, Atmos. Chem. Phys. source
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- Premisecitation
Studies in Brazil and New Mexico have shown increased concentrations of acetaldehyde and PAN in the atmosphere during periods of increased biofuel use.
“Studies in Brazil and New Mexico have shown increased concentrations of acetaldehyde and PAN in the atmosphere during periods of increased biofuel use [99].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [99] Gaffney, 1997, Potential air quality effects of using ethanol-gasoline fuel blends: A field study in Albuquerque, New Mexico, Environ. Sci. Technol. source
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- Interpretationreasoning
Photolysis contributes to the HOx budget and can be an important additional source of HOx, e.g., in the upper Troposphere.
“Therefore, photolysis contributes to the HO x budget and can be an important additional source of HO x , e.g., in the upper Troposphere [103].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [103] Wasiuk, D.K., Khan, M.A.H., Shallcross, D.E., and Lowenberg, M.H. (2016). An aircraft fuel burn and emissions inventory for 2005-2011. Atmosphere, 7. source
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- Interpretationreasoning
Increased biofuel usage results in an unfavorable rise in NOx, aldehyde and PAN emissions.
“A trade-off arises from the replacement of fossil fuels with biofuels and increased biofuel usage results in a reduction of harmful PM, CO and VOC emissions compared with fossil fuels, but an unfavorable rise in NO x , aldehyde and PAN emissions.”
Quote in the paperSubstantial claim - Premisecitation
The lifetime of ethanol is long enough (1-3 days) to be transported long distances before oxidation by OH radicals to give acetaldehyde and consequently form PAN.
“The lifetime of ethanol is long enough (1-3 days) to be transported long distances before oxidation by OH radicals to give acetaldehyde and consequently form PAN.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
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- Premisecitation
Some research suggests that burning biofuels in one location, such as a power generation facility, is more efficient than burning in numerous sub-optimal vehicle engines.
“Some research [110,111] suggests that burning biofuels in one location, such as a power generation facility, is more efficient than burning in numerous sub-optimal vehicle engines.”
Quote in the paperNot a substantial claim0 of 2 sources checked - Premisecitation
Reports have shown that use of FT-SPK displayed emissions which contained negligible quantities of sulphur, soot and aromatic content.
“Reports have shown that use of FT-SPK displayed emissions which contained negligible quantities of sulphur, soot and aromatic content [124].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [124] Timko, 2011, Combustion products of petroleum jet fuel, a Fischer-Tropsch synthetic fuel and a biomass fatty acid methyl ester fuel for a gas turbine engine, Combust. Sci. Technol. source
Not checked in the free run.
- Premisecitation
Due to the nature of jet fuels, alternative fuels currently employed in road transportation and biodiesel cannot be used within the aviation industry.
“Due to the nature of jet fuels, alternative fuels currently employed in road transportation and biodiesel cannot be used within the aviation industry.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisereasoning
Many of these impurities would be destructive for FT catalysts.
“Many of these impurities would be destructive for FT catalysts.”
Quote in the paperSubstantial claim - Premisecitation
BAF must be in line with ASTM D1655 specifications to be compatible with the existing air fleets.
“However, BAF must be in line with ASTM D1655 specifications to be compatible with the existing air fleets [122].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [122] Yang, 2019, An overview on performance characteristics of bio-jet fuels, Fuel source
Not checked in the free run.
- Premisecitation
The zonal plot shows the highest levels up to 35 and 30 ppt at 0-20°S and 30°N-40°N, respectively.
“The zonal plot shows the highest levels up to 35 and 30 ppt at 0-20 • S and 30 • N-40 • N, respectively (Figure 4b).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
Not checked in the free run.
- Premisecitation
Emissions from biofuels can also occur at different stages of the supply chain such as transporting feedstock, producing liquid biofuel, and distributing biofuels.
“To a lesser extent, emissions from biofuels can also occur at different stages of the supply chain such as transporting feedstock to the biorefinery, producing the liquid biofuel, and distributing biofuels to consumers [106].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [106] National Research and Council (2011). Renewable Fuel Standard: Potential Economic Effects of U.S. Biofuel Policy.
Not checked in the free run.
- Premisecitation
Production of FT-SPK shows the use of syngas (CO + H2) which can be converted to jet fuels.
“Production of Fischer-Tropsch Synthetic Paraffinic Kerosene (FT-SPK), displayed in Scheme 1, shows the use of syngas (CO + H 2 ) which can be converted to jet fuels [123].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [123] Blakey, 2011, Aviation gas turbine alternative fuels: A review, Proc. Combust. Inst. source
Not checked in the free run.
- Interpretationreasoning
Increased biofuel usage results in a reduction of harmful PM, CO and VOC emissions compared with fossil fuels.
“A trade-off arises from the replacement of fossil fuels with biofuels and increased biofuel usage results in a reduction of harmful PM, CO and VOC emissions compared with fossil fuels, but an unfavorable rise in NO x , aldehyde and PAN emissions.”
Quote in the paperSubstantial claim - Premisecitation
HFS-SIP fuels, produced via hydroprocessing processes of β-farnesene, have been certified to be blended in 10 vol% with kerosene and used as aviation fuel.
“HFS-SIP fuels, produced via hydroprocessing processes of β-farnesene, have been certified to be blended in 10 vol% with kerosene and used as aviation fuel [122].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [122] Yang, 2019, An overview on performance characteristics of bio-jet fuels, Fuel source
Not checked in the free run.
- Premisecitation
It is difficult to identify a microorganism suitable to produce C5 and other C4 substituted alcohols from sugar glucose while minimising the steps in the process and making it cost effective.
“It is difficult to identify a microorganism suitable to produce C5 and other C4 substituted alcohols from sugar glucose while minimising the steps in the process and making it cost effective [141].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [141] Atsumi, 2008, Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels, Nature source
Not checked in the free run.
- Premisecitation
Waste oils possess a higher abundance of impurities which could interact with catalysts present and disrupt hydroprocessing.
“Furthermore, waste oils possess a higher abundance of impurities which could interact with catalysts present and disrupt hydroprocessing [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
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- Premisecitation
Low-grade waste oils cannot be used as the concentration of free fatty acids is too high to produce biofuels.
“Low-grade waste oils cannot be used as the concentration of free fatty acids is too high to produce biofuels [134].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [134] Toba, 2011, Hydrodeoxygenation of waste vegetable oil over sulfide catalysts, Catal. Today source
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- Premisecitation
Development of a biomass feedstock that is suitable for this process still poses a problem.
“Development of a biomass feedstock that is suitable for this process still poses a problem [123].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [123] Blakey, 2011, Aviation gas turbine alternative fuels: A review, Proc. Combust. Inst. source
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- Premisecitation
Utilisation of waste cooking oils removes the concern over growing crops just for oil usage as these oils have already been used in another sector and are thus multi-purpose.
“Utilisation of waste cooking oils removes the concern over growing crops just for oil usage as these oils have already been used in another sector and are thus multi-purpose [133].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [133] Chiaramonti, 2014, Sustainable bio kerosene: Process routes and industrial demonstration activities in aviation biofuels, Appl. Energy source
Not checked in the free run.
- Premisecitation
FT-SPK fuels are required to be blended with traditional kerosene fuels (50%) before use in aircraft to meet standard aviation fuel specifications.
“Unfortunately, FT-SPK fuels are required to be blended with traditional kerosene fuels (50%) before use in aircraft to meet standard aviation fuel specifications [122].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [122] Yang, 2019, An overview on performance characteristics of bio-jet fuels, Fuel source
Not checked in the free run.
- Premisenone given
Microorganisms have been reported to be extremely effective in creating alternative aviation blending fuels.
“Microorganisms has been reported to be extremely effective in creating alternative aviation blending fuels.”
Quote in the paperNot a substantial claim - Premisecitation
The use of non-edible jatropha oil coupled with Ni catalysts at high temperatures led to a production of 8% aromatic content.
“The use of non-edible jatropha oil coupled with Ni catalysts at high temperatures led to a production of 8% aromatic content.”
Quote in the paperNot a substantial claim - Premisenone given
Direct conversion of sugar to hydrocarbon molecules has been reported which avoids complexity issues with a number of synthetic steps involved.
“However, direct conversion of sugar to hydrocarbon molecules has been reported which avoids complexity issues with a number of synthetic steps involved.”
Quote in the paperNot a substantial claim - Premisecitation
Issues have been reported with using waste oils.
“However, issues have been reported with using waste oils.”
Quote in the paperNot a substantial claim - Premisecitation
To effectively convert these to jet fuels many steps are required involving oxygen removal and C-C coupling reactions to increase the carbon length to 9-16 in line with kerosene fuels.
“To effectively convert these to jet fuels many steps are required involving oxygen removal and C-C coupling reactions to increase the carbon length to 9-16 in line with kerosene fuels [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisecitation
Genetically engineered yeast has been utilised as it consumes sugars and excretes long chain alkenes, predominantly β-farnesene.
“Genetically engineered yeast has been utilised as it consumes sugars and excretes long chain alkenes, predominantly β-farnesene [138].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [138] Bauen, 2020, Sustainable aviation fuels, Johns. Matthey Technol. Rev. source
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- Premisecitation
ATJ-SPK must be blended with kerosene at approximately 15 vol% to be used as aviation fuel.
