Thin-film photovoltaic power generation offers decreasing greenhouse gas emissions and increasing environmental co-benefits in the long term
Abstract
Thin-film photovoltaic (PV) technologies have improved significantly recently, and similar improvements are projected into the future, warranting reevaluation of the environmental implications of PV to update and inform policy decisions. By conducting a hybrid life cycle assessment using the most recent manufacturing data and technology roadmaps, we compare present and projected environmental, human health, and natural resource implications of electricity generated from two common thin-film PV technologies-copper indium gallium selenide (CIGS) and cadmium telluride (CdTe)-in the United States (U.S.) to those of the current U.S. electricity mix. We evaluate how the impacts of thin films can be reduced by likely cost-reducing technological changes: (1) module efficiency increases, (2) module dematerialization, (3) changes in upstream energy and materials production, and (4) end-of-life recycling of balance of system (BOS). Results show comparable environmental and resource impacts for CdTe and CIGS. Compared to the U.S. electricity mix in 2010, both perform at least 90% better in 7 of 12 and at least 50% better in 3 of 12 impact categories, with comparable land use, and increased metal depletion unless BOS recycling is ensured. Technological changes, particularly efficiency increases, contribute to 35-80% reductions in all impacts by 2030.
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Digital tracking and modelling devices, sensors, sensing devices and programmable logic controllers, hybrid genetic algorithms, and automated optical sorting are already utilized in recycling and reuse circular approaches.
“digital tracking and modelling devices used in the steel industry [121], sensors employed for thin-film photovoltaic (PV) technologies [122] and on buildings [123], sensing devices and programmable logic controllers for a steel industrial complex for water [124], hybrid genetic algorithms employed on household appliances [125], and automated optical sorting for recycled glass [126].”
From Digitisation and the Circular Economy: A Review of Current Research and Future Trends (2018) · cites this paper as [122]
Cites
Handbook on life cycle assessment operational guide to the ISO standards
Guinée, J. B. (2002) · The International Journal of Life Cycle Assessment · doi:10.1007/bf02978897 · Cited by 2,783 · see citing works
Environmental management. Life cycle assessment. Principles and framework
(2006) · doi:10.3403/30151316 · Cited by 1,427 · see citing works
Handbook of Photovoltaic Science and Engineering
(2010) · Wiley eBooks · doi:10.1002/9780470974704 · Cited by 1,393 · see citing works
Bare, J. (2002) · Journal of Industrial Ecology · doi:10.1162/108819802766269539 · Cited by 987 · see citing works
Environmental impacts of utility-scale solar energy
Hernandez, R. R., Easter, S. B., Murphy-Mariscal, M. L., Maestre, F. T., Tavassoli, M., Allen, E. B., Barrows, C. W., Belnap, J., Ochoa-Hueso, R., Ravi, S., et al. (2014) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2013.08.041 · Cited by 850 · see citing works
Majeau-Bettez, G., Hawkins, T. R., & Strømman, A. H. (2011) · Environmental Science & Technology · doi:10.1021/es103607c · Cited by 662 · see citing works
Emissions from Photovoltaic Life Cycles
Fthenakis, V. M., Kim, H. C., & Alsema, E. A. (2008) · Environmental Science & Technology · doi:10.1021/es071763q · Cited by 613 · see citing works
Land use and electricity generation: A life-cycle analysis
Fthenakis, V. M., & Kim, H. C. (2008) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2008.09.017 · Cited by 577 · see citing works
