The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Hydrogen Generation in Microbial Reverse-Electrodialysis Electrolysis Cells Using a Heat-Regenerated Salt Solution
Abstract
Hydrogen gas can be electrochemically produced in microbial reverse-electrodialysis electrolysis cells (MRECs) using current derived from organic matter and salinity-gradient energy such as river water and seawater solutions. Here, it is shown that ammonium bicarbonate salts, which can be regenerated using low-temperature waste heat, can also produce sufficient voltage for hydrogen gas generation in an MREC. The maximum hydrogen production rate was 1.6 m(3) H(2)/m(3)·d, with a hydrogen yield of 3.4 mol H(2)/mol acetate at a salinity ratio of infinite. Energy recovery was 10% based on total energy applied with an energy efficiency of 22% based on the consumed energy in the reactor. The cathode overpotential was dependent on the catholyte (sodium bicarbonate) concentration, but not the salinity ratio, indicating high catholyte conductivity was essential for maximizing hydrogen production rates. The direction of the HC and LC flows (co- or counter-current) did not affect performance in terms of hydrogen gas volume, production rates, or stack voltages. These results show that the MREC can be successfully operated using ammonium bicarbonate salts that can be regenerated using conventional distillation technologies and waste heat making the MREC a useful method for hydrogen gas production from wastes.
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“Pt-based materials have been the most effective cathode catalysts for MECs;7”
From A 3D hybrid of layered MoS 2 /nitrogen-doped graphene nanosheet aerogels: an effective catalyst for hydrogen evolution in microbial electrolysis cells (2014) · cites this paper as [7]
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Cites
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Microbial Electrolysis Cells for High Yield Hydrogen Gas Production from Organic Matter
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Self-citationA novel ammonia—carbon dioxide forward (direct) osmosis desalination process
McCutcheon, J. R., McGinnis, R. L., & Elimelech, M. (2005) · Desalination · doi:10.1016/j.desal.2004.11.002 · Cited by 978
Hydrogen Production in a Single Chamber Microbial Electrolysis Cell Lacking a Membrane
Call, D. F., & Logan, B. E. (2008) · Environmental Science & Technology · doi:10.1021/es8001822 · Cited by 959
Self-citationMcCutcheon, J. R., McGinnis, R. L., & Elimelech, M. (2005) · Journal of Membrane Science · doi:10.1016/j.memsci.2005.10.048 · Cited by 839
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Sustainable and efficient biohydrogen production via electrohydrogenesis
Cheng, S., & Logan, B. E. (2007) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0706379104 · Cited by 680
Self-citationPractical Potential of Reverse Electrodialysis As Process for Sustainable Energy Generation
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Energy Capture from Thermolytic Solutions in Microbial Reverse-Electrodialysis Cells
Cusick, R. D., Kim, Y., & Logan, B. E. (2012) · Science · doi:10.1126/science.1219330 · Cited by 274
Self-citationA novel ammonia–carbon dioxide osmotic heat engine for power generation
McGinnis, R. L., McCutcheon, J. R., & Elimelech, M. (2007) · Journal of Membrane Science · doi:10.1016/j.memsci.2007.08.027 · Cited by 263
Ni foam cathode enables high volumetric H2 production in a microbial electrolysis cell
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Microbial Electrodialysis Cell for Simultaneous Water Desalination and Hydrogen Gas Production
Mehanna, M., Kiely, P. D., Call, D. F., & Logan, B. E. (2010) · Environmental Science & Technology · doi:10.1021/es1025646 · Cited by 233
Self-citationChae, K., Choi, M., Kim, K., Ajayi, F. F., Chang, I. S., & Kim, I. S. (2009) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2009.11.114 · Cited by 205
Kim, Y., & Logan, B. E. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1106335108 · Cited by 170
Self-citationMicrobial Reverse Electrodialysis Cells for Synergistically Enhanced Power Production
Kim, Y., & Logan, B. E. (2011) · Environmental Science & Technology · doi:10.1021/es200979b · Cited by 134
Self-citationNam, J.-Y., Tokash, J. C., & Logan, B. E. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.05.148 · Cited by 120
Self-citationAmmonia inhibition of electricity generation in single-chambered microbial fuel cells
Nam, J.-Y., Kim, H., & Shin, H. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.03.091 · Cited by 111
Self-citationEnhanced hydrogen generation using a saline catholyte in a two chamber microbial electrolysis cell
Nam, J.-Y., & Logan, B. E. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.08.106 · Cited by 93
Self-citationAmmonia inhibition and microbial adaptation in continuous single-chamber microbial fuel cells
Kim, H., Nam, J.-Y., & Shin, H. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.03.061 · Cited by 73
Self-citationKim, T.-W., Kim, Y. M., Yun, C., Jang, H., Kim, W., & Park, S. (2011) · Desalination · doi:10.1016/j.desal.2011.09.008 · Cited by 60
Self-citation
Research works printed but not linked: 1
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Cited by
Sorted by citations
Membrane-based processes for sustainable power generation using water
Logan, B. E., & Elimelech, M. (2012) · Nature · doi:10.1038/nature11477 · Cited by 1,666
Self-citationAssessment of Microbial Fuel Cell Configurations and Power Densities
Logan, B. E., Wallack, M. J., Kim, K., He, W., Feng, Y., & Saikaly, P. E. (2015) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.5b00180 · Cited by 525
Self-citationRecent developments and future perspectives of reverse electrodialysis technology: A review
Mei, Y., & Tang, C. Y. (2017) · Desalination · doi:10.1016/j.desal.2017.10.021 · Cited by 505
Membrane technology in renewable-energy-driven desalination
Ali, A., Tufa, R. A., Macedonio, F., Curcio, E., & Drioli, E. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.07.047 · Cited by 444
Zhang, Y., & Angelidaki, İ. (2014) · Water Research · doi:10.1016/j.watres.2014.02.031 · Cited by 429
Metadata
- Authors
- Nam, J.-Y., Cusick, R. D., Kim, Y., & Logan, B. E.
- Affiliations
- Pennsylvania State University (US)
- Corresponding author
- Logan, Bruce E.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-09
- Volume
- 46
- Issue
- 9
- Pages
- 5240-5246
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2101213156
- Cited by
- 105
- References
- 23
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 2 · 2023: 6 · 2022: 12 · 2021: 8 · 2020: 9 · 2019: 6 · 2018: 7 · 2017: 10 · 2016: 10 · 2015: 12 · 2014: 8 · 2013: 6 · 2012: 5
- FWCI
- 8.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
- Funders
- King Abdullah University of Science and Technology
- National Renewable Energy Laboratory
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › Microbial Fuel Cells and Bioremediation
- Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane-based Ion Separation Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Anaerobic Digestion and Biogas Production
- Keywords
- hydrogen production, waste heat recovery, salinity gradient energy, acetate oxidation, cathodic overpotential, co-current and counter-current flow, energy efficiency, distillation
- MeSH terms
- Bicarbonates, Bioelectric Energy Sources, Hydrogen, Sodium Bicarbonate, Salinity
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