“Unfortunately, ATJ-SPK would also be required to be blended with kerosene (approx.15 vol%) to be used as aviation fuel [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisecitation
Presently, the iso-butanol/ethanol feedstock is generally obtained through sugar microbial fermentation commonly employed in both wine and beer production processes.
“Presently, the iso-butanol/ethanol feedstock is generally obtained through sugar microbial fermentation commonly employed in both wine and beer production processes [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisereasoning
The method of extracting sugars initially provides some difficulty.
“However, the method of extracting sugars initially provides some difficulty.”
Quote in the paperNot a substantial claim - Interpretationreasoning
The effects of i-butanol oxidation on ozone are significant in the upper troposphere because sufficient timescales allow transport of RO2 to higher altitudes.
“The effects are significant in the upper troposphere, with sufficient timescales allowing the transport of RO 2 and hence effects on ozone to be seen at these higher altitudes.”
Quote in the paperSubstantial claim - Premisecitation
There have been limited studies investigating the impact of biofuel emissions on altering O3 and SOA formation.
“Currently, there have been limited studies investigating the impact of biofuel emissions on altering O 3 and SOA formation [152].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [152] He, 2020, Secondary organic aerosol formation from evaporated biofuels: Comparison to gasoline and correction for vapor wall losses, Environ. Sci. Process. Impacts source
Not checked in the free run.
- Premisecitation
ATJ-SPK could only be employed within short-haul flights because its energy density would decrease aircraft flight range.
“Although the implementation of iso-butanol would be promising, this ATJ-SPK could only be employed within short-haul flights as the energy density of the fuel would decrease the aircraft flight range if employing this fuel [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisecitation
ATJ-SPK would also be required to be blended with kerosene (approx.15 vol%) to be used as aviation fuel.
“Unfortunately, ATJ-SPK would also be required to be blended with kerosene (approx.15 vol%) to be used as aviation fuel [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Interpretationreasoning
Mass production of HEFA-SPK with algae oil can reduce production costs due to high yield of these microorganisms.
“Mass production of HEFA-SPK with algae oil proposes a solution to reduce current produc-tion costs due to the high yield production of these microorganisms.”
Quote in the paperSubstantial claim - Interpretationown data
Anthropogenic emissions from biofuel usage could be a significant part of anthropogenic sources of upper tropospheric ozone that contribute to global climate change.
“This had led to growing concerns around anthropogenic sources of upper tropospheric ozone and their role in global climate change [150], with this study finding that anthropogenic emissions from biofuel usage could be a significant part of this.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [150] Jacob, 2001, Chemistry of HOx radicals in the upper troposphere, Atmos. Environ. source
Not checked in the free run.
- Interpretationreasoning
Wider application of biofuels presents a trade-off between reduction in PM pollution and increase in harmful NOx and PAN emissions.
“This demonstrates that the wider application of biofuels presents a trade-off between a reduction in PM pollution or an increase in harmful NO x and PAN emissions.”
Quote in the paperSubstantial claim - Premisecitation
Iso-butanol/ethanol feedstock is generally obtained through sugar microbial fermentation, as used in wine and beer production.
“Presently, the iso-butanol/ethanol feedstock is generally obtained through sugar microbial fermentation commonly employed in both wine and beer production processes [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Premisecitation
ATJ-SPK presents an advantage over FT-SPK because FT-SPK only produces saturated linear hydrocarbons.
“This presents an advantage over FT-SPK, as this process only produces saturated linear hydrocarbons [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
- Interpretationreasoning
NOx and RO2 radicals formed during multi-generation oxidation of i-butanol catalyze ozone formation by promoting NO2 production in a coupled photochemical cycle.
“This NO x and RO 2 radicals formed over the course of the multi-generation oxidation of i-butanol resulted in the catalysis of ozone formation, as they promote the production of NO 2 in a closely coupled photochemical reaction cycle.”
Quote in the paperSubstantial claim - Premisecitation
Replacing aviation fossil fuels with biofuels can achieve a significant reduction in GHG emissions.
“For example, research by Kousoulidou et al. [117] and Mohsin et al. [118] showed that a significant reduction in GHG emissions can be achieved by replacing aviation fossil fuels with biofuels.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [117] Kousoulidou, 2016, Biofuels in aviation: Fuel demand and CO2 emissions evolution in Europe toward 2030, Transp. Res. Part. D Transp. Environ. source
Not checked in the free run.
- cites [118] Mohsin, 2017, Assessment of Biofuels in Aviation Industry for Environmental Sustainability, Chem. Eng. Trans.
Not checked in the free run.
- Premisecitation
i-Butanol is predominantly removed from the atmosphere via reaction with the OH radical, a highly site-specific process.
“Once emitted, i-butanol is predominantly removed from the atmosphere via reaction with the OH radical, which is a highly sitespecific process.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [143] McGillen, 2013, Gas-Phase Rate Coefficients for the OH plus n-, i-, s- and t-Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behaviour and Site-Specific Reactivity, J. Phys. Chem. A source
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- cites [144] McGillen, 2016, Experimentally Determined Site-Specific Reactivity of the Gas-Phase OH and Cl plus i-Butanol Reactions Between 251 and 340 K, J. Phys. Chem. A source
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- Premisecitation
Photo-oxidation products of i-butanol can influence tropospheric ozone, SOA, and PANs.
“Once released into the atmosphere, the photo-oxidation products of i-butanol can influence tropospheric ozone, as well as other secondary pollutants such as secondary organic aerosols (SOA) and PANs.”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [143] McGillen, 2013, Gas-Phase Rate Coefficients for the OH plus n-, i-, s- and t-Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behaviour and Site-Specific Reactivity, J. Phys. Chem. A source
Not checked in the free run.
- cites [144] McGillen, 2016, Experimentally Determined Site-Specific Reactivity of the Gas-Phase OH and Cl plus i-Butanol Reactions Between 251 and 340 K, J. Phys. Chem. A source
Not checked in the free run.
- Interpretationnone given
HEFA-SPK fuels are compatible with current air fleets if blended with current kerosene fuels.
“HEFA-SPK fuels also provide an effective solution and, like FT-SPK, fuels are compatible with current air fleets if blended with current kerosene fuels.”
Quote in the paperSubstantial claim - Premisenone given
Ethanol cannot be used directly in aircraft engines due to its high volatility, high water absorption and a [cut off].
“Ethanol, in particular, cannot be used directly in aircraft engines due to its high volatility, high water absorption and a”
Quote in the paperNot a substantial claim - Interpretationcitation
The increase in upper tropospheric ozone from i-butanol emissions could have implications for global climate.
“The increase in ozone in the upper troposphere could have implications for the global climate.”
Quote in the paperSubstantial claim - Interpretationnone given
All mentioned alternative aviation fuels must be blended with CAF to be compatible with current air fleets.
“Furthermore, all of these alternative fuels also have to be blended with CAF to be compatible with current air fleets.”
Quote in the paperNot a substantial claim - Premisecitation
Blending FT fuels leads to clear emission reductions in CO2, CO, SOx, and NOx.
“However, advancements in bio-fuel implementation are promising, with clear emission reduction in CO 2 , CO, SO x and NO x , particularly when blending FT fuels [124].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [124] Timko, 2011, Combustion products of petroleum jet fuel, a Fischer-Tropsch synthetic fuel and a biomass fatty acid methyl ester fuel for a gas turbine engine, Combust. Sci. Technol. source
Not checked in the free run.
- Premisecitation
Ozone is a potent greenhouse gas at upper tropospheric altitudes due to its ability to absorb IR, UV, and visible radiation.
“Numerous studies have reported its potency as a greenhouse gas at these altitudes, due to its ability to absorb IR, UV and visible radiation [146][147][148][149].”
Quote in the paperSubstantial claim0 of 4 sources checked- cites [146] Wang, 1980, Greenhouse effects due to man-made perturbations of trace gases, J. Atmos. Sci. source
Not checked in the free run.
- cites [147] Lacis, 1990, Radiative forcing of climate by changes in the vertical distribution of ozone, J. Geophys. Res. source
Not checked in the free run.
- cites [148] Hauglustaine, 1994, The importance of atmospheric chemistry in the calculation of radiative forcing on the climate system, J. Geophys. Res. source
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- cites [149] Mickley, 1999, Radiative forcing from tropospheric ozone calculated with a unified chemistry-climate model, J. Geophys. Res. source
Not checked in the free run.
- Premisecitation
The relatively short lifetime of i-butanol (a few days) means its emissions and oxidation products are likely to impact local and regional air quality.
“The relatively short lifetime of i-butanol (a few days) [143] mean that its emission and its oxidation products are likely to impact local and regional air quality.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [143] McGillen, 2013, Gas-Phase Rate Coefficients for the OH plus n-, i-, s- and t-Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behaviour and Site-Specific Reactivity, J. Phys. Chem. A source
Not checked in the free run.
- May combine two claims. 71
- Classified as probably not a substantial claim. 63
May combine two claims.