Midpoints versus endpoints: The sacrifices and benefits
Bare, J., Hofstetter, P., Pennington, D., & de Haes, H. A. U. (2000) · The International Journal of Life Cycle Assessment · doi:10.1007/bf02978665 · Cited by 550 · see citing works
Land-Use Requirements for Solar Power Plants in the United States
Ong, S., USDOE Office of Energy Efficiency and Renewable Energy (EERE), Campbell, C., et al. (2013) · doi:10.2172/1086349 · Cited by 464 · see citing works
Sustainability of photovoltaics: The case for thin-film solar cells
Fthenakis, V. M. (2009) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2009.05.001 · Cited by 443 · see citing works
Eyer, J., & Corey, G. P. (2010) · doi:10.2172/1031895 · Cited by 391 · see citing works
End-of-life management and recycling of PV modules
Fthenakis, V. M. (2000) · Energy Policy · doi:10.1016/s0301-4215(00)00091-4 · Cited by 369 · see citing works
Life Cycle Greenhouse Gas Emissions of Crystalline Silicon Photovoltaic Electricity Generation
Hsu, D. D., O’Donoughue, P., Fthenakis, V. M., Heath, G. A., Kim, H. C., Sawyer, P., Choi, J., & Turney, D. E. (2012) · Journal of Industrial Ecology · doi:10.1111/j.1530-9290.2011.00439.x · Cited by 323 · see citing works
Self-citationFunctions, commodities and environmental impacts in an ecological–economic model
Suh, S. (2004) · Ecological Economics · doi:10.1016/j.ecolecon.2003.10.013 · Cited by 314 · see citing works
Self-citationFthenakis, V. M., & Alsema, E. A. (2006) · Progress in Photovoltaics Research and Applications · doi:10.1002/pip.706 · Cited by 310 · see citing works
Raugei, M., Bargigli, S., & Ulgiati, S. (2006) · Energy · doi:10.1016/j.energy.2006.10.003 · Cited by 306 · see citing works
Burkhardt, J. J., Heath, G. A., & Turchi, C. S. (2011) · Environmental Science & Technology · doi:10.1021/es1033266 · Cited by 294 · see citing works
Self-citationLife cycle impact analysis of cadmium in CdTe PV production
Fthenakis, V. M. (2004) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2003.12.001 · Cited by 280 · see citing works
Wiedmann, T., Suh, S., Feng, K., Manfred Lenzen, A., Acquaye, A. A., Scott, K., & Barrett, J. (2011) · Environmental Science & Technology · doi:10.1021/es2007287 · Cited by 265 · see citing works
Self-citationParameters affecting the life cycle performance of PV technologies and systems
Pacca, S. A., Sivaraman, D., & Keoleian, G. A. (2007) · Energy Policy · doi:10.1016/j.enpol.2006.10.003 · Cited by 261 · see citing works
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Goodrich, A. C., James, T. L., et al. (2012) · doi:10.2172/1036048 · Cited by 254 · see citing works
Greenhouse-gas emissions from solar electric- and nuclear power: A life-cycle study
Fthenakis, V. M., & Kim, H. C. (2006) · Energy Policy · doi:10.1016/j.enpol.2006.06.022 · Cited by 240 · see citing works
Arvesen, A., & Hertwich, E. G. (2012) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2012.06.023 · Cited by 232 · see citing works
Frischknecht, R. (2010) · The International Journal of Life Cycle Assessment · doi:10.1007/s11367-010-0201-6 · Cited by 220 · see citing works
Implications for CdTe and CIGS technologies production costs of indium and tellurium scarcity
Candelise, C., Winskel, M., & Gross, R. (2012) · Progress in Photovoltaics Research and Applications · doi:10.1002/pip.2216 · Cited by 195 · see citing works
Denholm, P. L., & Margolis, R. (2008) · Energy Policy · doi:10.1016/j.enpol.2008.05.035 · Cited by 193 · see citing works
Life Cycle Greenhouse Gas Emissions of Thin‐film Photovoltaic Electricity Generation
Kim, H. C., Fthenakis, V. M., Choi, J., & Turney, D. E. (2012) · Journal of Industrial Ecology · doi:10.1111/j.1530-9290.2011.00423.x · Cited by 171 · see citing works
