Dehydration of ethanol to ethylene
Abstract
This article is an up-to-date review of the literature available on the subject of ethanol to ethylene. The process of ethanol to ethylene has broad development prospects. Compared with the process of petroleum to ethylene, ethanol dehydration to ethylene is economically feasible. Researchers have been redirecting their interest to the ethylene production process, catalysts, and reaction mechanisms. A fluidized bed reactor, together with a wear-resistant, efficient, and stable catalyst will be the focus of future research that includes a deep understanding of the large-scale activated alumina catalyst and the molecular sieve catalyst used, and will promote the development of the ethanol dehydration to ethylene process and provide strong support for the market competiveness of the process.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
To obtain jet fuel from small alcohols, ethanol and butanol are first dehydrated to corresponding alkenes ethylene and butylene, which are then oligomerized to a desired range of sizes.
“To obtain jet fuel from these small alcohols, ethanol and butanol (separated from the fermentation broth) are first dehydrated to corresponding alkenes ethylene and butylene (Harvey and Meylemans, 2011; Zhang and Yu, 2013). The alkenes are then oligomerized to a desired range of sizes (i.e., number of carbon atoms) that fit the end application (Heveling et al., 1998; Harvey and Meylemans, 2011).”
From Gas Fermentation—A Flexible Platform for Commercial Scale Production of Low-Carbon-Fuels and Chemicals from Waste and Renewable Feedstocks (2016) · cites this paper as Zhang and Yu, 2013
Cites
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
Huber, G. W., Iborra, S., & Corma, A. (2006) · Chemical Reviews · doi:10.1021/cr068360d · Cited by 7,680 · see citing works
Chemical reactor analysis and design
Brooks, B. W. (1991) · The Chemical Engineering Journal · doi:10.1016/0300-9467(91)85016-o · Cited by 2,169 · see citing works
March's Advanced Organic Chemistry
Smith, M. B., & March, J. (2006) · Wiley eBooks · doi:10.1002/0470084960 · Cited by 1,842 · see citing works
Crystal structure and structure-related properties of ZSM-5
OLSON, D. H. L., KOKOTAILO, G. T., Lawton, S. L., & Meier, W. M. (1981) · The Journal of Physical Chemistry · doi:10.1021/j150615a020 · Cited by 1,172 · see citing works
Lok, B. M., Messina, C. A., Patton, R. L., Gajek, R. T., Cannan, T. R., & Flanigen, E. M. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00332a063 · Cited by 978 · see citing works
VANKONINGSVELD, H., JANSEN, J., & VANBEKKUM, H. (1990) · Zeolites · doi:10.1016/0144-2449(94)90134-1 · Cited by 510 · see citing works
New Solid Acids and Bases - Their Catalytic Properties
(1989) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(08)x6021-5 · Cited by 444 · see citing works
Alumina: Catalyst and Support. I. Alumina, its Intrinsic Acidity and Catalytic Activity1
Pines, H., & Haag, W. O. (1960) · Journal of the American Chemical Society · doi:10.1021/ja01495a021 · Cited by 425 · see citing works
Dehydration of Ethanol into Ethylene over Solid Acid Catalysts
Takahara, I., Saito, M., Inaba, M., & Murata, K. (2005) · Catalysis Letters · doi:10.1007/s10562-005-8698-1 · Cited by 297 · see citing works
Catalytic dehydration of bioethanol to ethylene over TiO2/γ-Al2O3 catalysts in microchannel reactors
Chen, G., Li, S., Jiao, F., & Yuan, Q. (2007) · Catalysis Today · doi:10.1016/j.cattod.2007.01.071 · Cited by 214 · see citing works
Varışlı, D., Doğu, T., & Doğu, G. (2007) · Chemical Engineering Science · doi:10.1016/j.ces.2007.01.017 · Cited by 202 · see citing works
Acid-catalysed dehydration of alcohols in supercritical water
Ramayya, S., Brittain, A. M., DeAlmeida, C., Mok, W. S. L., & Antal, M. J. (1987) · Fuel · doi:10.1016/0016-2361(87)90183-9 · Cited by 196 · see citing works
Comparison of four catalysts in the catalytic dehydration of ethanol to ethylene
