Characterization of hydrous species in minerals by high-speed proton MAS-NMR
Abstract
Proton magic-angle spinning (MAS) NMR at 200 and 500 MHz and at high spinning speeds (ca. 8 kHz) has been used to characterize hydrous species, both stoichiometric and nonstoichiometric, in a variety of minerals. High-resolution \n^1H MAS-NMR spectra of minerals containing stoichiometric hydroxyl groups as the only hydrous species are obtainable provided that the hydrogen density in the sample is less than about 15 atoms/nm^3. Structurally isolated water molecules in analcite, NaAlSi_2O_6•H_2O, and gypsum, CaSO_4•2H_2O, yield characteristic ^1H MAS-NMR spectra with numerous spinning sidebands extending over a range of about 100 kHz, reflecting the strong, largely inhomogeneous character of the homonuclear dipolar coupling. The field dependence of both line widths and spinning sideband patterns provides evidence about the nature of the \nbroadening interactions. Lawsonite and hemimorphite, minerals containing stoichiometric amounts of both OH and H_2O groups, yield spectra with numerous intense spinning sidebands; strong dipolar interactions preclude discrimination of OH and H_2O. \nNonstoichiometric hydrogen in nominally anhydrous minerals (feldspars, nepheline, quartz, and grossular garnet) is found to occur in a variety of forms: mobile H_2O in fluid inclusions, anisotropically constrained, isolated H_2O molecules, and clustered species consistent with H_4O_4^(4-) groups in a hydrogarnet substitution.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The water associated with 13C in milled wollastonite is rigidly bound structural water, not fluid inclusions or surface sorbed.
“the strong sideband pattern presented indicates that the water is rigidly bound structural water and not fluid inclusions or surface sorbed [38, 39].”
From Mechanochemical formation of highly stable amorphous calcium carbonate in calcium silicates: Potential long-term storage of CO2 in cement (2024) · cites this paper as [39]
Cites
Still being checked.
Cited by
Sorted by citations
Matulonis, U. A., Shapira‐Frommer, R., Santin, A. D., Lisyanskaya, A. S., Pignata, S., Vergote, I. B., Raspagliesi, F., Sonke, G. S., Birrer, M. J., Provencher, D. M., et al. (2019) · Annals of Oncology · doi:10.1093/annonc/mdz135 · Cited by 856 · see citing works
Mg/Al Ordering in Layered Double Hydroxides Revealed by Multinuclear NMR Spectroscopy
Sideris, P. J., Nielsen, U. G., Gan, Z., & Grey, C. P. (2008) · Science · doi:10.1126/science.1157581 · Cited by 676 · see citing works
Properties of magnesium silicate hydrates (M-S-H)
Nied, D., Enemark‐Rasmussen, K., L’Hôpital, E., Skibsted, J., & Lothenbach, B. (2015) · Cement and Concrete Research · doi:10.1016/j.cemconres.2015.10.003 · Cited by 394 · see citing works
Structural characterization of noncrystalline solids and glasses using solid state NMR
Eckert, H. (1992) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/0079-6565(92)80001-v · Cited by 392 · see citing works
Self-citationApplications of high-resolution 1H solid-state NMR
Brown, S. P. (2011) · Solid State Nuclear Magnetic Resonance · doi:10.1016/j.ssnmr.2011.11.006 · Cited by 329 · see citing works
Citrate bridges between mineral platelets in bone
Davies, E., Müller, K. H., Wong, W. C., Pickard, C. J., Reid, D. G., Skepper, J. N., & Duer, M. J. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1315080111 · Cited by 280 · see citing works
Jiang, Y., Huang, J., Dai, W., & Hunger, M. (2011) · Solid State Nuclear Magnetic Resonance · doi:10.1016/j.ssnmr.2011.03.007 · Cited by 258 · see citing works
Structural Characteristics of Synthetic Amorphous Calcium Carbonate
Michel, F. M., MacDonald, J., Feng, J., Phillips, B. L., Ehm, L., Tarabrella, C., Parise, J. B., & Reeder, R. J. (2008) · Chemistry of Materials · doi:10.1021/cm800324v · Cited by 241 · see citing works