Environmental Impact of Crystalline Silicon Photovoltaic Module Production
Alsema, E. A., & Scholten, M. J. D. W. (2005) · MRS Proceedings · doi:10.1557/proc-0895-g03-05 · Cited by 165 · see citing works
Energy payback and life‐cycle CO2 emissions of the BOS in an optimized 3·5 MW PV installation
Mason, J. E., Fthenakis, V. M., Hansen, T., & Kim, H. C. (2005) · Progress in Photovoltaics Research and Applications · doi:10.1002/pip.652 · Cited by 164 · see citing works
Future recycling flows of tellurium from cadmium telluride photovoltaic waste
Marwede, M., & Reller, A. (2012) · Resources Conservation and Recycling · doi:10.1016/j.resconrec.2012.09.003 · Cited by 158 · see citing works
The Impact of Tellurium Supply on Cadmium Telluride Photovoltaics
Zweibel, K. (2010) · Science · doi:10.1126/science.1189690 · Cited by 154 · see citing works
On the Future Availability of the Energy Metals
Graedel, T. E. (2011) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-062910-095759 · Cited by 148 · see citing works
Replacing Gasoline with Corn Ethanol Results in Significant Environmental Problem-Shifting
Yang, Y., Bae, J., Kim, J., & Suh, S. (2012) · Environmental Science & Technology · doi:10.1021/es203641p · Cited by 147 · see citing works
Self-citationThe Western Wind and Solar Integration Study Phase 2
USDOE Office of Energy Efficiency and Renewable Energy (EERE), R. P. O. W. E. T. O., Lew, D. J., Brinkman, G., et al. (2013) · doi:10.2172/1220243 · Cited by 122 · see citing works
Zhai, P., & Williams, E. (2010) · Environmental Science & Technology · doi:10.1021/es1026695 · Cited by 115 · see citing works
Whitaker, M., Heath, G. A., Burkhardt, J. J., et al. (2013) · Environmental Science & Technology · doi:10.1021/es400821x · Cited by 112 · see citing works
Self-citationLife-cycle analyses of very-large scale PV systems using six types of PV modules
Ito, M., Komoto, K., & Kurokawa, K. (2009) · Current Applied Physics · doi:10.1016/j.cap.2009.11.028 · Cited by 108 · see citing works
Life-cycle assessment of photovoltaic systems: results of Swiss studies on energy chains
Dones, R., & Frischknecht, R. (1998) · Progress in Photovoltaics Research and Applications · doi:10.1002/(sici)1099-159x(199803/04)6:2 · Cited by 104 · see citing works
Emissions and encapsulation of cadmium in CdTe PV modules during fires
Fthenakis, V. M., Fuhrmann, M., Heiser, J., et al. (2005) · Progress in Photovoltaics Research and Applications · doi:10.1002/pip.624 · Cited by 97 · see citing works
Woodhouse, M. A., Goodrich, A. C., Margolis, R., et al. (2012) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2012.03.023 · Cited by 91 · see citing works
Arvesen, A., & Hertwich, E. G. (2011) · Environmental Research Letters · doi:10.1088/1748-9326/6/4/045102 · Cited by 79 · see citing works
Althaus, H., & Classen, M. (2004) · The International Journal of Life Cycle Assessment · doi:10.1065/lca2004.11.181.5 · Cited by 79 · see citing works
Thin-Film Photovoltaic Cells: Long-Term Metal(loid) Leaching at Their End-of-Life
Zimmermann, Y., Schäffer, A., Corvini, P. F.-X., & Lenz, M. (2013) · Environmental Science & Technology · doi:10.1021/es402969c · Cited by 77 · see citing works
Scale-up issues of CIGS thin film PV modules
Dhere, N. G. (2010) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2010.02.019 · Cited by 76 · see citing works
Sustainability metrics for extending thin-film photovoltaics to terawatt levels
Fthenakis, V. M. (2012) · MRS Bulletin · doi:10.1557/mrs.2012.50 · Cited by 75 · see citing works
20 000 PERL silicon cells for the ‘1996 World Solar Challenge’ solar car race
Zhao, J., Wang, A., Yun, F., Zhang, G., Roche, D., Wenham, S. R., & Green, M. A. (1997) · Progress in Photovoltaics Research and Applications · doi:10.1002/(sici)1099-159x(199707/08)5:4 · Cited by 72 · see citing works