Zhang, X., Wang, R., Yang, X., et al. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.04.004 · Cited by 190 · see citing works
Chiang, H., & Bhan, A. (2010) · Journal of Catalysis · doi:10.1016/j.jcat.2010.01.021 · Cited by 188 · see citing works
Production of Ethylene from Hydrous Ethanol on H-ZSM-5 under Mild Conditions
Phillips, C. B., & Datta, R. (1997) · Industrial & Engineering Chemistry Research · doi:10.1021/ie9702542 · Cited by 187 · see citing works
The dehydration of alcohols on alumina XIV. Reactivity and mechanism
Knözinger, H. (1972) · Journal of Catalysis · doi:10.1016/0021-9517(72)90007-3 · Cited by 186 · see citing works
Dehydration of Alcohols on Aluminum Oxide
Knözinger, H. (1968) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196807911 · Cited by 174 · see citing works
FIXED BED CATALYTIC REACTORS—CURRENT DESIGN STATUS
Froment, G. F. (1967) · Industrial & Engineering Chemistry · doi:10.1021/ie50686a006 · Cited by 166 · see citing works
Synthesis gas production by steam reforming of ethanol
Galvita, V., Semin, G. L., Belyaev, V. D., Semikolenov, V. A., Tsiakaras, P. E., & Sobyanin, V. A. (2001) · Applied Catalysis A General · doi:10.1016/s0926-860x(01)00708-6 · Cited by 139 · see citing works
Alcohol Dehydration: Mechanism of Ether Formation Using an Alumina Catalyst
Shi, B. C., & Davis, B. H. (1995) · Journal of Catalysis · doi:10.1006/jcat.1995.1301 · Cited by 129 · see citing works
Ramesh, K., Chang, J. Y., Han, Y., et al. (2010) · Industrial & Engineering Chemistry Research · doi:10.1021/ie901666f · Cited by 125 · see citing works
Adsorption and reactions of ethanol and ethanol–water mixture on alumina-supported Pt catalysts
Dömök, M., Tóth, M., Raskó, J., et al. (2006) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2006.06.001 · Cited by 122 · see citing works
Silica-supported heteropolyacids as catalysts in alcohol dehydration reactions
Vázquez, P., Pizzio, L. R., Cáceres, C. V., et al. (2000) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(00)00346-0 · Cited by 121 · see citing works
Structure and reactivity of phosphorous modified H-ZSM-5 catalysts for ethanol dehydration
Ramesh, K., Hui, L. M., Han, Y., et al. (2008) · Catalysis Communications · doi:10.1016/j.catcom.2008.10.034 · Cited by 116 · see citing works
Haber, J., Pamin, K., Matachowski, L., et al. (2002) · Journal of Catalysis · doi:10.1006/jcat.2002.3514 · Cited by 114 · see citing works
Catalytic dehydration of alcohols over alumina Mechanism of ether formation
JAIN, J. (1967) · Journal of Catalysis · doi:10.1016/0021-9517(67)90260-6 · Cited by 111 · see citing works
Ethanol production from biomass: Analysis of process efficiency and sustainability
Bastianoni, S., & Marchettini, N. (1996) · Biomass and Bioenergy · doi:10.1016/s0961-9534(96)00037-2 · Cited by 109 · see citing works
The bioethanol-to-ethylene (B.E.T.E.) process
Mao, R. L. V., Nguyen, T. M., & McLaughlin, G. (1989) · Applied Catalysis · doi:10.1016/s0166-9834(00)82798-0 · Cited by 101 · see citing works
The dehydration of alcohols over aluminaI. The reaction scheme
Knözinger, H., & KOHNE, R. (1966) · Journal of Catalysis · doi:10.1016/s0021-9517(66)80007-6 · Cited by 101 · see citing works
Catalytic dehydration of bioethanol to ethylene: Pilot-scale studies and process simulation
Kagyrmanova, A. P., Чумаченко, В. А., Korotkikh, V. N., et al. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.06.049 · Cited by 100 · see citing works
Catalytic Conversion of Bio-ethanol to Ethylene over La-Modified HZSM-5 Catalysts in a Bioreactor
Ouyang, J., Kong, F., Su, G., et al. (2009) · Catalysis Letters · doi:10.1007/s10562-009-0047-3 · Cited by 94 · see citing works
Ethanol to gasoline process: effect of variables, mechanism, and kinetics
Costa, E., Uguina, A., Aguado, J., & Hernandez, P. J. (1985) · Industrial & Engineering Chemistry Process Design and Development · doi:10.1021/i200029a003 · Cited by 88 · see citing works
