Sustainable polymers from renewable resources
Abstract
Renewable resources are used increasingly in the production of polymers. In particular, monomers such as carbon dioxide, terpenes, vegetable oils and carbohydrates can be used as feedstocks for the manufacture of a variety of sustainable materials and products, including elastomers, plastics, hydrogels, flexible electronics, resins, engineering polymers and composites. Efficient catalysis is required to produce monomers, to facilitate selective polymerizations and to enable recycling or upcycling of waste materials. There are opportunities to use such sustainable polymers in both high-value areas and in basic applications such as packaging. Life-cycle assessment can be used to quantify the environmental benefits of sustainable polymers.
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PLA-b-PCL-b-PLA copolymers, resulting in a soft block surrounded by hard ones, are interesting due to their properties as thermoplastic elastomers.
“Especially PLA‐b‐PCL‐b‐PLA copolymers, resulting in a soft block surrounded by hard ones, are interesting due to their properties as thermoplastic elastomers. [12]”
From Master of Chaos and Order: Opposite Microstructures of PCL‐<i>co</i>‐PGA‐<i>co</i>‐PLA Accessible by a Single Catalyst** (2022) · cites this paper as [12]
Terpenes and CO2 are useful feedstocks for polyesters and polycarbonates.
“In addition to these two major classes of biomass, terpenes and CO2 are also useful feedstocks for polyesters and polycarbonates.16,83”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [16]
Plant oil is converted to fatty acids and glycerol for biodiesel and oleochemical production.
“Another common renewable resource is plant oil, which is converted to fatty acids and glycerol for biodiesel and oleochemical production.16,25,81”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [16]
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- Authors
- Zhu, Y., Romain, C., & Williams, C. K.
- Affiliations
- University of Oxford (GB)
- Imperial College London (GB)
- Corresponding author
- Williams, Charlotte K.
- Venue
- Nature
- Published
- 2016-12-14
- Volume
- 540
- Issue
- 7633
- Pages
- 354-362
- ISSN
- 0028-0836 (ISSN-L)
- 1476-4687
- OpenAlex
- W2483057761
- Cited by
- 2,762
- References
- 97
- Citations by year
- 2026: 231 · 2025: 309 · 2024: 324 · 2023: 385 · 2022: 353 · 2021: 315 · 2020: 328 · 2019: 250 · 2018: 189 · 2017: 77
- FWCI
- 9.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nature (publishedVersion)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Spiral (Imperial College London) (submittedVersion)
- Funders
- China Scholarship Council
- Engineering and Physical Sciences Research Council (EP/C544838/1, EP/H046380/1, EP/M013839/1, EP/K035274/1, EP/L017393/1, EP/K014676/1, EP/K014668/1)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Life Sciences › Agricultural and Biological Sciences › General Agricultural and Biological Sciences › Bioeconomy and Sustainability Development
- Keywords
- sustainable polymers, renewable resources, terpenes, vegetable oils, carbohydrates, elastomers, hydrogels, flexible electronics, resins, engineering polymers, composite materials, polymer catalysis, selective polymerization, waste recycling, upcycling, packaging, life cycle assessment
- MeSH terms
- Carbohydrates, Carbon Dioxide, Conservation of Natural Resources, Elasticity, Electronics, Plant Oils, Plants, Plastics, Polymers, Terpenes, Hydrogels
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