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Four-Coordinate Organoboron Compounds with a π-Conjugated Chelate Ligand for Optoelectronic Applications
Abstract
Four-coordinate organoboron compounds with a π-conjugated chelate backbone have emerged recently as highly attractive materials for a number of applications including use as emitters and electron-transport materials for organic light-emitting diodes (OLEDs) or organic field transistors, photoresponsive materials, and sensory and imaging materials. Many applications of this class of boron compounds stem from the electronic properties of the π-conjugated chelate backbone. Charge-transfer transitions from an aromatic substituent attached to the boron center of the π-conjugated chelate backbone and steric congestion have also been found to play important roles in the luminescent and photochromic properties of the four-coordinate boron compounds. This article provides an update-to-date account on the application aspects of this important class of compounds in materials science with the emphasis on OLED applications and photochromic switching.
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Metadata
- Authors
- Rao, Y.-L., & Wang, S.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-05-23
- Volume
- 50
- Issue
- 24
- Pages
- 12263-12274
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W1993058251
- Cited by
- 277
- References
- 41
- FWCI
- 9.73
- Type
- journal article
- Language
- en
- Open access
- closed
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