Djieugoue, M.-A., Prakash, A., & Kevan, L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp000504j · Cited by 86 · see citing works
Dahl, I. M., Wendelbo, R., Andersen, A., et al. (1999) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(98)00328-x · Cited by 82 · see citing works
Andrigo, P. (1999) · Catalysis Today · doi:10.1016/s0920-5861(99)00076-0 · Cited by 82 · see citing works
The mechanism of dehydrogenation of ethanol on magnesium oxide
Takezawa, N. (1975) · Journal of Catalysis · doi:10.1016/0021-9517(75)90067-6 · Cited by 75 · see citing works
Xu, X., Almeida, C. P. D., & Antal, M. J. (1991) · Industrial & Engineering Chemistry Research · doi:10.1021/ie00055a012 · Cited by 71 · see citing works
Fixed Bed Catalytic Reactors. Technological and Fundamental Design Aspects
Froment, G. F. (1974) · Chemie Ingenieur Technik · doi:10.1002/cite.330460903 · Cited by 69 · see citing works
A Review of Techniques for the Process Intensification of Fluidized Bed Reactors
Zhang, W. (2009) · Chinese Journal of Chemical Engineering · doi:10.1016/s1004-9541(08)60264-5 · Cited by 68 · see citing works
Catalytic dehydration of ethanol over silica-alumina
Roca, F. F. (1969) · Journal of Catalysis · doi:10.1016/0021-9517(69)90414-x · Cited by 66 · see citing works
Mizuno, N., & Misono, M. (1997) · Current Opinion in Solid State and Materials Science · doi:10.1016/s1359-0286(97)80109-x · Cited by 66 · see citing works
The Surface Area and Catalytic Activity of Aluminum Oxide
Brey, W. S., & Krieger, K. A. (1949) · Journal of the American Chemical Society · doi:10.1021/ja01179a016 · Cited by 59 · see citing works
Recovery of ethene-selective FeOx/Al2O3 ethanol dehydration catalyst from industrial chemical wastes
El‐Katatny, E. A., Halawy, S. A., Mohamed, M. A., et al. (2000) · Applied Catalysis A General · doi:10.1016/s0926-860x(99)00539-6 · Cited by 50 · see citing works
Ethanol dehydration on alumina catalysts I. The thermal desorption of surface compounds
ARAI, H. (1967) · Journal of Catalysis · doi:10.1016/0021-9517(67)90193-5 · Cited by 49 · see citing works
Parametric sensitivity of a fixed bed catalytic reactor
Lopez, A., de Lasa, H., & Porras, J. A. (1981) · Chemical Engineering Science · doi:10.1016/0009-2509(81)85007-5 · Cited by 43 · see citing works
Mechanism and kinetics of the acid-catalyzed dehydration of ethanol in supercritical water
Xu, X., Almeida, C. D. O., & Antal, M. J. (1990) · The Journal of Supercritical Fluids · doi:10.1016/0896-8446(90)90027-j · Cited by 42 · see citing works
Saito, Y. (1987) · Journal of Catalysis · doi:10.1016/0021-9517(87)90243-0 · Cited by 36 · see citing works
Dehydration mechanism of ethanol in the pseudoliquid phase of H3-Cs PW12O40
Okuhara, T., Arai, T., Ichiki, T., et al. (1989) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(89)80263-9 · Cited by 36 · see citing works
Active surface centres in a heterogeneous CdO catalyst for ethanol decomposition
El‐Salaam, K. M. A., & Hassan, E. A. (1982) · Surface Technology · doi:10.1016/0376-4583(82)90031-0 · Cited by 34 · see citing works
Ethanol conversion over ion-exchanged ZSM-5 zeolites
Bun, S., Nishiyama, S., Tsuruya, S., et al. (1990) · Applied Catalysis · doi:10.1016/s0166-9834(00)82184-3 · Cited by 34 · see citing works
Transition states of catalytic dehydration and dehydrogenation of alcohols
NOLLER, H., & Thomke, K. (1979) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(79)85013-0 · Cited by 33 · see citing works
The Dehydration of Secondary and Tertiary Alcohols
Henne, A. L., & Matuszak, A. H. (1944) · Journal of the American Chemical Society · doi:10.1021/ja01238a012 · Cited by 32 · see citing works
Parametric sensitivity in fixed-bed catalytic reactors
Henning, G. P., & Perez, G. A. (1986) · Chemical Engineering Science · doi:10.1016/0009-2509(86)85200-9 · Cited by 31 · see citing works
DEHYDRATION OF ALCOHOLS OVER ALUMINA
