The DOI matches its Crossref record.
Kinetic and Heat Transfer Control in the Slow and Flash Pyrolysis of Solids
Abstract
The coupled effects of particle size and external heating conditions (reactor heating rate and final temperature) on cellulose pyrolysis are investigated by means of a computer model accounting for all main transport phenomena, variable thermophysical properties and primary, and secondary reaction processes. The dynamics of particle conversion are predicted, and final product distributions are favorably compared with experimental measurements. A map is constructed, in terms of particle size as a function of the reactor temperature, to identify the transition from a kinetically controlled conversion to a heat transfer controlled conversion (thermally thin and thermally thick regimes) and from flash to slow-conventional pyrolysis. Conditions for maximizing oil, gas, or char yields are also discussed.
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Citations
Cited by
Modeling chemical and physical processes of wood and biomass pyrolysis
DIBLASI, C. (2008) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2006.12.001 · Cited by 1,752
An overview of advances in biomass gasification
Sikarwar, V. S., Zhao, M., Clough, P., Yao, J., Zhong, X., Memon, M. Z., Shah, N., Anthony, E. J., & Fennell, P. S. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00935b · Cited by 1,258
Kinetics and Mechanism of Cellulose Pyrolysis
Lin, Y.-C., Cho, J., Tompsett, G. A., Westmoreland, P. R., & Huber, G. W. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp906702p · Cited by 698
Dogu, O., Pelucchi, M., Van de Vijver, R., Van Steenberge, P. H. M., D'hooge, D. R., Cuoci, A., Mehl, M., Frassoldati, A., Faravelli, T., & Van Geem, K. M. (2021) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100901 · Cited by 698
Biomass pyrolysis-a review of modelling, process parameters and catalytic studies
Sharma, A., Pareek, V., & Zhang, D. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.04.193 · Cited by 675
Product Distribution from Pyrolysis of Wood and Agricultural Residues
Di Blasi, C., Signorelli, G., Di Russo, C., & Rea, G. (1999) · Industrial & Engineering Chemistry Research · doi:10.1021/ie980711u · Cited by 441
Self-citationGhodake, G. S., Shinde, S. K., Kadam, A. A., Saratale, R. G., Saratale, G. D., Kumar, M., Palem, R. R., AL-Shwaiman, H. A., Elgorban, A. M., Syed, A., et al. (2021) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2021.126645 · Cited by 414
MILLER, R. S., & BELLAN, J. (1997) · Combustion Science and Technology · doi:10.1080/00102209708935670 · Cited by 388
Cellulose Pyrolysis Kinetics: Revisited
Antal, M. J., Várhegyi, G., & Jakab, E. (1998) · Industrial & Engineering Chemistry Research · doi:10.1021/ie970144v · Cited by 323
Brown, A. L., Dayton, D. C., Nimlos, M. R., & Daily, J. W. (2001) · Energy & Fuels · doi:10.1021/ef010083k · Cited by 69
Effects of pyrolysis conditions and ash formation on gasification rates of biomass char
Strandberg, A., Holmgren, P., Wagner, D. R., Molinder, R., Wiinikka, H., Umeki, K., & Broström, M. (2017) · Energy & Fuels · doi:10.1021/acs.energyfuels.7b00688 · Cited by 48
Lebrun Thauront, J., Soja, G., Schmidt, H., & Abiven, S. (2024) · GCB Bioenergy · doi:10.1111/gcbb.13170 · Cited by 15
“This affects the particle temperature throughout the pyrolysis process (Di Blasi, 1996; Koufopanos et al., 1991; Park et al., 2010; Pyle & Zaror, 1984; Siddiqi et al., 2020; Simmons & Gentry, 1986).”
Metadata
- Authors
- Di Blasi, C.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 35
- Issue
- 1
- Pages
- 37-46
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W1975283685
- Cited by
- 230
- References
- 0
- FWCI
- 9.34
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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