PremisecitationAlgae can fix CO2, which has been proposed as a method for removing CO2 from flue gases from power plants, thus reducing GHG emissions.
“The use of algae also has other environmental advantages, as a result of their ability to fix CO 2 , which has been proposed as a method for removing CO 2 from flue gases from power plants, thus reducing GHG emissions [29][30][31].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [29][30][31]
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
PremisecitationBiofuels can negatively impact food security and production.
“The literature suggests biofuels can negatively impact food security and production; however, this is dependent on the type of feedstock used in biofuel production.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationEthanol is currently the most widely used biofuel globally, accounting for approximately 80% of all liquid biofuel production.
“Ethanol is currently the most widely used biofuel globally, accounting for approximately 80% of all liquid biofuel production [15,16].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [15] Lee, J.W. (2013). Advanced Biofuels and Bioproducts, Springer. [1st ed.]. source
Not checked in the free run.
- cites [16] Popp, J., Harangi-Rakos, M., Gabnai, Z., Balogh, P., Antal, G., and Bai, A. (2016). Biofuels and their co-products as livestock feed: Global economic and environmental implications. Molecules, 21. source
Not checked in the free run.
Probably not a substantial claim: may not pass S2 (checkable), S4 (based).
Premisenone givenAdvanced biofuels, derived from inedible biomass, require further research and development to reach their full commercial potential.
“Advanced biofuels, derived from inedible biomass, are heavily favoured but require further research and development to reach their full commercial potential.”
Quote in the paperNot a substantial claimClassified as probably not a substantial claim. May combine two claims.
Premisenone givenThere has been little research on the economic and environmental feasibility of using algae as a biofuel feedstock, with concerns regarding its commercial-scale production.
“However, there has been little research on the economic and environmental feasibility of using algae as a biofuel feedstock, with concerns regarding its commercial-scale production.”
Quote in the paperSubstantial claimMay combine two claims.
Premisenone givenReplacing fossil fuels by biofuels can substantially reduce particulate matter (PM) and carbon monoxide (CO) emissions.
“Replacing fossil fuels by biofuels can substantially reduce particulate matter (PM), carbon monoxide (CO) emissions, but simultaneously increase emissions of nitrogen oxides (NO x ), acetaldehyde (CH 3 CHO) and peroxyacetyl nitrate (PAN), resulting in debates concerning the way biofuels should be implemented.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationPolicies in Europe, the US and Brazil caused the biofuel industry to grow in the last decade, with biofuels now representing around 3% of transport fuels in use globally.
“The introduction of such policies, particularly in Europe, the US and Brazil, has caused the biofuel industry to grow in the last decade with biofuels now representing around 3% of transport fuels in use globally [12,13].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [12] Eisentraut, A. (2011). Technology Roadmap—Biofuels for Transport, International Energy Agency. Available online: https://fiva.org/wp-content/uploads/2019/04/Technology-Biofuels-for-Transport.pdf.
Not checked in the free run.
- cites [13] Timilsina, 2014, Biofuels in the long-run global energy supply mix for transportation, Philos. Trans. R. Soc. A source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationIndonesia has the potential to become the largest biofuel manufacturer in the world.
“Indonesia has the potential to become the largest biofuel manufacturer in the world [45].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [45] Putrasari, 2016, Resources, policy and research activities of biofuel in Indonesia: A review, Energy Rep. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationGlobal biofuel production and consumption in 2019 increased by ~3% and ~6%, respectively.
“Global biofuel production and consumption in 2019 increased by ~3% and ~6%, respectively, as displayed in Figure 3a,b.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [1] BP (2020). Statistical Review of World Energy, BP p.l.c.. [69th ed.]. Available online: https://www.bp.com/en/global/corporate/energy-economics/statistical-review-of-world-energy.html.
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
InterpretationreasoningIncreasing use of biofuel across the world is likely to make up a significant proportion of global trace VOCs in the near future.
“Increasing use of biofuel across the world is likely to make up a significant proportion of global trace VOCs in the near future.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationBiodiesel has better lubricity and is less toxic than conventional diesel, making it safer and easier to handle.
“Biodiesel also has a better lubricity and is less toxic than conventional diesel, making it safer and easier to handle [57].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [57] US Department of Energy (2004). Biodiesel Handling and Use Guidelines.
Not checked in the free run.
Probably not a substantial claim: may not pass S4 (based).
Interpretationnone givenLarge-scale use of biofuel will result in direct emissions into the atmosphere via leakage, evaporation or incomplete combustion.
“The large-scale use of biofuel will result in direct emissions into the atmosphere via leakage, evaporation or incomplete combustion.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenSecond, third and fourth generation biofuels are still in the research and development phase and have not reached their full commercial potential.
“Second, third and fourth generation biofuels are commonly referred to as 'advanced biofuels' and thought to hold many advantages over first generation fuels, but, they are still in the research and development phase and have not reached their full commercial potential.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationThe agricultural crops for bioethanol production on an industrial scale led to rapid and irreversible soil degradation, water scarcity, fertilizer use and pesticide application resulting in air and water pollution, and the loss of wild and agricultural biodiversity.
“The agricultural crops (e.g., sugarcane, corn) for bioethanol production on an industrial scale led to rapid and irreversible soil degradation, water scarcity, fertilizer use and pesticide application resulting in air and water pollution, and the loss of wild and agricultural biodiversity [65].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [65] Wu, 2018, Bioenergy production and environmental impacts, GeoSci. Lett. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
Interpretationnone givenThe reduced application of advanced biofuels in industry makes projections of their future environmental impact difficult.
“Additionally, despite the strong agreement across the literature that a shift to advanced biofuels is needed, the reduced application of these fuels in industry makes projections of their future environmental impact difficult.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationReduced food production is likely to trigger a subsequent rise in food prices, which could harm the economy and worsen food insecurity for those in poverty.
“Reduced food production is likely to trigger a subsequent rise in food prices, which could harm the economy and worsen food insecurity for those in poverty [11].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [11] Arutyunov, 2017, Energy resource of the 21st century: Problems and forecasts. Can renewable energy source replace fossil fuels?, Russ. Chem. Rev. source
Not checked in the free run.
May combine two claims.
PremisecitationReduced GHG emissions would lead to a lower global temperature, which could both increase crop yield and the quality of crops grown.
“Reduced GHG emissions would lead to a lower global temperature, which could both increase crop yield and the quality of crops grown [56].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [56] Subramaniam, 2020, Biofuels, environmental sustainability and food security: A review of 51 countries, Energy Res. Soc. Sci. source
Not checked in the free run.
May combine two claims.
PremisecitationThe production and end use of biofuels comes with concerns of deforestation, biodiversity loss and increased fertilizer and pesticide use.
“Biofuels also have higher production costs in the current market due to requirement of more intensive processing procedures and, as with increased agriculture of any form, the production and end use of biofuels comes with concerns of deforestation, biodiversity loss and increased fertilizer and pesticide use [60].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [60] Webb, A., and Coates, D. (2012). Biofuels and Biodiversity. Secretariat of the Convention on Biological Diversity, Secretariat of the Convention on Biological Diversity.
Not checked in the free run.
May combine two claims.
PremisecitationBiofuels have both positive and negative effects on the economy, environment and public health.
“Biofuels have both positive and negative effects on the economy, environment and public health [52]; many studies suggest it is crucial that governments across the globe rigorously consider these impacts prior to any future biofuel investments or implementation strategies [53,54].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [52] Mizik, 2021, Economic and sustainability of biodiesel production- A systematic literature review, Clean Technol. source
Not checked in the free run.
May combine two claims.
InterpretationcitationSugarcane ethanol production in Brazil costs less than that in the US, and Brazil would benefit from using biofuel as an energy source.
“However, EROEI for the production of ethanol from sugarcane in Brazil is 5 to 10, suggesting sugarcane ethanol production in Brazil costs less than that in US [50,51] and Brazil would benefit with using biofuel as energy source.”
Quote in the paperSubstantial claim0 of 2 sources checkedMay combine two claims.
PremisecitationBrazilian biofuel production between 2005 and 2014 was estimated at 17.4 billion L, saving 12.9 billion US dollars in fossil fuel import costs.
“For instance, Brazilian biofuel production between 2005 and 2014 was estimated at 17.4 billion L, saving 12.9 billon US dollars in fossil fuel import costs [39].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [39] Coelho, 2017, History, evolution and environmental impact of biodiesel in Brazil: A review, Renew. Sust. Energ. Rev. source
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Probably not a substantial claim: may not pass S2 (checkable), S3 (load-bearing).
InterpretationcitationThe best approach may be a combination of resources to manage the increasing global demand.
“Instead of solely relying on one generation of biofuel, the best approach may be a combination of resources to manage the increasing global demand [48].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [48] Lee, 2013, From first- to third-generation biofuels: Challenges of producing a commodity from a biomass of increasing complexity, Anim. Front. source
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May combine two claims.
PremisecitationChallenges to commercialize the large-scale production of advanced biofuels include high cost of production and the need for improvement of current conversion technologies.
“However, there are challenges to commercialize the large-scale production of these advanced biofuels as the cost of production is high and the performance of current conversion technologies requires improvement [47,68].”