Guillaume Renaudin, A., Russias, J., Leroux, F., Coumes, C. C. D., & Frizon, F. (2009) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2009.09.024 · Cited by 218 · see citing works
Calculation of magic-angle spinning nuclear magnetic resonance spectra of paramagnetic solids
Nayeem, A., & Yesinowski, J. P. (1988) · The Journal of Chemical Physics · doi:10.1063/1.454800 · Cited by 164 · see citing works
Self-citationXue, X., & Kanzaki, M. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.08.016 · Cited by 150 · see citing works
General aspects of zeolite acidity characterization
Sandoval-Díaz, L.-E., Gonzalez‐Amaya, J., & Trujillo, C. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.04.038 · Cited by 146 · see citing works
The concentration and speciation of hydrogen in feldspars using FTIR and 1 H MAS NMR spectroscopy
Johnson, E. A., & Rossman, G. R. (2003) · American Mineralogist · doi:10.2138/am-2003-5-620 · Cited by 145 · see citing works
Self-citationSolid-state NMR investigations on the nature of hydrogen bonds
Brunner, E., & Sternberg, U. (1998) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/s0079-6565(97)00018-6 · Cited by 144 · see citing works
Li, J., Zhou, X., Wang, F., Ning, X., Wen, Y., Song, B., Yang, C., Wu, D., Ke, X., & Peng, L. (2022) · Nature Communications · doi:10.1038/s41467-022-33912-7 · Cited by 131 · see citing works
Analytical Methods for Measuring Water in Nominally Anhydrous Minerals
Rossman, G. R. (2006) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2006.62.1 · Cited by 129 · see citing works
Self-citationMason, H. E., Du Frane, W. L., Walsh, S. D. C., Dai, Z., Charnvanichborikarn, S., & Carroll, S. A. (2013) · Environmental Science & Technology · doi:10.1021/es3039906 · Cited by 128 · see citing works
A structural consideration of kanemite, octosilicate, magadiite and kenyaite
Almond, G. G., Harris, R. K., & Franklin, K. R. (1997) · Journal of Materials Chemistry · doi:10.1039/a606856a · Cited by 119 · see citing works
Defects in structure as the sources of the surface charges of kaolinite
Zhu, X., Zhu, Z., Lei, X., & Yan, C. (2016) · Applied Clay Science · doi:10.1016/j.clay.2016.01.033 · Cited by 108 · see citing works
Effect of water on the phase relations in Earth's mantle and deep water cycle
Litasov, K. D., & Ohtani, E. (2007) · Geological Society of America eBooks · doi:10.1130/2007.2421(08 · Cited by 102 · see citing works
Xue, X., & Kanzaki, M. (2009) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2009.03468.x · Cited by 99 · see citing works
Charoy, B., de Donato, P., Barrès, O., & Pinto-Coelho, C. V. (1996) · American Mineralogist · doi:10.2138/am-1996-3-414 · Cited by 98 · see citing works
Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates
Sangodkar, R. P., Smith, B. J., Gajan, D., Rossini, A. J., Roberts, L. R., Funkhouser, G. P., Lesage, A., Emsley, L., & Chmelka, B. F. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00622 · Cited by 97 · see citing works
Polymerization of Silicates in Layered Double Hydroxides
Depège, C., METOUI, F. ‐. E., Forano, C., Roy, A., Dupuis, J., & Besse, J. P. (1996) · Chemistry of Materials · doi:10.1021/cm950533k · Cited by 94 · see citing works
Dehydration, Dehydroxylation, and Rehydroxylation of Single-Walled Aluminosilicate Nanotubes
Kang, D., Zang, J., Wright, E., McCanna, A. L., Jones, C. W., & Nair, S. (2010) · ACS Nano · doi:10.1021/nn101211y · Cited by 93 · see citing works
Kim, H. N., & Lee, S. K. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.05.047 · Cited by 92 · see citing works
Single-Walled Aluminosilicate Nanotube/Poly(vinyl alcohol) Nanocomposite Membranes
