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Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy
Abstract
The binary transition-metal monophosphides CrP, MnP, FeP, and CoP have been studied with X-ray photoelectron spectroscopy. The shifts in phosphorus 2p(3/2) core line binding energies relative to that of elemental phosphorus indicated that the degree of ionicity of the metal-phosphorus bond decreases on progressing from CrP to CoP. The metal 2p(3/2) core line binding energies differ only slightly and show similar line shapes to those of the elemental metals, reaffirming the notion that these transition-metal phosphides have considerable metallic character. The satellite structure observed in the Co 2p(3/2) X-ray photoelectron spectra of Co metal and CoP was examined by reflection electron energy loss spectroscopy and has been attributed to plasmon loss, not final state effects as has been previously suggested. Valence-band spectra of the transition-metal phosphides agree well with the density of states profiles determined from band structure calculations. The electron populations of the different electronic states were extracted from the fitted valence-band spectra, and these confirm the presence of strong M-P and weak P-P bonding interactions. Atomic charges determined from the P 2p core line spectra and the fitted valence-band spectra support the approximate formulation M(1+)P(1-) for these phosphides.
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Hüfner, S. (1995) · Springer Series in Solid-State Sciences · doi:10.1007/978-3-662-03150-6 · Cited by 854
Cited by
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Grosvenor, A. P., Biesinger, M. C., Smart, R. S. C., & McIntyre, N. S. (2006) · Surface Science · doi:10.1016/j.susc.2006.01.041 · Cited by 2,434
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Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885
Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Advanced Materials · doi:10.1002/adma.201401692 · Cited by 835
Jiao, L., Zhou, Y.-X., & Jiang, H.-L. (2016) · Chemical Science · doi:10.1039/c5sc04425a · Cited by 798
Liang, H., Gandi, A. N., Xia, C., Hedhili, M. N., Anjum, D. H., Schwingenschlögl, U., & Alshareef, H. N. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00206 · Cited by 588
Liu, M., & Li, J. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b10727 · Cited by 538
Pu, Z., Zhao, J., Amiinu, I. S., Li, W., Wang, M., He, D., & Mu, S. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00197b · Cited by 484
Chang, J., Xiao, Y., Xiao, M., Ge, J., Liu, C., & Xing, W. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02076 · Cited by 478
Li, J., Liu, H.-X., Gou, W., Zhang, M., Xia, Z., Zhang, S., Chang, C.-R., Ma, Y., & Qu, Y. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00752k · Cited by 473
Ryu, J., Jung, N., Jang, J. H., Kim, H.-J., & Yoo, S. J. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00349 · Cited by 455
Zhang, X., Zhang, X., Xu, H., Wu, Z., Wang, H., & Liang, Y. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201606635 · Cited by 263
Chen, J., Shi, H., Li, L., & Li, K. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2013.08.026 · Cited by 259
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Xing, Z., Liu, Q., Asiri, A. M., & Sun, X. (2015) · ACS Catalysis · doi:10.1021/cs5014943 · Cited by 238
Wang, P., Song, F., Amal, R., Ng, Y. H., & Hu, X. (2016) · ChemSusChem · doi:10.1002/cssc.201501599 · Cited by 203
Yu, X., Zhang, S., Li, C., Zhu, C., Chen, Y., Gao, P., Qi, L., & Zhang, X. (2016) · Nanoscale · doi:10.1039/c6nr01867j · Cited by 165
Burns, A. W., Layman, K. A., Bale, D. H., & Bussell, M. E. (2008) · Applied Catalysis A: General · doi:10.1016/j.apcata.2008.03.022 · Cited by 164
Li, H., Zhao, X., Liu, H., Chen, S., Yang, X., Lv, C., Zhang, H., She, X., & Yang, D. (2018) · Small · doi:10.1002/smll.201802824 · Cited by 124
Zhang, X., Han, Y., Huang, L., & Dong, S. (2016) · ChemSusChem · doi:10.1002/cssc.201600904 · Cited by 60
Metadata
- Authors
- Grosvenor, A. P., Wik, S. D., Cavell, R. G., & Mar, A.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-10-22
- Volume
- 44
- Issue
- 24
- Pages
- 8988-8998
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2043690521
- Cited by
- 464
- References
- 1
- FWCI
- 2.06
- Type
- journal article
- Language
- en
- Open access
- closed
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