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Use of Reverse Osmosis Membranes to Remove Perfluorooctane Sulfonate (PFOS) from Semiconductor Wastewater

Tang, Chuyang Y., Fu, Q. Shiang, Robertson, A. P., Criddle, Craig S., Leckie, James O.·2006·Environmental Science & Technology

Abstract

Perfluorooctane sulfonate (PFOS) and related substances are persistent, bioaccumulative, and toxic, and thus of substantial environmental concern. PFOS is an essential photolithographic chemical in the semiconductor industry with no substitutes yet identified. The industry seeks effective treatment technologies. The feasibility of using reverse osmosis (RO) membranes for treating semiconductor wastewater containing PFOS has been investigated. Commercial RO membranes were characterized in terms of permeability, salt rejection, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and membrane surface zeta potential (streaming potential measurements). Filtration tests were performed to determine the membrane flux and PFOS rejection. Over a wide range of feed concentrations (0.5 - 1500 ppm), the RO membranes generally rejected 99% or more of the PFOS. Rejection was better for tighter membranes, but was not affected by membrane zeta potential. Flux decreased with increasing PFOS concentration. While the flux reduction was severe for a loose RO membrane probably due to its higher initial flux, very stable flux was maintained for tighter membranes. At a very high feed concentration (about 500 ppm), all the membranes exhibited an identical stable flux. Isopropyl alcohol, present in some semiconductor wastewaters, had a detrimental effect on membrane flux. Where present it needs to be removed from the wastewater prior to using RO membranes.

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Research works printed but not linked: 18

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Metadata

Authors
Tang, C. Y., Fu, Q. S., Robertson, A. P., Criddle, C. S., & Leckie, J. O.
Venue
Environmental Science & Technology
Published
2006-10-05
Volume
40
Issue
23
Pages
7343-7349
ISSN
  • 0013-936X (ISSN-L)
  • 1520-5851
OpenAlex
W2009809824
Cited by
422
References
2
FWCI
13.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Use of Reverse Osmosis Membranes to Remove Perfluorooctane Sulfonate (PFOS) from Semiconductor Wastewater. https://app.cochat.ai/papers/10.1021/es060831q
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Tang, C. Y., Fu, Q. S., Robertson, A. P., Criddle, C. S., & Leckie, J. O. (2006). Use of Reverse Osmosis Membranes to Remove Perfluorooctane Sulfonate (PFOS) from Semiconductor Wastewater. Environmental Science & Technology. https://doi.org/10.1021/es060831q

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