The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Au3SnP7@Black Phosphorus: An Easy Access to Black Phosphorus
Abstract
Black phosphorus can be prepared under low-pressure conditions at 873 K from red phosphorus via the addition of small quantities of gold, tin, and tin(IV) iodide. Au3SnP7, AuSn, and Sn4P3 were observed as additional phases. Tin(IV) iodide remains unreacted during the preparation process. The crystal structure of black phosphorus was redetermined from single crystals. P (295 K): a = 3.316(1) A, b = 10.484(2) A, c = 4.379(1) A, V = 152.24(6) A3, space group Cmce (No. 64). Solid-state 31P MAS NMR spectroscopy and X-ray powder diffraction were performed to substantiate the high crystal quality of black phosphorus. A possible mechanism for the formation is discussed in terms of the comparable structural features of black phosphorus and Au3SnP7. Thermodynamic calculations showed that the only relevant gas-phase species, P4, and the transport reactions are not suitable for the preparation of orthorhombic black phosphorus at temperatures above 773 K. A kinetically controlled mechanism must be favored instead of a thermodynamically controlled formation. The new preparation method of black phosphorus represents an easy and effective way to avoid complicated preparative setups, toxic catalysts, or "dirty" flux methods and is of general interest in elemental chemistry.
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Cites
Thermochemical Data of Pure Substances
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Baehr, H. D. (1992) · Forschung im Ingenieurwesen · doi:10.1007/bf02561491 · Cited by 1,178
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Bridgman, P. W. (1914) · Journal of the American Chemical Society · doi:10.1021/ja02184a002 · Cited by 811
The Atomic Distribution in Red and Black Phosphorus and the Crystal Structure of Black Phosphorus
Hultgren, R., Gingrich, N. S., & Warren, B. E. (1935) · The Journal of Chemical Physics · doi:10.1063/1.1749671 · Cited by 427
Cited by
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
Surface Modification of 2D Photocatalysts for Solar Energy Conversion
Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
Li, B., Lai, C., Zeng, G., Huang, D., Qin, L., Zhang, M., Cheng, M., Liu, X., Yi, H., Zhou, C., et al. (2019) · Small · doi:10.1002/smll.201804565 · Cited by 367
A fast low-pressure transport route to large black phosphorus single crystals
Nilges, T., Kersting, M., & Pfeifer, T. (2008) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2008.03.008 · Cited by 287
Self-citationRevealing the Origins of 3D Anisotropic Thermal Conductivities of Black Phosphorus
Zhu, J., Park, H., Chen, J., Gu, X., Zhang, H., Karthikeyan, S., Wendel, N., Campbell, S. A., Dawber, M., Du, X., et al. (2016) · Advanced Electronic Materials · doi:10.1002/aelm.201600040 · Cited by 108
Metadata
- Authors
- Lange, S., Schmidt, P., & Nilges, T.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-18
- Volume
- 46
- Issue
- 10
- Pages
- 4028-4035
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2091337215
- Cited by
- 396
- References
- 4
- FWCI
- 4.64
- Type
- journal article
- Language
- en
- Open access
- closed
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