Quote in the paperNot a substantial claim0 of 2 sources checkedMay combine two claims.
PremisecitationAdditional benefits have been recognized when using microalgae as a feedstock, such as faster biomass production, high oil content and a capability to grow throughout the year in both natural and artificial environments.
“Additional benefits have been recognized when using microalgae as a feedstock, such as faster biomass production, high oil content and a capability to grow throughout the year in both natural and artificial environments [67].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [67] Sharma, 2020, Sustainable environmental management and related biofuel technologies, J. Environ. Manag. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationA considerable amount of research on biofuels as a renewable energy source is inconclusive and contradictory.
“A considerable amount of research on biofuels as a renewable energy source is inconclusive and contradictory [38][39][40][41].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [38][39][40][41]
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Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationRecent studies highlighted negative consequences of expanding first generation biofuel production further and argue for a greater effort on the production of advanced biofuels.
“Despite first generation biofuels being successfully implemented globally, recent studies highlighted negative consequences of expanding their production further and argue for a greater effort on the production of advanced biofuels [46][47][48].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [46][47][48]
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May combine two claims.
InterpretationreasoningA shift towards biofuel production would allow countries without large crude oil reserves to reduce both their dependence on fossil fuels and their import costs.
“In addition, not all countries have large crude oil reserves so a shift towards biofuel production would allow countries to reduce both their dependence on fossil fuels and, consequently, their import costs.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationCompared with diesel, biodiesel has a lower calorific value, higher NOx emissions, higher copper strip corrosion and fuel pumping difficulty.
“In spite of these benefits, several problems stand in the way of using biofuels as a replacement to fossil fuels, for example, comparing with diesel, biodiesel has a lower calorific value, higher NO x emissions, higher copper strip corrosion and fuel pumping difficulty [58,59].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [58] Agarwal, 2006, Experimental investigation of control of NOx emissions in biodiesel-fueled compression ignition engine, Renew. Energy source
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- cites [59] Demirbas, 2009, Progress and recent trends in biodiesel fuels, Energy Conv. Manag. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationBiofuels are often sold in the global market as blends with fossil fuels, in order to be compatible with conventional vehicle engines and reduce the need for additives.
“Biofuels are often sold in the global market as blends with fossil fuels, in order to be compatible with conventional vehicle engines and reduce the need for additives [43].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [43] Yusoff, 2020, Sustainability of Palm biodiesel in transportation: A review on biofuel standard, policy and international collaboration between Malaysia and Colombia, BioEnergy Res. source
Not checked in the free run.
May combine two claims.
InterpretationreasoningBiofuel production as an alternative to natural fossil fuel could destroy the natural ecosystem and violate the equilibrium of global biosphere processes.
“Biofuel production as an alternative of natural fossil fuel could destroy the natural ecosystem and violate the equilibrium of global biosphere processes.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based). May combine two claims.
Premisenone givenBrazil has successfully implemented public policies to increase biofuel consumption and in turn improve air quality.
“Brazil has successfully implemented public policies to increase biofuel consumption and in turn improve air quality.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationH-abstraction reaction can occur at different reaction sites along ethanol.
“Initially, this takes place via a H-abstraction reaction which can occur at different reaction sites along ethanol [96].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [96] Atkinson, 2006, IUPAC Subcommittee. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II- gas phase reactions of organic species, Atmos. Chem. Phys. source
Not checked in the free run.
May combine two claims.
PremisecitationAdding up all the biodiesel consumed in Brazil since 2008, the GHG avoided emissions have already reached 21.8 million tons of CO2, equivalent to nearly 158 million trees in an area corresponding to 144 thousand football fields.
“a recent report released by the Brazilian Department of Agriculture Livestock Supply states that by “adding up all the biodiesel consumed in Brazil since 2008, the GHG avoided emissions have already reached 21.8 million tons of CO 2 , which is equivalent to nearly 158 million trees in an area corresponding to 144 thousand football fields” [39,76].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [39] Coelho, 2017, History, evolution and environmental impact of biodiesel in Brazil: A review, Renew. Sust. Energ. Rev. source
Not checked in the free run.
- cites [76] Brazil Ministry of Agriculture, Livestock and Supply (2021, August 30). Benefícios Ambientais da Produção e do USO do Biodiesel. Brazil, Available online: https://ubrabio.com.br/sites/1800/1891/PDFs/BenefAciosAmbientaisdaProduAAoeUsodoBiod.pdf.
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May combine two claims.
PremisecitationInitial degradation of ethanol involves direct breakage of the C-C bond forming the hydroxymethyl radical, which reacts with oxygen or decomposes to produce formaldehyde.
“The initial degradation of ethanol involves the direct breakage of the C-C bond forming the hydroxymethyl radical, which either reacts with oxygen or decomposes in the atmosphere, to produce formaldehyde [95].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [95] Zhu, 2013, Effects of ethanol-biodiesel blend and diesel oxidation catalyst (DOC) on particulate and unregulated emissions, Fuel source
Not checked in the free run.
May combine two claims.
PremisecitationAlthough biofuels are still producing CO2, the carbon footprint is smaller as biomass feedstocks act as a carbon sink by absorbing CO2 for photosynthesis during crop growth.
“Although biofuels are still producing CO 2 , the carbon footprint is smaller as biomass feedstocks act as a carbon sink by absorbing CO 2 for photosynthesis during crop growth [40,75].”
Quote in the paperSubstantial claim0 of 2 sources checked- cites [40] Muhammad, 2018, Biofuels as the starring substitute to fossil fuels, Pet. Sci. Eng.
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- cites [75] Porqueras, 2012, Biofuels and CO2 neutrality: An opportunity, Biofuels source
Not checked in the free run.
May combine two claims.
PremisecitationDelaying fuel injection, addition of water in biofuel blends, and medium engine speed are potential ways to decrease NOx pollution.
“For instance, delaying fuel injection, addition of water in biofuel blends, and a medium engine speed are all potential ways to decrease NO x pollution [53,89,91].”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [53] AQEG (2021, August 30). Road Transport Biofuels: Impact on UK Air Quality, Available online: https://www.gov.uk/government/publications/road-transportbiofuels-impact-on-uk-air-quality.
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- cites [89] Tan, 2017, Engine performance and emissions characteristics of a diesel engine fueled with diesel-biodiesel-bioethanol emulsions, Energy Convers. Manag. source
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- cites [91] Gharehghani, 2019, Simulataneous reduction of CO and NOx emissions as well as fuel consumption by using water and nano particles in diesel-biodiesel blend, J. Clean. Prod. source
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May combine two claims.
PremisecitationThe higher oxygen content of ethanol and biodiesel compared with petrol and diesel leads to a more complete combustion and hence a decrease in particulate content and exhaust gas.
“The main explanation for these reduced emissions within literature is that the higher oxygen content of ethanol and biodiesel, compared with petrol and diesel [73,74], leads to a more complete combustion and hence a decrease in particulate content and exhaust gas [11].”
Quote in the paperSubstantial claim0 of 3 sources checked- cites [73] Varol, 2014, Comparison of methanol, ethanol, or n-butanol blending with unleaded gasoline on exhaust emissions of an SI engine. Energy Sources, Part A: Recovery, Util. Environ. Eff.
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- cites [74] Giakoumis, 2014, Assessment of NOx emissions during transient diesel engine operation with biodiesel blends, J. Energy Eng. source
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- cites [11] Arutyunov, 2017, Energy resource of the 21st century: Problems and forecasts. Can renewable energy source replace fossil fuels?, Russ. Chem. Rev. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
InterpretationcitationThe inconsistency between literature on biofuel emissions is understandable due to complexity of combustion and variation between studies such as engine type, vehicle age, fuel injection strategy and other conditions.
“This inconsistency between literature is understandable due to the complexity of combustion and the variation between different studies such as: engine type, vehicle age, fuel injection strategy and other conditions, which influence emissions [53,90].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [53] AQEG (2021, August 30). Road Transport Biofuels: Impact on UK Air Quality, Available online: https://www.gov.uk/government/publications/road-transportbiofuels-impact-on-uk-air-quality.
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- cites [90] Tabatabaei, 2018, A comprehensive review on the environmental impacts of diesel/biodiesel additives, Energy Convers. Manag. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationApproximately 85% of the abstraction occurs at the α-site of ethanol.
“Approximately 85% of the abstraction occurs at the α-site of ethanol.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [96] Atkinson, 2006, IUPAC Subcommittee. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II- gas phase reactions of organic species, Atmos. Chem. Phys. source
Not checked in the free run.
May combine two claims.
PremisecitationReaction with OH involves H-abstraction from the carbonyl carbon to form a peroxyacetyl radical which can react with NO2 to produce PAN.
“Reaction with OH involves H-abstraction from the carbonyl carbon to form a peroxyacetyl radical which can go on to react with NO 2 and produce PAN [98,99].”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [98] Tanner, 1988, Atmospheric chemistry of aldehydes: Enhanced peroxyacetyl nitrate formation from ethanol-fueled vehicular emissions, Environ. Sci. Technol. source
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- cites [99] Gaffney, 1997, Potential air quality effects of using ethanol-gasoline fuel blends: A field study in Albuquerque, New Mexico, Environ. Sci. Technol. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationShort-term O3 exposure is strongly associated with mortality across the world.
