The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks
Abstract
This work presents an experimental investigation of water adsorption in metal–organic frameworks (MOFs) at room temperature and up to 90% relative humidity. Structural degradation of the materials after regeneration is analyzed via powder X-ray diffraction (PXRD) and nitrogen adsorption measurements. MOFs with open metal sites are quite hydrophilic but appear to maintain their structure according to PXRD. However, significant surface area loss indicates that decomposition is occurring and is likely an attribute of oxygen presence during the regeneration procedure. Materials with copper paddle-wheel (HKUST-1), 5-coordinated magnesium (Mg MOF-74), and 7-coordinated zirconium (UiO-66(-NH 2 )) maintain good structural stability, while Zn-COOH containing MOFs (DMOF-1; DMOF-1-NH 2; UMCM-1) undergo complete loss of crystallinity.
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Cites
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Self-citationDirect Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Water adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
Applications of water stable metal–organic frameworks
Wang, C., Liu, X., Keser Demir, N., Chen, J. P., & Li, K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00362a · Cited by 1,249
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Metadata
- Authors
- Schoenecker, P. M., Carson, C. G., Jasuja, H., Flemming, C. J. J., & Walton, K. S.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-18
- Volume
- 51
- Issue
- 18
- Pages
- 6513-6519
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2327890045
- Cited by
- 557
- References
- 2
- FWCI
- 22.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schoenecker, P. M., Carson, C. G., Jasuja, H., Flemming, C. J. J., & Walton, K. S. (2012). Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie202325p
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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