Suh, S. (2009) · Eco-efficiency in industry and science · doi:10.1007/978-1-4020-5737-3_32 · Cited by 65 · see citing works
Self-citationBright Future: Solar Power as a Major Contributor to the U.S. Grid
Denholm, P. L., Margolis, R., Mai, T., et al. (2013) · IEEE Power and Energy Magazine · doi:10.1109/mpe.2012.2234404 · Cited by 61 · see citing works
Life Cycle Assessment of Photovoltaics; Update of the ecoinvent Database
Jungbluth, N., Dones, R., & Frischknecht, R. (2007) · MRS Proceedings · doi:10.1557/proc-1041-r01-03 · Cited by 60 · see citing works
Supply-Chain Dynamics of Tellurium, Indium, and Gallium Within the Context of PV Manufacturing Costs
Woodhouse, M. A., Goodrich, A. C., Margolis, R., et al. (2013) · IEEE Journal of Photovoltaics · doi:10.1109/jphotov.2013.2242960 · Cited by 58 · see citing works
Bare, J. (2006) · Human and Ecological Risk Assessment An International Journal · doi:10.1080/10807030600561683 · Cited by 52 · see citing works
Domínguez-Ramos, A., Held, M., García, R. A., et al. (2010) · The International Journal of Life Cycle Assessment · doi:10.1007/s11367-010-0192-3 · Cited by 32 · see citing works
Pacca, S. A., Sivaraman, D., & Keoleian, G. A. (2006) · Deep Blue (University of Michigan) · doi:10.7302/22179 · Cited by 20 · see citing works
CIGS and CdTe based thin film PV modules, an industrial r/evolution
Dimmler, B. (2012) · Conference record of the IEEE Photovoltaic Specialists Conference · doi:10.1109/pvsc.2012.6318101 · Cited by 16 · see citing works
Panasonic sets new record for solar cell efficiency
(2014) · Physics Today · doi:10.1063/pt.5.028014 · Cited by 13 · see citing works
Life Cycle Assessment for Photovoltaics: Update Within Ecoinvent Data v2.0
Jungbluth, N., Frischknecht, R., & Tuchschmid, M. (2008) · EU PVSEC · doi:10.4229/23rdeupvsec2008-6bo.8.4 · Cited by 9 · see citing works
Understanding the Environmental Implications of Energy Transitions. A Case Study for Wind Power
Arvesen, A. (2013) · NORA - Norwegian Open Research Archives · Cited by 5 · see citing works
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- Authors
- Bergesen, J. D., Heath, G. A., Gibon, T., & Suh, S.
- Affiliations
- University of California, Santa Barbara (US)
- National Laboratory of the Rockies (US)
- Norwegian University of Science and Technology (NO)
- Corresponding author
- Suh, Sangwon
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-25
- Volume
- 48
- Issue
- 16
- Pages
- 9834-9843
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2333617135
- Cited by
- 77
- References
- 58
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 5 · 2023: 9 · 2022: 6 · 2021: 5 · 2020: 4 · 2019: 3 · 2018: 12 · 2017: 8 · 2016: 9 · 2015: 7 · 2014: 3
- FWCI
- 6.89
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Office of Energy Efficiency and Renewable Energy
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › Photovoltaic Systems and Sustainability
- Physical Sciences › Environmental Science › Environmental Engineering › Environmental Impact and Sustainability
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Solar Thermal and Photovoltaic Systems
- Keywords
- thin-film solar cells, Cu(In,Ga)Se2, CdTe, greenhouse gas emissions, environmental co-benefits, life cycle assessment, technology roadmap, module efficiency, metal depletion, land use, human health effects, natural resource depletion, electricity generation
- MeSH terms
- Carcinogens, Conservation of Natural Resources, Electricity, Energy-Generating Resources, Environment, Gallium, Gases, Metals, Selenium, Tellurium, United States, Greenhouse Effect, Cadmium Compounds, Uncertainty, Climate Change
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