“with many also reporting a strong association with mortality across the world [86][87][88].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [86][87][88]
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Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationPAN is a key contributor to photochemical smog, typically in warm summer climates, causing eye irritation and respiratory issues.
“PAN is a key contributor to photochemical smog, typically in warm summer climates, which consequently causes eye irritation and respiratory issues [53].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [53] AQEG (2021, August 30). Road Transport Biofuels: Impact on UK Air Quality, Available online: https://www.gov.uk/government/publications/road-transportbiofuels-impact-on-uk-air-quality.
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationAccording to the Air Transport Action Group, a key part of the aviation sector's carbon-neutral growth strategy is the use of low-carbon, sustainable aviation fuels, which have bio-based components.
“According to the Air Transport Action Group, a key part of the aviation sector's carbon-neutral growth strategy is the use of low-carbon, sustainable aviation fuels, which have bio-based components [117].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [117] Kousoulidou, 2016, Biofuels in aviation: Fuel demand and CO2 emissions evolution in Europe toward 2030, Transp. Res. Part. D Transp. Environ. source
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Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Interpretationnone givenAn example of a potential environmental barrier could be the implications of land-use changes which may be required to grow sufficient amounts of biofuel feedstock to meet the demand.
“An example of a potential environmental barrier could be the implications of land-use changes which may be required to grow sufficient amounts of biofuel feedstock to meet the demand.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationA study by Jacobson showed that such a blend causes elevations in PAN and increases ozone-related mortality.
“A study undertaken by Jacobson [104] also showed that such a blend causes elevations in the levels of PAN, whilst also increasing ozone-related mortality.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [104] Jacobson, 2007, Effects of ethanol (E85) versus gasoline vehicles on cancer and mortality in the United States, Environ. Sci. Technol. source
Not checked in the free run.
May combine two claims.
PremisereasoningInvestigation into biomass feedstocks has presented issues associated with preparation, as many feedstocks are highly oxygenated, while jet fuels are required to be fully deoxygenated hydrocarbons.
“Investigation into biomass feedstocks has presented issues associated with preparation, as many feedstocks are highly oxygenated, while jet fuels are required to be fully deoxygenated hydrocarbons.”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisereasoningBefore the Fischer-Tropsch synthesis, the syngas must be purified and adjusted to ensure the syngas ratios of CO and H2 are appropriate for FT.
“Before the Fischer-Tropsch synthesis, the syngas must be purified and adjusted to ensure the syngas ratios of CO and H 2 are appropriate for FT.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationAviation fuel consumption currently accounts for 3% of the total global fossil fuels used.
“Consequently, aviation fuel consumption currently accounts for 3% of the total global fossil fuels used [116].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [116] Lee, 2010, Can we accelerate the improvement of energy efficiency in aircraft systems?, Energy Convers. Manag. source
Not checked in the free run.
May combine two claims.
PremisereasoningBiofuels must therefore involve chemical transformation to selectively remove oxygen and structural adjustments.
“Biofuels must therefore involve chemical transformation to selectively remove oxygen and structural adjustments.”
Quote in the paperSubstantial claimMay combine two claims.
PremisereasoningOther areas with higher ethanol mixing ratios include south-eastern U.S.A., East Asia (China) and South Asia (India).
“Other areas of the globe with higher ethanol mixing ratios include the south-eastern U.S.A., East Asia (areas of China) and South Asia (around India).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
Not checked in the free run.
May combine two claims.
InterpretationcitationThis application of biofuels is helping to remove harmful waste gases such as CO2, whilst simultaneously producing electricity which could later be used to power battery-driven vehicles in a non-polluting way.
“Therefore, this application of biofuels is helping to remove harmful waste gases such as CO 2 , whilst simultaneously producing electricity which could later be used to power battery-driven vehicles in a non-polluting way [113].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [113] Consoli, C. (2019). Bioenergy and Carbon Capture Storage, Global CCS Institute. Available online: http://www.globalccsinstitute.com/wp-content/uploads/2019/03/BECCS-Perspective_FINAL_PDF.pdf.
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationMany airlines are currently involved in research efforts to enable the implementation of these biofuels and reduce the carbon footprint of aviation.
“Many airlines are currently involved in research efforts to enable the implementation of these biofuels and reduce the carbon footprint of aviation [118].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [118] Mohsin, 2017, Assessment of Biofuels in Aviation Industry for Environmental Sustainability, Chem. Eng. Trans.
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationOnce synthesised, the crude product is processed, involving both cracking and separation techniques.
“Once synthesised, the crude product is processed, which involving both cracking and separation techniques [123].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [123] Blakey, 2011, Aviation gas turbine alternative fuels: A review, Proc. Combust. Inst. source
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Probably not a substantial claim: may not pass S4 (based). May combine two claims.
Interpretationnone givenBiofuel use in road transportation alone is unlikely to reduce GHG emissions sufficiently to achieve the Paris Agreement climate target, hence a wider application across the transport sector is necessary.
“Biofuel use in road transportation alone is unlikely to reduce GHG emissions sufficiently to achieve the Paris Agreement climate target, hence a wider application across the transport sector is necessary.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisereasoningAlthough this technique is well-developed, the specific composition of the gas stream is hard to control as impurities may be present in the feedstock, these include N2, chlorine (Cl) and tar.
“Although this technique is well-developed, the specific composition of the gas stream is hard to control as impurities may be present in the feedstock, these include N 2 , chlorine (Cl) and tar.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationThe demand for conventional aviation fuels will continue to grow to 860 Mt/year by 2050, which is more than 4 times the demand observed in 2010.
“It is currently estimated that the demand for conventional aviation fuels (CAF), such as Jet A and Jet A-1 (comprise of 20% naphthalene, 20% paraffins, 40% iso-paraffins and 20% aromatic compounds from the crude distillate), will continue to grow to 860 Mt/year by 2050, which is more than 4 times the demand observed in 2010 [115].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [115] Chiaramonti, 2019, Sustainable Aviation Fuels: The challenge of decarbonization, Energy Procedia source
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May combine two claims.
PremisecitationThe aviation industry emits approximately 700 million tonnes of CO2 eq and is accountable for almost 12% of transportation emissions worldwide.
“The aviation industry emits approximately 700 million tonnes of CO 2 eq and is accountable for almost 12% of transportation emissions worldwide [114].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [114] Chuck, C. (2016). Biofuels for Aviation: Feedbacks, Technology and Implementation, Academic Press.
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May combine two claims.
InterpretationcitationThis increases the cost and time of this process, which poses a problem for commercial-scale implementation.
“This increases the cost and time of this process, which poses a problem for commercial-scale implementation [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based). May combine two claims.
Premisenone givenThe FT reaction has been extensively studied, and it has been shown FT-SPK produced contains a high concentration of long chain paraffins, both branched and unbranched, which are produced from syngas in the presence of iron or cobalt catalysts.
“The FT reaction has been extensively studied, and it has been shown FT-SPK produced contains a high concentration of long chain paraffins, both branched and unbranched, which are produced from syngas in the presence of iron or cobalt catalysts.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationPalm oil and many crops obtained from deforestation are not encouraged as these cause further environmental damage in different sectors.
“Palm oil and many crops obtained from deforestation are not encouraged as these cause further environmental damage in different sectors [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
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May combine two claims.
PremisecitationJet fuel alternatives must be utilised at low temperatures and display high energy density to supply the energetic demand of long-haul flights, properties which biodiesels do not display.
“Jet fuel alternatives (e.g., fuels derived from biomass) must also be utilised at low temperatures and also display high energy density to supply the energetic demand of long-haul flights, properties which biodiesels do not display [120].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
May combine two claims.
PremisecitationPhotolysis yields HCO and CH3 radicals, where HCO instantly forms HO2 radicals on reaction with O2.
“Photolysis yields HCO and CH 3 radicals, where HCO instantly forms HO 2 radicals on reaction with O 2 .”
Quote in the paperNot a substantial claim0 of 3 sources checked- cites [100] Khan, 2015, The global atmospheric budget and distribution of acetone using the 3-D global model, STOCHEM-CRI, Atmos. Environ. source
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- cites [101] Khan, 2017, Global budget and distribution of peroxyacetyl nitrate (PAN) for present and preindustrial scenarios, Int. J. Earth Environ. Sci. source
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- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
Not checked in the free run.
May combine two claims.
PremisecitationIn 2018, aviation biofuel production was around 15 million L, which accounted for under 0.1% of total aviation fuel consumption.
“In 2018, aviation biofuel production was around 15 million L, which accounted for under 0.1% of total aviation fuel consumption [119].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [119] Le Feuvre, P. (2019). Are Aviation Biofuels Ready for Take-Off?, IEA. Available online: https://www.iea.org/commentaries/are-aviation-biofuels-ready-for-take-off.
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe gasification process requires conversion of biomass feedstock lignocellulose into syngas under high-temperature conditions while controlling the oxidant species present.