Adkins, H., & Perkins, P. P. (1925) · Journal of the American Chemical Society · doi:10.1021/ja01681a036 · Cited by 31 · see citing works
Fluidized-Bed Combustion Technology
Tavoulareas, E. (1991) · Annual Review of Energy and the Environment · doi:10.1146/annurev.eg.16.110191.000325 · Cited by 24 · see citing works
Phosphoric acid systems. 2. Catalytic conversion of fermentation ethanol to ethylene
PEARSON, D. E., Tanner, R. D., Picciotto, I. D., et al. (1981) · Industrial & Engineering Chemistry Product Research and Development · doi:10.1021/i300004a028 · Cited by 22 · see citing works
Catalytic conversion of alcohols on Al2O3-Cr2O3 catalysts I: The catalytic decomposition of ethanol
Ezzo, E. M., El-Shobaky, G. A., & Selim, M. M. (1980) · Surface Technology · doi:10.1016/0376-4583(80)90068-0 · Cited by 22 · see citing works
Thermal Decomposition of 2-Fluoroethanol: Single Pulse Shock Tube and ab Initio Studies
Rajakumar, B., Reddy, K. P. J., & Arunan, E. (2003) · The Journal of Physical Chemistry A · doi:10.1021/jp027323x · Cited by 21 · see citing works
Thermal decomposition of haloethanols: single pulse shock tube and ab initio studies
Rajakumar, B., Reddy, K. P. J., & Arunan, E. (2005) · Shock Waves · doi:10.1007/978-3-540-27009-6_93 · Cited by 14 · see citing works
Studies on the mixed oxide catalyst Al2O3-Cr2O3 I. Surface properties
Ezzo, E. M., El-Nabarawy, T., & Youssef, A. M. (1979) · Surface Technology · doi:10.1016/0376-4583(79)90051-7 · Cited by 12 · see citing works
Studies of the mixed oxide catalyst Al2O3-Cr2O3 II: The catalytic conversion of ethanol
Ezzo, E. M., Yousef, N. A., & Mazhar, H. S. (1981) · Surface Technology · doi:10.1016/0376-4583(81)90009-1 · Cited by 7 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Sustainable polymers from renewable resources
Zhu, Y., Romain, C., & Williams, C. K. (2016) · Nature · doi:10.1038/nature21001 · Cited by 2,762 · see citing works
Liew, F., Martin, M. E., Tappel, R. C., Heijstra, B. D., Mihalcea, C., & Köpke, M. (2016) · Frontiers in Microbiology · doi:10.3389/fmicb.2016.00694 · Cited by 485 · see citing works
Renewable bio-jet fuel production for aviation: a review
Wei, H., Liu, W., Chen, X., Yang, Q., Li, J., & Chen, H. (2019) · Fuel · doi:10.1016/j.fuel.2019.06.007 · Cited by 435 · see citing works
the alcohol-to-jet conversion pathway for drop-in biofuels: techno-economic evaluation
Geleynse, S., Brandt, K., Garcia‐Perez, M., Wolcott, M., & Zhang, X. (2018) · ChemSusChem · doi:10.1002/cssc.201801690 · Cited by 250 · see citing works
Techno-economic assessment of biorefinery technologies for aviation biofuels supply chains in Brazil
Alves, C. M., Valk, M., de Jong, S., Bonomi, A., van der Wielen, L. A. M., & Mussatto, S. I. (2017) · Biofuels, Bioproducts and Biorefining · doi:10.1002/bbb.1711 · Cited by 87 · see citing works
A Closed‐Loop Recyclable Low‐Density Polyethylene
Unger, C., Schmalz, H., Lipp, J., Kretschmer, W. P., & Kempe, R. (2024) · Advanced Science · doi:10.1002/advs.202307229 · Cited by 23 · see citing works
- Authors
- Zhang, M., & Yu, Y.
- Affiliations
- Tianjin University (CN)
- Corresponding author
- Yu, Yingzhe
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-03
- Volume
- 52
- Issue
- 28
- Pages
- 9505-9514
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2319008145
- Cited by
- 485
- References
- 61
- Citations by year
- 2026: 42 · 2025: 50 · 2024: 39 · 2023: 41 · 2022: 40 · 2021: 33 · 2020: 43 · 2019: 47 · 2018: 38 · 2017: 36 · 2016: 27 · 2015: 30 · 2014: 18 · 2013: 1
- FWCI
- 14.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Industrial & Engineering Chemistry Research (publishedVersion)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Keywords
- ethanol dehydration, ethylene production, molecular sieve catalysts, fluidized bed reactor, reaction mechanism, catalyst stability, process economics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review