Kang, D., Tong, H. M., Zang, J., Choudhury, R. P., Sholl, D. S., Beckham, H. W., Jones, C. W., & Nair, S. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am201614w · Cited by 86 · see citing works
High-resolution magic-angle-spinning NMR spectra of protons in deuterated solids
McDermott, A. E., Creuzet, F., Kolbert, A. C., & Griffin, R. G. (1992) · Journal of Magnetic Resonance (1969) · doi:10.1016/0022-2364(92)90141-s · Cited by 85 · see citing works
Xue, X., & Kanzaki, M. (2007) · The Journal of Physical Chemistry B · doi:10.1021/jp073968r · Cited by 84 · see citing works
Acid and Base Catalysis on Zeolites
Weitkamp, J., & Hunger, M. (2007) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(07)80810-x · Cited by 83 · see citing works
Brunner, E. (1995) · Journal of Molecular Structure · doi:10.1016/0022-2860(95)08867-u · Cited by 81 · see citing works
Zeng, Q., Nekvasil, H., & Grey, C. P. (1999) · The Journal of Physical Chemistry B · doi:10.1021/jp990726l · Cited by 80 · see citing works
Periodicity of amide proton exchange rates in a coiled-coil leucine zipper peptide
Goodman, E. M., & Kim, P. S. (1991) · Biochemistry · doi:10.1021/bi00114a002 · Cited by 80 · see citing works
Solubility of H 2 O in nominally anhydrous mantle minerals using 1 H MAS NMR
Kohn, S. C. (1996) · American Mineralogist · doi:10.2138/am-1996-11-1224 · Cited by 77 · see citing works
Mason, H. E., McCubbin, F. M., Smirnov, A., & Phillips, B. L. (2009) · American Mineralogist · doi:10.2138/am.2009.3095 · Cited by 72 · see citing works
Hou, G., Paramasivam, S., Yan, S., Polenova, T. E., & Vega, A. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3084972 · Cited by 72 · see citing works
Water contents of pyroxenes in intraplate lithospheric mantle
Bonadiman, C., Hao, Y., Coltorti, M., Dallai, L., Faccini, B., & Huang, Y. X. (2009) · European Journal of Mineralogy · doi:10.1127/0935-1221/2009/0021-1935 · Cited by 71 · see citing works
A 31P and 1H MAS NMR study of phosphate sorption onto calcium carbonate
Hinedi, Z. R., Goldberg, S., Chang, A. C., & Yesinowski, J. P. (1992) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(92)90015-e · Cited by 71 · see citing works
Self-citationLi, Z., Khimyak, Y. Z., & Taubert, A. (2008) · Materials · doi:10.3390/ma1010003 · Cited by 68 · see citing works
Residual linewidths of NMR spectra of - systems under magic-angle spinning
Brunner, E., Freude, D., Gerstein, B. C., & Pfeifer, H. (1990) · Journal of Magnetic Resonance (1969) · doi:10.1016/0022-2364(90)90367-i · Cited by 68 · see citing works
Mantle Volatiles—Distribution and Consequences
Luth, R. W. (2003) · Elsevier eBooks · doi:10.1016/b0-08-043751-6/02124-1 · Cited by 67 · see citing works
Hydrous species in feldspars: A reassessment based on FTIR and SIMS
Mosenfelder, J. L., Rossman, G. R., & Johnson, E. A. (2015) · American Mineralogist · doi:10.2138/am-2015-5034 · Cited by 64 · see citing works
Self-citationKeppler, H., & Rauch, M. (2000) · Physics and Chemistry of Minerals · doi:10.1007/s002699900070 · Cited by 63 · see citing works
Lee, J., Lee, W., Kang, K., Lee, T., & Lee, S. K. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c04078 · Cited by 62 · see citing works
Ultrahydrous stishovite from high-pressure hydrothermal treatment of SiO 2
Spektor, K., Nylén, J., Stoyanov, E., Navrotsky, A., Hervig, R. L., Leinenweber, K. D., Holland, G. P., & Häußermann, U. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1117152108 · Cited by 62 · see citing works
Wu, G., Freure, C. J., & Verdurand, E. (1998) · Journal of the American Chemical Society · doi:10.1021/ja983126t · Cited by 62 · see citing works
Solid State NMR of Porous Materials
Koller, H., & Weiß, M. (2011) · Topics in current chemistry · doi:10.1007/128_2011_123 · Cited by 59 · see citing works
Ordering of hydroxyl defects in hydrous wadsleyite (β-Mg 2 SiO 4 )