“The gasification process requires conversion of biomass feedstock lignocellulose into syngas under high-temperature conditions while controlling the oxidant species present [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationCurrently, there are many alternative fuels suggested that could help decarbonise the aviation industry and thus reduce the environmental impact of the sector.
“Currently, there are many alternative fuels suggested that could help decarbonise the aviation industry and thus reduce the environmental impact of the sector [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
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May combine two claims.
PremisecitationKhan et al. showed that an increased emission flux (~11.5 Tg/year) of ethanol as a biofuel and from vegetation can cause an increment of acetaldehyde by up to 30% in areas such as Brazil, Australia and Indonesia, which led to an increase in PAN (by up to 3%) over the ocean near to acetaldehyde source regions.
“Khan et al. [102] showed that an increased emission flux (~11.5 Tg/year) of ethanol as a biofuel and from vegetation can cause an increment of acetaldehyde by up to 30% in areas such as Brazil, Australia and Indonesia (Figure 5a) which led to an increase in PAN (by up to 3%) over the ocean near to acetaldehyde source regions (Figure 5b).”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [102] Khan, 2017, An estimate of the global budget and distribution of ethanol using a global 3-D atmospheric chemistry transport model STOCHEM-CRI, Trans. Royal Soc. S. Afr. source
Not checked in the free run.
May combine two claims.
PremisecitationThe Drax power station in the U.K. has recently converted four of its six generating units from coal to wood pellets and operates carbon capture and storage (CCS) technologies alongside power generation.
“For example, the Drax power station in the U.K. has recently converted four of its six generating units from coal to wood pellets and operates carbon capture and storage (CCS) technologies alongside power generation [112].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [112] Clayton, 2019, Drax group’s bioenergy CCS (BECCS) project, Greenh. Gas. Sci. Technol. source
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Probably not a substantial claim: may not pass S2 (checkable), S3 (load-bearing).
Premisenone givenTo be sustainable, BAF must be produced from sustainable feedstocks.
“To be sustainable, BAF must be produced from sustainable feedstocks.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationBiomass Alternative Fuels (BAF) are synthetic paraffinic kerosene's (SPK) which can be blended with CAF.
“Biomass Alternative Fuels (BAF) are synthetic paraffinic kerosene's (SPK) which can be blended with CAF [121].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [121] Doliente, 2020, Bio-aviation fuel: A comprehensive review and analysis of the supply chain components, Front. Energy Res. source
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Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationSnåre et al. further investigated this catalytic reactivity, identifying a greater variety of catalysts that could be used for deoxygenation processes, including Pd/C.
“Snåre et al. [130] further investigated this catalytic reactivity, identifying a greater variety of catalysts that could be used for deoxygenation processes, including Pd/C.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [130] Murzin, 2006, Heterogeneous catalytic deoxygenation of stearic acid for production of biodiesel, Ind. Eng. Chem. Res. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationAs algae are known to have a high yield production and function at low water and fertilizer concentrations, this could be a cost-effective solution.
“As algae are known to have a high yield production and function at low water and fertilizer concentrations, this could be a cost-effective solution [137].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [137] Fortier, 2014, Life cycle assessment of bio-jet fuel from hydrothermal liquefaction of microalgae, Appl. Energy source
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May combine two claims.
PremisecitationAlthough often camelina crops are grown in rotation with wheat crops, where land would otherwise be left to refresh itself, this still presents a problem as the feedstock would only be available seasonally.
“Although often camelina crops are grown in rotation with wheat crops, where land would otherwise be left to refresh itself, this still presents a problem as the feedstock would only be available seasonally [132].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [132] Ruiz, 2013, Biodiesel from Camelina sativa: A comprehensive characterization, Fuel source
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Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThis employed the use of Grubb's catalyst for the alkene cross-metathesis and Pt/ZSM-22 catalyst for hydrodeoxygenation.
“This employed the use of Grubb's catalyst for the alkene cross-metathesis and Pt/ZSM-22 catalyst for hydrodeoxygenation.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [131] Wang, 2018, Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating, Biotechnol. Biofuels source
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Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationCurrently, only iso-butanol and ethanol are used in ATJ-SPK processes, but future development hopes to incorporate all C2-C5 alcohols in the production process.
“Currently, only iso-butanol and ethanol are used in ATJ-SPK processes, but, future development hopes to incorporate all C2-C5 alcohols in the production process [122].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [122] Yang, 2019, An overview on performance characteristics of bio-jet fuels, Fuel source
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Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenThese free fatty acid chains must be catalytically deoxygenated through hydrodeoxygenation reactions or decarboxylation reactions resulting in long linear alkanes.
“These free fatty acid chains must be catalytically deoxygenated through hydrodeoxygenation reactions or decarboxylation reactions resulting in long linear alkanes, as seen in Scheme 2”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThis occurred in the presence of either N2 or H2 providing less stringent reactive components with a greater extent of carboxylation under N2 atmosphere.
“This occurred in the presence of either N 2 or H 2 providing less stringent reactive components with a greater extent of carboxylation under N 2 atmosphere.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [129] Takemura, 1985, Catalytic decarboxylation of benzoic acid, Ind. Eng. Chem. Prod. Res. Dev. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
InterpretationcitationDevelopment into these conditions could increase the number of aromatic components produced this way.
“Development into these conditions could increase the number of aromatic components produced this way [135].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [135] Verma, 2015, Diesel and aviation kerosene with desired aromatics from hydroprocessing of Jatropha oil over hydrogenation catalysts supported on hierarchical mesoporous SAPO-11, Appl. Catal. A source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenβ-farnesene is typically produced from sugarcane and lignocellulosic biomass.
“The structure of β-farnesene and is displayed in Scheme 3 and typically is produced from sugarcane and lignocellulosic biomass.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenSeveral reports have detailed the potential use of waste cooking oils in the formation of alternative jet fuels.
“As environmental conscience has increased, several reports have detailed the potential use of waste cooking oils in the formation of alternative jet fuels.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationResearch conducted by Wang et al. reported an efficient 4-step conversion method for synthesising HEFA-SPK.
“Research conducted by Wang et al. [131] reported an efficient 4-step conversion method for synthesising HEFA-SPK.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [131] Wang, 2018, Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating, Biotechnol. Biofuels source
Not checked in the free run.
Classified as probably not a substantial claim. May combine two claims.
PremisecitationThese steps include enzyme transesterification, catalytic transfer hydrogenation, alkene cross-metathesis and catalytic hydrodeoxygenation.
“These steps include enzyme transesterification, catalytic transfer hydrogenation, alkene cross-metathesis and catalytic hydrodeoxygenation.”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [131] Wang, 2018, Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating, Biotechnol. Biofuels source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationThe formation of aromatic paraffins is important for use in jet fuels as they contribute to ensuring valves in engine systems are sealed properly by promoting swelling of the valve.
“The formation of aromatic paraffins is important for use in jet fuels as they contribute to ensuring valves in engine systems are sealed properly by promoting swelling of the valve [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
May combine two claims.
PremisecitationThis method was highly efficient and provided a more economically feasible solution compared with previously reported hydrotreatment processes.
“This method was highly efficient and provided a more economically feasible solution compared with previously reported hydrotreatment processes.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [131] Wang, 2018, Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating, Biotechnol. Biofuels source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationThe literature has reported promising results from the vegetable oils processed into jet fuels, with many reports indicating these fuels have been already blended with CAF to power commercial jets.
“The literature has reported promising results from the vegetable oils processed into jet fuels, with many reports indicating these fuels have been already blended with CAF to power commercial jets [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationTakemura et al. reported Ni and Pd catalysts with aluminium supports were useful for forming aromatic paraffins, particularly through decarboxylation of benzoic acid in a batch autoclave.
“Takemura et al. [129] reported Ni and Pd catalysts with aluminium supports were useful for forming aromatic paraffins, particularly through decarboxylation of benzoic acid in a batch autoclave.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [129] Takemura, 1985, Catalytic decarboxylation of benzoic acid, Ind. Eng. Chem. Prod. Res. Dev. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenTypically, highly oxygenated sugar molecules, containing OH, CO and COOH groups, have a carbon number of 6.
“Typically, highly oxygenated sugar molecules, containing OH, CO and COOH groups, have a carbon number of 6.”
Quote in the paperNot a substantial claimMay combine two claims.
InterpretationcitationThis process uses an expensive feedstock and the production of the fuel is a high energy process, implantation of HFS-SIP fuels on a commercial scale would be extremely costly.
“Nevertheless, this process uses an expensive feedstock and the production of the fuel is a high energy process, implantation of HFS-SIP fuels on a commercial scale would be extremely costly [138].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [138] Bauen, 2020, Sustainable aviation fuels, Johns. Matthey Technol. Rev. source
Not checked in the free run.
Probably not a substantial claim: may not pass S1 (asserted), S3 (load-bearing).
PremisecitationReports have recommended that the cost of production could be reduced if propane, produced during the hydroprocessing stage, was sold back to for use in industry.
“Additionally, reports have recommended that the cost of production could be reduced if propane, produced during the hydroprocessing stage, was sold back to for use in industry [136].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [136] Caballero, 2017, Microbial alkane production for jet fuel industry: Motivation, state of the art and perspectives, Microb. Biotechnol. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenFurther research has been conducted recently in processing fatty acids into aromatics and cycloalkanes, components also present in CAF.
