NEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFICIENTS
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFICIENTSEdward N. Fuller, Paul D. Schettler, and J. Calvin. GiddingsCite this: Ind. Eng. Chem. 1966, 58, 5, 18–27Publication Date (Print):May 1, 1966Publication History Published online1 May 2002Published inissue 1 May 1966https://pubs.acs.org/doi/10.1021/ie50677a007https://doi.org/10.1021/ie50677a007research-articleACS PublicationsRequest reuse permissionsArticle Views12407Altmetric-Citations1654LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts
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The maximum operating temperature of the membrane is typically 90 °C and should not be exceeded so as to avoid reduced proton mobility through the membrane and flooding due to increased water crossover from the anode.
“The maximum operating temperature of the membrane, is typically 90 °C and should not be exceeded so as to avoid reduced proton mobility through the membrane, [154] as well as flooding due to increased water crossover from the anode.[145,250]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [250]
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“It must be also taken into account that the majority of the data used by Fuller et al. (1966) to obtain their equation was obtained at or under atmospheric pressure.”
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“In Equation (24), Tp and pressure in the SP2 chamber are used as T and Ptotal, respectively. υ is the parameter (without dimensions) for each atom in a molecular constituent (Fuller et al. 1966). υ is 16.5 for C, 1.98 for H, 5.48 for O.”
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“estimated by Fuller-Shettler-Giddings (FSG) empirical equation [33], which can be simplified to the form”
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“…and Coughlin, 1976): t))X(R,ε1)(1(Z ρ f ρεt)ε(R, 0 R Rw, r0 (17) The molecular diffusivity of gas i in N2 was calculated using the equation proposed by Fuller et al. (1966): 2 1/3i1/3A 0.51 i 1 A 1.757 Am, v)(v)( P )M M( T 10D (18) Knudsen diffusivity was calculated using the…”
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“We expect slightly more smoothing in CO2 than in CH4 because the diffusivity of CO2 is smaller than that of CH4 by factor of 1.3 [Fuller et al., 1966].”
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“The temperature dependence of diffusivity was considered using the approach of Fuller et al. (1966): Dfields Dlabs = ( Tfield Tlab )1.75 , (8) where Dsfield is the temperature-corrected effective diffusion coefficient, Dslab the effective diffusion coefficient measured at the laboratory, Tfield the…”
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Singh, R., Sui, P. C., Wong, K. H., Kjeang, E., Knights, S., & Djilali, N. (2018) · Journal of The Electrochemical Society · doi:10.1149/2.0351806jes · Cited by 105 · see citing works
Kinetic study of SO2 removal over lignin-based activated carbon
Rosas, J. M., Ruiz-Rosas, R. R., Rodríguez‐Mirasol, J., & Cordero, T. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.08.111 · Cited by 104 · see citing works
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Multiphase porous media modelling: A novel approach to predicting food processing performance
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“A similar equation was proposed by Fuller et al. (1966) to determine the binary diffusion coefficient, as shown below: DAW D 10¡ 3T1:75f Mw CMA MwMA P P vð Þ13v C P vð Þ13a h i2 0:5 (2) where Tf is the arithmetic average temperature between the surface temperature of the material and ambient…”
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Sohaib, Q., Gómez‐Coma, L., Albo, J., et al. (2019) · Separation and Purification Technology · doi:10.1016/j.seppur.2019.115986 · Cited by 101 · see citing works
- Authors
- Fuller, E. N., Schettler, P. D., & Giddings, J. C.
- Venue
- Industrial & Engineering Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1966-05-01
- Volume
- 58
- Issue
- 5
- Pages
- 18-27
- ISSN
- 0019-7866 (ISSN-L)
- 1541-5724
- OpenAlex
- W2075886908
- Cited by
- 2,515
- References
- 0
- Citations by year
- 2026: 141 · 2025: 141 · 2024: 160 · 2023: 130 · 2022: 148 · 2021: 136 · 2020: 134 · 2019: 124 · 2018: 113 · 2017: 108 · 2016: 101 · 2015: 81 · 2014: 99 · 2013: 71 · 2012: 99
- FWCI
- 2.12
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Industrial & Engineering Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Spectroscopy › Diffusion Coefficients in Liquids
- Physical Sciences › Chemistry › Spectroscopy › Adsorption, diffusion, and thermodynamic properties of materials
- Physical Sciences › Mathematics › Applied Mathematics › Gas Dynamics and Kinetic Theory
- Keywords
- diffusion coefficient, forecasting methods, gas mixtures, transport properties
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