Kohn, S. C., Brooker, R. A., Frost, D. J., Slesinger, A. E., & Wood, B. J. (2002) · American Mineralogist · doi:10.2138/am-2002-2-310 · Cited by 59 · see citing works
Solid-State NMR Study of the Role of H and Na in AB-Type Carbonate Hydroxylapatite
Mason, H. E., Kozlowski, A., & Phillips, B. L. (2007) · Chemistry of Materials · doi:10.1021/cm0716598 · Cited by 59 · see citing works
Gu, Z., Ridenour, C. F., Bronnimann, C. E., Iwashita, T., & McDermott, A. E. (1996) · Journal of the American Chemical Society · doi:10.1021/ja952130r · Cited by 59 · see citing works
Tonarini, S., Forte, C., Petrini, R., & Ferrara, G. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(02)00987-0 · Cited by 58 · see citing works
Xue, X., & Kanzaki, M. (2006) · Solid State Nuclear Magnetic Resonance · doi:10.1016/j.ssnmr.2006.11.001 · Cited by 58 · see citing works
Speciation of Silanol Groups in Precipitated Silica Nanoparticles by 1H MAS NMR Spectroscopy
Hartmeyer, G., Marichal, C., Lebeau, B., Rigolet, S., Caullet, P., & Hernandez, J. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp071490l · Cited by 55 · see citing works
29 Si and 1 H NMR spectroscopy of high-pressure hydrous magnesium silicates
Phillips, B. L., Burnley, P. C., Worminghaus, K., & Navrotsky, A. (1997) · Physics and Chemistry of Minerals · doi:10.1007/s002690050031 · Cited by 54 · see citing works
Tanner, S. F., Hills, B. P., & Parker, R. (1991) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9918702613 · Cited by 54 · see citing works
One- and two-dimensional 1H magic-angle spinning experiments on hydrous silicate glasses
Schaller, T., & Sebald, A. (1995) · Solid State Nuclear Magnetic Resonance · doi:10.1016/0926-2040(95)00028-o · Cited by 54 · see citing works
Duma, L., Abergel, D., Tékély, P., & Bodenhausen, G. (2008) · Chemical Communications · doi:10.1039/b801154k · Cited by 53 · see citing works
NMR Spectroscopy of Inorganic Earth Materials
Stebbins, J. F., & Xue, X. (2014) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2014.78.15 · Cited by 52 · see citing works
Solid-state NMR spectroscopy for the analysis of element-based non-covalent interactions
Xu, Y., Szell, P. M. J., Kumar, V., & Bryce, D. L. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213237 · Cited by 52 · see citing works
Observation of bicarbonate in calcite by NMR spectroscopy
Feng, J. (2006) · American Mineralogist · doi:10.2138/am.2006.2206 · Cited by 51 · see citing works
Xue, X. (2006) · American Mineralogist · doi:10.2138/am.2006.2064 · Cited by 50 · see citing works
Fe(III) Docking-Activated Sites in Layered Birnessite for Efficient Water Oxidation
Ju, M., Chen, Z., Zhu, H. M., Cai, R., Lin, Z., Chen, Y., Wang, Y., Gao, J., Long, X., & Yang, S. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c01181 · Cited by 49 · see citing works
Kim, G., Blanc, F., Hu, Y., & Grey, C. P. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp312410t · Cited by 48 · see citing works
Brunner, E. (1990) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9908603957 · Cited by 48 · see citing works
Proton and carbon NMR measurements of the effects of hydration on the wheat protein ω-gliadin
Belton, P. S., Gil, A. M., Grant, A., Alberti, E., & Tatham, A. S. (1998) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/s1386-1425(98)00025-0 · Cited by 45 · see citing works
Investigation of the water sorption properties of Mars-relevant micro- and mesoporous minerals
Jänchen, J., Bish, D. L., Möhlmann, D., & Stach, H. (2005) · Icarus · doi:10.1016/j.icarus.2005.10.010 · Cited by 45 · see citing works
Proton MAS NMR studies of hydroxyl groups in alkaline earth cation-exchanged zeolite Y
Hunger, M., Freude, D., Pfeifer, H., Prager, D., & Reschetilowski, W. (1989) · Chemical Physics Letters · doi:10.1016/0009-2614(89)80039-9 · Cited by 44 · see citing works