“Further research has been conducted recently in processing fatty acids into aromatics and cycloalkanes, components also present in CAF.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
InterpretationcitationThe abundance of catalysts available for this process give the potential for mass implementation of these routes within the biofuel aviation industry.
“The abundance of catalysts available for this process give the potential for mass implementation of these routes within the biofuel aviation industry.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing).
PremisecitationConversion of alcohol to jet synthetic paraffinic kerosene involves three key steps involving dehydration to remove heteroatom oxygen to produce alkenes, oligomerisation to increase the carbon chain length of the alkenes and finally hydrogenation to produce the unsaturated long chain alkanes.
“Conversion of alcohol to jet synthetic paraffinic kerosene involves three key steps involving dehydration to remove heteroatom oxygen to produce alkenes, oligomerisation to increase the carbon chain length of the alkenes and finally hydrogenation to produce the unsaturated long chain alkanes [125].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [125] 2017, A review on the production processes of renewable jet fuel, Renew. Sustain. Energy Rev. source
Not checked in the free run.
May combine two claims.
PremisecitationBoth ethanol and iso-butanol are easily dehydrated in the presence of acid catalysts such as silica-alumina and at moderate temperatures, e.g., 250 °C and 325 °C, respectively.
“Both ethanol and iso-butanol are easily dehydrated in the presence of acid catalysts such as silica-alumina and at moderate temperatures, e.g., 250 °C and 325 °C, respectively [140].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [140] Hu, 2010, Selective dehydration of bio-ethanol to ethylene catalyzed by lanthanum-phosphorous-modified HZSM-5: Influence of the fusel, Biotechnol. J. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
Premisenone givenSugar molecules have also been reported as potential feedstocks for production of alternative fuels.
“Sugar molecules have also been reported as potential feedstocks for production of alternative fuels.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationA wide range of vegetable oil feedstocks have been reported, including camelina, canola rapeseed, soybean and jatropha oils, although production of jet fuels utilising these oils is controversial as the production is not entirely sustainable.
“Furthermore, a wide range of vegetable oil feedstocks have been reported, these include camelina, canola rapeseed, soybean and jatropha oils, although production of jet fuels utilising these oils is controversial as the production is not entirely sustainable [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing). May combine two claims.
PremisecitationAs a non-edible crop, camelina possesses a high oil content, but growing this crop purely for oil uses poses a question regarding feedstock availability and land use concerns.
“As a non-edible crop, camelina possesses a high oil content, but, growing this crop purely for oil uses poses a question regarding feedstock availability and land use concerns [120].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
May combine two claims.
PremisecitationHydrogenation of β-farnesene produces farnesane which is an alkane which has displayed potential as a high energy density alternative fuel option.
“Hydrogenation of β-farnesene produces farnesane which is an alkane which has displayed potential as a high energy density alternative fuel option [139].”
Quote in the paperSubstantial claim0 of 1 sources checked- cites [139] Liu, 2018, Renewable production of high density jet fuel precursor sesquiterpenes from Escherichia coli, Biotechnol. Biofuels source
Not checked in the free run.
May combine two claims.
PremisecitationExtraction of sugars from non-edible lignocellulosic feedstocks requires several processing stages and is costly because the lignin structure must be weakened before extraction.
“Extraction of sugars from non-edible feedstocks, namely lignocellulose, require several stages of processing and poses a problem as the structure of the lignin surrounding the cellulose must be weakened before extraction which is a costly process [125].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [125] 2017, A review on the production processes of renewable jet fuel, Renew. Sustain. Energy Rev. source
Not checked in the free run.
May combine two claims.
PremisecitationIso-butanol has lower water absorption and higher energy density than ethanol, but its energy density is still much lower than CAF.
“iso-butanol has a lower water absorption and higher energy density than ethanol, however, it is still much lower than CAF [142].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [142] Wang, W., Tao, L., Markham, J., Zhang, Y., Tan, E., Batan, L., Biddy, M., Wang, W.-C., Tao, L., and Zhang, Y. (2021, August 30). Review of Biojet Fuel Conversion Technologies, Available online: https://www.nrel.gov/docs/fy16osti/66291.pdf.
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing).
Interpretationnone givenThe impact of aviation biofuels on other environmental factors such as biodiversity and air quality remains uncertain.
“However, the impact of aviation biofuels on other environmental factors, such as biodiversity and air quality remains uncertain and requires further investigation.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationEthanol cannot be used directly in aircraft engines due to high volatility, high water absorption, and much lower energy density than CAF.
“Ethanol, in particular, cannot be used directly in aircraft engines due to its high volatility, high water absorption and a much lower energy density than CAF”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [142] Wang, W., Tao, L., Markham, J., Zhang, Y., Tan, E., Batan, L., Biddy, M., Wang, W.-C., Tao, L., and Zhang, Y. (2021, August 30). Review of Biojet Fuel Conversion Technologies, Available online: https://www.nrel.gov/docs/fy16osti/66291.pdf.
Not checked in the free run.
Probably not a substantial claim: may not pass S4 (based). May combine two claims.
Interpretationnone givenHFS-SIP fuels provide a simple direct sugar-to-hydrocarbon process employing microorganisms and avoiding multi-step processing.
“HFS-SIP fuels provide a simple direct sugar-to-hydrocarbon process employing microorganisms and avoiding multi-step processing.”
Quote in the paperNot a substantial claimMay combine two claims.
InterpretationreasoningUse of i-butanol as a global biofuel will result in significant emissions into the atmosphere, and its subsequent transport and degradation are likely to impact atmospheric composition.
“Thus, the use of i-butanol as a global biofuel will result in significant emissions into the atmosphere, with its subsequent transport and degradation likely to impact atmospheric composition.”
Quote in the paperSubstantial claimClassified as probably not a substantial claim.
Interpretationnone givenThe success of biofuels as a renewable energy source can be determined by factors such as geographical region, climate, economic infrastructure, and feedstock used.
“A variety of factors can determine the success of biofuels as a renewable energy source, such as the geographical region and climate, economic infrastructure and the feedstock used in biofuel production.”
Quote in the paperSubstantial claimProbably not a substantial claim: may not pass S4 (based).
Interpretationnone givenAdvanced biofuels, particularly algae-derived, have a strong capability to replace fossil fuels without causing food insecurity and biodiversity loss.
“Advanced biofuels, particularly those derived from algae, have a strong capability to replace fossil fuels without giving rise to negative effects such as food insecurity and biodiversity loss.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationThe OH radical reaction with i-butanol has competing pathways leading to different stable end products and potentially different impacts on atmospheric composition.
“There are a number of competing pathways by which this reaction can proceed, thus leading to the formation of different stable end product(s) (see Figure 6) and potentially, different impacts on atmospheric composition.”
Quote in the paperNot a substantial claim0 of 2 sources checked- cites [143] McGillen, 2013, Gas-Phase Rate Coefficients for the OH plus n-, i-, s- and t-Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behaviour and Site-Specific Reactivity, J. Phys. Chem. A source
Not checked in the free run.
- cites [144] McGillen, 2016, Experimentally Determined Site-Specific Reactivity of the Gas-Phase OH and Cl plus i-Butanol Reactions Between 251 and 340 K, J. Phys. Chem. A source
Not checked in the free run.
May combine two claims.
PremisecitationExtraction of sugars from non-edible feedstocks, namely lignocellulose, require several stages of processing and poses a problem as the structure of the lignin surrounding the cellulose must be weakened before extraction which is a costly process.
“Extraction of sugars from non-edible feedstocks, namely lignocellulose, require several stages of processing and poses a problem as the structure of the lignin surrounding the cellulose must be weakened before extraction which is a costly process [125].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [125] 2017, A review on the production processes of renewable jet fuel, Renew. Sustain. Energy Rev. source
Not checked in the free run.
Probably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Interpretationnone givenAlterations in fuel composition from biofuels could have a significant impact on atmospheric chemistry.
“Alas, these alterations in fuel composition could have a significant impact on atmospheric chemistry.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S3 (load-bearing), S4 (based).
Premisenone givenWith edible feedstocks, sugar cane and corn, extraction of sugar is relatively simple and requires only hot water treatment.
“With edible feedstocks, sugar cane and corn, extraction of sugar is relatively simple and requires only hot water treatment.”
Quote in the paperNot a substantial claimProbably not a substantial claim: may not pass S4 (based).
Interpretationnone givenATJ-SPK and HEFA-SPK fuels provide a synthetic method for producing aromatic hydrocarbons, whereas other mentioned fuel alternatives cannot.
“Although, ATJ-SPK and HEFA-SPK fuels do provide a synthetic method for producing aromatic hydrocarbons, whereas other fuel alternatives mentioned currently cannot.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationAlgae feedstocks provide a cost-effective solution to biofuel growth due to minimal water and fertilizer requirements, but commercial-scale production is problematic.
“Algae feedstocks provide a cost-effective solution to biofuel growth, due to minimal water and fertilizer requirements, but, problems emerge with producing the feedstock on a commercial scale [151].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [151] Yaakob, 2015, Aviation biofuel from renewable resources: Routes, opportunities and challenges, Renew. Sustain. Energy Rev. source
Not checked in the free run.
