The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Formation of Iodo-Trihalomethanes during Disinfection and Oxidation of Iodide-Containing Waters
Open accessAbstract
The formation of iodo-trihalomethanes (I-THMs) such as iodoform (CHI 3 ) during oxidative treatment of iodide-containing drinking waters can be responsible for taste and odor problems. I-THMs are formed by reactions of hypoiodous acid (HOI) with natural organic matter. HOI is quickly formed from naturally occurring iodide (I - ) by oxidation with ozone, chlorine, or chloramine. The kinetics of reactions of HOI with organic model compounds as well as the resulting CHI 3 formation were measured. Substituted phenols, phenol, and, to a smaller extent, α-methyl carbonyl compounds were found to be reactive toward HOI and also to yield CHI 3 . Resorcinol ( m -hydroxyphenol) had the highest yield of CHI 3 . The kinetics of I-THM formation were also measured in natural waters which were oxidatively treated with ozone, chlorine, or chloramine. When ozone was used, no I-THMs were detected and ≥90% of I - was transformed to IO 3 - . Chlorine led to the formation of both IO 3 - and I-THMs. With increasing chlorine doses, the CHI 3 formation decreased, whereas IO 3 - formation, as well as the formation of classical THMs such as chloroform, increased. In chloramination processes, I-THMs (especially CHI 3 ) were the main products. The CHI 3 formation in the oxidation of natural waters increased in the order O 3 < Cl 2 < NH 2 Cl.
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Citations
Cites
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Oxidation of Iodide and Hypoiodous Acid in the Disinfection of Natural Waters
Bichsel, Y., & von Gunten, U. (1999) · Environmental Science & Technology · doi:10.1021/es990336c · Cited by 412
Self-citationTurner, D. H., Flynn, G. W., Sutin, N., & Beitz, J. V. (1972) · Journal of the American Chemical Society · doi:10.1021/ja00760a020 · Cited by 155
Iodoform taste complaints in chloramination
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Chlorination and Formation of Organoiodinated Compounds: The Important Role of Ammonia
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Cited by
RICHARDSON, S., PLEWA, M., WAGNER, E., SCHOENY, R., & DEMARINI, D. (2007) · Mutation Research/Reviews in Mutation Research · doi:10.1016/j.mrrev.2007.09.001 · Cited by 3,317
Occurrence of a new generation of disinfection byproducts†
Krasner, S. W., Weinberg, H. S., Richardson, S. D., Pastor, S. J., Chinn, R., Sclimenti, M. J., Onstad, G. D., & Thruston, A. D. (2006) · Environmental Science & Technology · doi:10.1021/es060353j · Cited by 1,633
von Gunten, U. (2003) · Water Research · doi:10.1016/s0043-1354(02)00458-x · Cited by 1,345
Self-citationLi, X.-F., & Mitch, W. A. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.7b05440 · Cited by 1,020
Cui, J., Gao, P., & Deng, Y. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.9b05565 · Cited by 742
Metadata
- Authors
- Bichsel, Y., & von Gunten, U.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-06-07
- Volume
- 34
- Issue
- 13
- Pages
- 2784-2791
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2038819303
- Cited by
- 406
- References
- 10
- FWCI
- 3.31
- Type
- journal article
- Language
- en
- Open access
- green
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