Phosphorus speciation in calcite speleothems determined from solid-state NMR spectroscopy
Mason, H. E., Frisia, S., Tang, Y., Reeder, R. J., & Phillips, B. L. (2007) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2006.11.040 · Cited by 44 · see citing works
Catalytically Active Sites: Generation and Characterization
Hunger, M. (2010) · Wiley eBooks · doi:10.1002/9783527630295.ch17 · Cited by 44 · see citing works
Preferential Siting of Aluminum Heteroatoms in the Zeolite Catalyst Al‐SSZ‐70
Berkson, Z. J., Hsieh, M., Smeets, S., Gajan, D., Lund, A., Lesage, A., Xie, D., Zones, S. I., McCusker, L. B., Baerlocher, C., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813533 · Cited by 43 · see citing works
Li, B., Li, N., Brouwers, H. J. H., Yu, Q., & Chen, W. (2019) · Construction and Building Materials · doi:10.1016/j.conbuildmat.2019.117347 · Cited by 43 · see citing works
Nanocrystalline CaF2 particles obtained by high-energy ball milling
Scholz, G., Dörfel, I., Heidemann, D., Feist, M., & Stößer, R. (2006) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2005.12.035 · Cited by 43 · see citing works
High Resolution Solid-State 1H Nmr Studies of Zeolites
Freude, D. (1989) · Studies in surface science and catalysis · doi:10.1016/s0167-2991(08)60523-6 · Cited by 43 · see citing works
Brunner, E. (1993) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9938900165 · Cited by 42 · see citing works
Kao, H., Grey, C. P., Pitchumani, K., Lakshminarasimhan, P., & Ramamurthy, V. (1998) · The Journal of Physical Chemistry A · doi:10.1021/jp980385w · Cited by 42 · see citing works
Formation of hydroxylapatite from co-sorption of phosphate and calcium by boehmite
Li, W., Xu, W., Parise, J. B., & Phillips, B. L. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.02.021 · Cited by 41 · see citing works
Investigating Local Structure in Layered Double Hydroxides with 17O NMR Spectroscopy
Zhao, L., Qi, Z., Blanc, F., Yu, G., Wang, M., Xue, N., Ke, X., Guo, X., Ding, W., Grey, C. P., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201301157 · Cited by 41 · see citing works
Comparative structural investigation of aluminium fluoride solvates
Kemnitz, E., Groß, U., Rüdiger, S., Scholz, G., Heidemann, D., Troyanov, S. I., Morosov, I. V., & Lemée-Cailleau, M. H. (2006) · Solid State Sciences · doi:10.1016/j.solidstatesciences.2006.07.008 · Cited by 41 · see citing works
Hung, L., Kao, H., & Lii, K. (2000) · Chemistry of Materials · doi:10.1021/cm000255b · Cited by 39 · see citing works
Wiebcke, M., Grube, M., Koller, H., Engelhardt, G., & Felsche, J. (1993) · Microporous Materials · doi:10.1016/0927-6513(93)80062-y · Cited by 38 · see citing works
Superacidity and Spectral Signatures of Hydroxyl Groups in Zeolites
Vayssilov, G. N., Aleksandrov, H. A., Dib, E., Medeiros-Costa, I. C., Nesterenko, N., & Mintova, S. (2022) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2022.112144 · Cited by 37 · see citing works
Dyballa, M., Obenaus, U., Lang, S., Gehring, B., Traa, Y., Koller, H., & Hunger, M. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.03.030 · Cited by 37 · see citing works
Zeng, Q., Stebbins, J. F., Heaney, A. D., & Erdogan, T. (1999) · Journal of Non-Crystalline Solids · doi:10.1016/s0022-3093(99)00516-5 · Cited by 37 · see citing works
High-resolution 1H MAS NMR spectra of 2∶1 phyllosilicates
Alba, M. D., Becerro, A. I., Arroyo, M. Á. C., & Perdigón, A. C. (2000) · Chemical Communications · doi:10.1039/a906577f · Cited by 36 · see citing works
Structural and Motional Features of a Layered Sodium Hydrous Silicate as Revealed by Solid State NMR
Gardiennet, C., & Tékély, P. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0256443 · Cited by 35 · see citing works