May combine two claims.
Interpretationnone givenAlternative aviation fuel solutions reduce emissions but do not completely prevent them.
“Although the solutions reduce emissions, they do not completely prevent them.”
Quote in the paperSubstantial claimMay combine two claims.
PremisecitationIncreased demand for biofuels for aviation decarbonisation could lead to deforestation, affecting soil fertility and decreasing biodiversity in forested regions.
“Decarbonisation of the aviation industry relies heavily on biofuels; however, this increase in demand could lead to deforestation which affects soil fertility and can decrease biodiversity in forested regions [146].”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [146] Wang, 1980, Greenhouse effects due to man-made perturbations of trace gases, J. Atmos. Sci. source
Not checked in the free run.
Probably not a substantial claim: may not pass S4 (based). May combine two claims.
InterpretationreasoningGreater production of advanced biofuels is likely to have a positive impact on the global economy and help mitigate climate change.
“A greater production of these fuels is likely to have a positive impact on the global economy and help to mitigate climate change.”
Quote in the paperNot a substantial claimMay combine two claims.
PremisecitationATJ-SPK implementation is at the beginning stage of development, particularly focusing on iso-butanol, which can produce aromatic paraffins required in jet fuel.
“The implementation of ATJ-SPK is at the beginning stage of development, particularly focusing on iso-butanol, as it can also be employed to produce aromatic paraffins which are also a required component of jet fuel.”
Quote in the paperNot a substantial claim0 of 1 sources checked- cites [120] Díaz-Pérez, M.A., and Serrano-Ruiz, J.C. (2020). Catalytic production of jet fuels from biomass. Molecules, 25. source
Not checked in the free run.
May combine two claims.
Interpretationnone givenHFS-SIP provides a costly route to producing biofuels, and commercial implementation would cost more than continuing with CAF.
“However, this provides a costly route to producing biofuels and commercial implementation would come at a higher cost than continuing with CAF.”
Quote in the paperNot a substantial claim
The paper relies on this without support.
Biofuels can be used within current infrastructures.
“Biofuels are arguably a potential renewable energy source in the transportation industry as they can be used within current infrastructures and require less technological advances than other renewable alternatives, such as electric vehicles and nuclear power.”
“In addition, biofuels can be used within current infrastructures and require less technological advances compared with other energy sources.”
The paper relies on this without support.
Biofuels require less technological advances compared with other energy sources.
“Biofuels are arguably a potential renewable energy source in the transportation industry as they can be used within current infrastructures and require less technological advances than other renewable alternatives, such as electric vehicles and nuclear power.”
“In addition, biofuels can be used within current infrastructures and require less technological advances compared with other energy sources.”
The paper relies on this without support.
Global demand for biofuels is projected to increase.
“As global demand for biofuels is projected to increase, it is essential to understand the consequences of using these fuels.”
The paper relies on this without support.
There is a strong agreement amongst scholars that a shift towards advanced biofuels is needed.
“However, as there is a strong agreement amongst scholars that a shift towards advanced biofuels is needed, it seems necessary to compare the emission properties and air quality impact of these different biofuel generations.”
The paper relies on this without support.
The first flight to use a biofuel blend was in 2008 and since then over 150,000 flights using biofuels have taken place.
“The first flight to use a biofuel blend was in 2008 and since then over 150,000 flights using biofuels, have taken place.”
The paper relies on this without support.
Both FT-SPK and HEFA-SPK have already been implemented in 50:50 blends with kerosene-type fuels and used commercially in aircraft.
“Both FT-SPK and HEFA-SPK, have already been implemented in 50:50 blends with kerosene-type fuels and used commercially in aircraft.”
The paper relies on this without support.
The use of non-edible jatropha oil coupled with Ni catalysts at high temperatures led to a production of 8% aromatic content.
“The use of non-edible jatropha oil coupled with Ni catalysts at high temperatures led to a production of 8% aromatic content.”
The paper relies on this without support.
The method of extracting sugars initially provides some difficulty.
“However, the method of extracting sugars initially provides some difficulty.”
The paper relies on this without support.
With edible feedstocks, sugar cane and corn, extraction of sugar is relatively simple and requires only hot water treatment.
“With edible feedstocks, sugar cane and corn, extraction of sugar is relatively simple and requires only hot water treatment.”
The paper relies on this without support.
Ethanol cannot be used directly in aircraft engines due to its high volatility, high water absorption and a [cut off].
“Ethanol, in particular, cannot be used directly in aircraft engines due to its high volatility, high water absorption and a”
The paper relies on this without support.
Butanol's energy density and chemical structure are much closer to gasoline than ethanol, overcoming miscibility issues associated with bioethanol.
“The energy density and chemical structure of butanol is much closer to gasoline, thus overcoming miscibility issues associated with bioethanol.”
The paper relies on this without support.
i-Butanol burns more cleanly (contains around 22% oxygen) and is far less corrosive than ethanol, allowing shipment through existing infrastructure.
“It also burns more cleanly (containing around 22% oxygen) and is far less corrosive than ethanol, meaning that it can be shipped and distributed through existing infrastructure.”
The paper relies on this without support.
PAN enables long-range transport of NOx away from primary sources and thermally decomposes to release NOx into the remote troposphere.
“PAN enables the long-range transport of NO x , away from primary sources and then thermally decomposes to release NO x into the remote troposphere.”
The paper relies on this without support.
There is a significant price difference between BAF and CAF.
“First, there is still a significant price difference between BAF and CAF.”
The paper relies on this without support.
Many biofuel processes require catalysts, and designing and selecting catalysts to improve cost-effectiveness is costly.
“Many processes discussed also require catalysts, the design and selection of catalysts to improve cost-effectiveness is in itself a costly process.”
The paper relies on this without support.
Algae growth requires stringent temperature conditions, which presents a problem.
“Additionally, stringent temperature requirements are needed for algae growth which presents a problem.”
The paper relies on this without support.
Fuel efficiencies of alternative fuels are still largely undefined.
“Furthermore, fuel efficiencies of alternative fuels are still largely undefined”
The paper relies on this without support.
BAF must be compatible with CAF because they are currently blended in aircraft.
“Finally, BAF must be compatible with CAF as they are currently blended when used in aircraft.”
The paper relies on this without support.
First-generation biofuels raise issues of food security and production that can increase poverty levels and harm the economy, particularly in developing countries.
“This is particularly important in developing countries as first-generation biofuels raise issues of food security and production which can increase poverty levels and harm the economy.”
The paper relies on this without support.
Commercialisation of advanced biofuels faces challenges because production costs are very high and conversion technologies need improvement.
“However, there are current challenges with commercialisation of advanced biofuels as their production costs are very high and conversion technologies need improvement.”
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Algae-based biofuels have gained popularity because of the high lipid content of microalgae, which may lead to biodiesel production.
“Furthermore, algae-based biofuels have gained popularity because of the high lipid content of microalgae, which may lead to biodiesel production.”
From Biofuel production: exploring renewable energy solutions for a greener future (2024) · cites this paper as [83]
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
Each contradiction between two passages listed here was confirmed by an independent check.
FT-SPK is described as both branched and exclusively linear
MajorThe paper says FT-SPK contains both branched and unbranched paraffins, but later says the FT-SPK process produces only linear hydrocarbons.
“FT-SPK produced contains a high concentration of long chain paraffins, both branched and unbranched”
“This presents an advantage over FT-SPK, as this process only produces saturated linear hydrocarbons [120].”
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Introduction to Biofuel Production: A Step Towards Sustainable Energy
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- Authors
- Khan, M. A. H., Bonifacio, S., Clowes, J., Foulds, A., Holland, R., Matthews, J. C., Percival, C. J., & Shallcross, D. E.
- Affiliations
- University of Bristol (GB)
- University of Manchester (GB)
- Jet Propulsion Laboratory (US)
- Corresponding author
- Shallcross, Dudley E.
- ORCID
- Venue
- Atmosphere
- Publisher
- MDPI AG
- Published
- 2021-10-03
- Volume
- 12
- Issue
- 10
- Pages
- 1289
- ISSN
- 2073-4433 (ISSN-L)
- OpenAlex
- W3204882063
- Cited by
- 140
- References
- 130
- Citations by year
- 2026: 29 · 2025: 32 · 2024: 42 · 2023: 25 · 2022: 11 · 2021: 1
- FWCI
- 8.09
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Atmosphere (publishedVersion, cc-by)
- Explore Bristol Research (submittedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- UWC Research Repository (University of the Western Cape) (submittedVersion)
- Funders
- Natural Environment Research Council (NE/K004905/1)
- Topics
- Physical Sciences › Environmental Science › Global and Planetary Change › Advanced Aircraft Design and Technologies
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Advanced Combustion Engine Technologies
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Keywords
- biofuels, renewable energy, transportation fuels, aviation biofuels, advanced biofuels, biofuel emissions, nitrogen oxides, particulate matter, food security, biofuel feedstock, ozone, climate change impacts, kerosene replacement, fuel blends, production costs
About these checks
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