The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Metal–Organic Frameworks Based on Previously Unknown Zr8/Hf8 Cubic Clusters
Abstract
The ongoing study of zirconium- and hafnium-porphyrinic metal-organic frameworks (MOFs) led to the discovery of isostructural MOFs based on Zr8 and Hf8 clusters, which are unknown in both cluster and MOF chemistry. The Zr8O6 cluster features an idealized Zr8 cube, in which each Zr atom resides on one vertex and each face of the cube is capped by one μ4-oxygen atom. On each edge of the cube, a carboxylate from a porphyrinic ligand bridges two Zr atoms to afford a 3D MOF with a very rare (4,12)-connected ftw topology, in which two types of polyhedral cages with diameters of ∼1.1 and ∼2.0 nm and a cage opening of ∼0.8 nm are found. The isostructural Zr- and Hf-MOFs exhibit high surface areas, gas uptakes, and catalytic selectivity for cyclohexane oxidation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Cited by
Catalysis and photocatalysis by metal organic frameworks
Dhakshinamoorthy, A., Li, Z., & Garcia, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00256h · Cited by 1,505
Metal‐Organic Framework Nanoparticles in Photodynamic Therapy: Current Status and Perspectives
Lismont, M., Dreesen, L., & Wuttke, S. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201606314 · Cited by 622
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Self-citationA reticular chemistry guide for the design of periodic solids
Jiang, H., Alezi, D., & Eddaoudi, M. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00287-y · Cited by 432
Self-citationA Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology
Feng, D., Gu, Z.-Y., Chen, Y.-P., Park, J., Wei, Z., Sun, Y., Bosch, M., Yuan, S., & Zhou, H.-C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510525s · Cited by 431
Self-citation
Metadata
- Authors
- Feng, D., Jiang, H.-L., Chen, Y.-P., Gu, Z.-Y., Wei, Z., & Zhou, H.-C.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-22
- Volume
- 52
- Issue
- 21
- Pages
- 12661-12667
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2105333668
- Cited by
- 233
- References
- 1
- FWCI
- 11.47
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Metal–Organic Frameworks Based on Previously Unknown Zr8/Hf8 Cubic Clusters. https://app.cochat.ai/papers/10.1021/ic4018536
- The paper
- Feng, D., Jiang, H.-L., Chen, Y.-P., Gu, Z.-Y., Wei, Z., & Zhou, H.-C. (2013). Metal–Organic Frameworks Based on Previously Unknown Zr8/Hf8 Cubic Clusters. Inorganic Chemistry. https://doi.org/10.1021/ic4018536
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
