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Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
Abstract
Liquids that consist of a mixture of an alcohol and either an amidine or a guanidine have been developed to switch from a low-polarity form to a high-polarity ionic liquid upon treatment with CO 2 at atmospheric pressure. Treatment with N 2 and/or mild heat (50−60 °C) reverses the process. These liquids can be used as switchable solvents to dissolve and then precipitate a solute or to dissolve reagents for a chemical synthesis and then precipitate the product.
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Citations
Cited by
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Green and sustainable solvents in chemical processes
Clarke, C. J., Tu, W.-C., Levers, O., Bröhl, A., & Hallett, J. P. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00571 · Cited by 2,071
Ionic liquids and catalysis: Recent progress from knowledge to applications
Olivier-Bourbigou, H., Magna, L., & Morvan, D. (2010) · Applied Catalysis A: General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Metadata
- Authors
- Phan, L., Chiu, D., Heldebrant, D. J., Huttenhower, H., John, E., Li, X., Pollet, P., Wang, R., Eckert, C. A., Liotta, C. L., & Jessop, P. G.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-05
- Volume
- 47
- Issue
- 3
- Pages
- 539-545
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2063560723
- Cited by
- 271
- References
- 0
- FWCI
- 5.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures. https://app.cochat.ai/papers/10.1021/ie070552r
- The paper
- Phan, L., Chiu, D., Heldebrant, D. J., Huttenhower, H., John, E., Li, X., Pollet, P., Wang, R., Eckert, C. A., Liotta, C. L., & Jessop, P. G. (2008). Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie070552r
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