König, R., Scholz, G., Pawlik, A., Jäger, C., van Rossum, B., Oschkinat, H., & Kemnitz, E. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804662f · Cited by 34 · see citing works
Buannic, L., Sperrin, L., Dervişoğlu, R., Blanc, F., & Grey, C. P. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp08523k · Cited by 33 · see citing works
Solid-state NMR analysis of Fe-bearing minerals: implications and applications for Earth sciences
Bégaudeau, K., Morizet, Y., Florian, P., Paris, M., & Mercier, J. (2012) · European Journal of Mineralogy · doi:10.1127/0935-1221/2012/0024-2192 · Cited by 33 · see citing works
Hydrogen in “anhydrous” minerals
Rossman, G. R. (1990) · Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms · doi:10.1016/0168-583x(90)90780-x · Cited by 32 · see citing works
Self-citationProtons in the magnesium phosphates phosphoellenbergerite and holtedahlite; an IR and NMR study
Brunet, F., & Schaller, T. (1996) · American Mineralogist · doi:10.2138/am-1996-3-413 · Cited by 32 · see citing works
Dervişoğlu, R., Middlemiss, D. S., Blanc, F., Lee, Y., Morgan, D. D., & Grey, C. P. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00328 · Cited by 31 · see citing works
The influence of homonuclear dipolar interaction on the residual linewidths of MAS NMR spectra
Brunner, E., Fenzke, D., Freude, D., & Pfeifer, H. (1990) · Chemical Physics Letters · doi:10.1016/0009-2614(90)85653-t · Cited by 31 · see citing works
Xue, X., Kanzaki, M., Turner, D., & Loroch, D. (2017) · American Mineralogist · doi:10.2138/am-2017-5878 · Cited by 31 · see citing works
Moran, L. B., Berkowitz, J. K., & Yesinowski, J. P. (1992) · Physical review. B, Condensed matter · doi:10.1103/physrevb.45.5347 · Cited by 31 · see citing works
Self-citationAssembly Chemistry of Anion-intercalated Layered Materials
Duan, X., Lu, J. G., & Evans, D. G. (2010) · Elsevier eBooks · doi:10.1016/b978-0-444-53599-3.10017-4 · Cited by 30 · see citing works
Brunet, F., Charpentier, T., Caër, S. L., & Renault, J. (2008) · Solid State Nuclear Magnetic Resonance · doi:10.1016/j.ssnmr.2007.12.001 · Cited by 29 · see citing works
Gindele, M. B., Vinod-Kumar, S., Rochau, J., Boemke, D., Groß, E., Redrouthu, V. S., Gebauer, D., & Mathies, G. (2024) · Nature Communications · doi:10.1038/s41467-023-44381-x · Cited by 28 · see citing works
Lesnichin, S. B., Shenderovich, I. G., Muljati, T., Silverman, D. N., & Limbach, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203478j · Cited by 28 · see citing works
Pandey, M. K., & Nishiyama, Y. (2015) · Journal of Magnetic Resonance · doi:10.1016/j.jmr.2015.10.015 · Cited by 28 · see citing works
Computational and Experimental 1H-NMR Study of Hydrated Mg-Based Minerals
Sorte, E. G., Rimsza, J., & Alam, T. M. (2020) · Molecules · doi:10.3390/molecules25040933 · Cited by 27 · see citing works
- Authors
- Yesinowski, J. P., Eckert, H., & Rossman, G. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1988-03
- Volume
- 110
- Issue
- 5
- Pages
- 1367-1375
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2026899018
- Cited by
- 200
- References
- 0
- Citations by year
- 2025: 2 · 2024: 3 · 2023: 5 · 2022: 5 · 2021: 5 · 2020: 6 · 2019: 7 · 2018: 4 · 2017: 7 · 2016: 2 · 2015: 12 · 2014: 8 · 2013: 7 · 2012: 5
- FWCI
- 4.09
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Spectroscopy › Advanced NMR Techniques and Applications
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Physical Sciences › Physics and Astronomy › Nuclear and High Energy Physics › NMR spectroscopy and applications
- Keywords
- hydrous minerals, hydroxyl groups, water molecules, analcime, gypsum, lawsonite, hemimorphite, fluid inclusions, hydrogarnet, feldspar, nepheline, grossular garnet, spinning sidebands, dipolar coupling, hydrogen density
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
