The DOI matches its Crossref record; 54 of the 54 references it cites were found in a registry or an index.
Single-Component and Binary CO2 and H2O Adsorption of Amine-Functionalized Cellulose
Abstract
A fundamental analysis of single-component and binary CO2 and H2O adsorption of amine-functionalized nanofibrillated cellulose is carried out in the temperature range of 283-353 K and at CO2 partial pressures in the range of 0.02-105 kPa, where the ultralow partial pressure range is relevant for the direct capture of CO2 from atmospheric air. Single-component CO2 and H2O adsorption experimental data are fitted to the Toth and Guggenheim-Anderson-de Boer models, respectively. Corresponding heats of adsorption, derived from explicit solutions of the van't Hoff equation, are -50 kJ/mol CO2 and -48.8 kJ/mol H2O. Binary CO2/H2O adsorption measurements for humid air reveal that the presence of H2O at 2.55 kPa enhances CO2 adsorption, while the presence of CO2 at 0.045 kPa does not influence H2O adsorption. The energy demand of the temperature-vacuum-swing adsorption/desorption cycle for delivering pure CO2 from air increases significantly with H2O adsorption and indicates the need to reduce the hygroscopicity of the adsorbent.
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“a TSA process was developed to evaluate the regeneration ability of the biochar through the different cycles with adsorption and desorption temperatures, 30 and 110 ᵒC, respectively, which a stable CO 2 adsorption capability up to 25 cycles was proved [206].”
From Biomass/Biochar carbon materials for CO2 capture and sequestration by cyclic adsorption processes: A review and prospects for future directions (2022) · cites this paper as [206]
In the citing paper
“The adsorbent produced through the 900 ᵒC pyrolysis (specific surface area of 569.64 m 2 .g -1 ) showed the higher CO 2 adsorption capacity around 1.556 mmol.g -1 at 30 ᵒC”
From Biomass/Biochar carbon materials for CO2 capture and sequestration by cyclic adsorption processes: A review and prospects for future directions (2022) · cites this paper as [206]
In the citing paper
“while the biochar impregnated with 5% magnesium nitrate represented the highest CO 2 adsorption performance (1.745 mmol.g -1 ) among other magnesium impregnation methods [206].”
From Biomass/Biochar carbon materials for CO2 capture and sequestration by cyclic adsorption processes: A review and prospects for future directions (2022) · cites this paper as [206]
Citations
Cites
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On a theory of the van der waals adsorption of gases
Brunauer, S., Deming, L. S., Deming, W. E., & Teller, E. (1940) · Journal of the American Chemical Society · doi:10.1021/ja01864a025 · Cited by 4,829
Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
Choi, S., Drese, J. H., & Jones, C. W. (2009) · ChemSusChem · doi:10.1002/cssc.200900036 · Cited by 2,602
High-Flux Solar-Driven Thermochemical Dissociation of CO 2 and H 2 O Using Nonstoichiometric Ceria
Chueh, W. C., Falter, C. P., Abbott, M., Scipio, D., Furler, P., Haile, S. M., & Steinfeld, A. (2010) · Science · doi:10.1126/science.1197834 · Cited by 1,515
Self-citationAnthropogenic Chemical Carbon Cycle for a Sustainable Future
Olah, G. A., Prakash, G. K. S., & Goeppert, A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202642y · Cited by 1,378
McDonald, T. M., Lee, W. R., Mason, J. A., Wiers, B. M., Hong, C. S., & Long, J. R. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300034j · Cited by 1,322
Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy
Graves, C., Ebbesen, S. D., Mogensen, M. B., & Lackner, K. S. (2010) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2010.07.014 · Cited by 1,058
Air as the renewable carbon source of the future: an overview of CO2 capture from the atmosphere
Goeppert, A., Czaun, M., Surya Prakash, G. K., & Olah, G. A. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21586a · Cited by 724
Flue gas treatment via CO2 adsorption
Sayari, A., Belmabkhout, Y., & Serna-Guerrero, R. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.02.007 · Cited by 595
Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent
Goeppert, A., Czaun, M., May, R. B., Prakash, G. K. S., Olah, G. A., & Narayanan, S. R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2100005 · Cited by 568
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Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Sorbents for the Direct Capture of CO 2 from Ambient Air
Shi, X., Xiao, H., Azarabadi, H., Song, J., Wu, X., Chen, X., & Lackner, K. S. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201906756 · Cited by 679
Cellulose Nanomaterials in Water Treatment Technologies
Carpenter, A. W., de Lannoy, C., & Wiesner, M. R. (2015) · Environmental Science & Technology · doi:10.1021/es506351r · Cited by 689
Deutz, S., & Bardow, A. (2021) · Nature Energy · doi:10.1038/s41560-020-00771-9 · Cited by 653
Understanding the Effect of Water on CO 2 Adsorption
Kolle, J. M., Fayaz, M., & Sayari, A. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00762 · Cited by 542
Metadata
- Authors
- Gebald, C., Wurzbacher, J. A., Borgschulte, A., Zimmermann, T., & Steinfeld, A.
- Affiliations
- ETH Zurich (CH)
- Empa (CH)
- Paul Scherrer Institute (CH)
- Corresponding author
- Steinfeld, Aldo
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-29
- Volume
- 48
- Issue
- 4
- Pages
- 2497-2504
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2328472521
- Cited by
- 226
- References
- 54
- Citations by year
- 2026: 34 · 2025: 26 · 2024: 38 · 2023: 26 · 2022: 22 · 2021: 14 · 2020: 7 · 2019: 16 · 2018: 8 · 2017: 13 · 2016: 9 · 2015: 9 · 2014: 4
- FWCI
- 13.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- DORA Empa (Swiss Federal Laboratories for Materials Science and Technology (Empa)) (submittedVersion)
- DORA PSI (Paul Scherrer Institute) (submittedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
- Physical Sciences › Engineering › Mechanical Engineering › Adsorption and Cooling Systems
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Adsorption, diffusion, and thermodynamic properties of materials
- Keywords
- CO2 adsorption, water adsorption, cellulose nanofibers, CO2 capture from air, Toth isotherm, GAB model, heat of adsorption, humid air, temperature vacuum swing adsorption, hygroscopicity, partial pressure of CO2
- MeSH terms
- Adsorption, Amines, Carbon Dioxide, Cellulose, Humidity, Temperature, Water, Nanofibers
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