Cited by 71Chemical Reaction MechanismsOrganic Chemistry Cycloaddition ReactionsAtmospheric chemistry and aerosols

Rates and mechanisms of reactions of nitrogen dioxide with alkenes in solution

Giamalva, David H., Kenion, Grant B., Church, Daniel F., Pryor, William A.·1987·Journal of the American Chemical Society

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRates and mechanisms of reactions of nitrogen dioxide with alkenes in solutionDavid H. Giamalva, Grant B. Kenion, Daniel F. Church, and William A. PryorCite this: J. Am. Chem. Soc. 1987, 109, 23, 7059–7063Publication Date (Print):November 1, 1987Publication History Published online1 May 2002Published inissue 1 November 1987https://pubs.acs.org/doi/10.1021/ja00257a025https://doi.org/10.1021/ja00257a025research-articleACS PublicationsRequest reuse permissionsArticle Views364Altmetric-Citations56LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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  • In carbon tetrachloride, the conjugated diene 2,5-dimethyl-2,4-hexadiene is 10^4-10^6 more reactive than monoalkenes.

    “In carbon tetrachloride, the conjugated diene 2,5-dimethyl-2,4-hexadiene is 10 4 -10 6 more reactive than monoalkenes (40), reinforcing that there will be a preferential reaction of ⅐ NO 2 with CLA rather than bis-allylic dienes, even when conjugated dienes are present in ϳ100-fold lower concentrations than other bis-allylic unsaturated fatty acids in plasma (41).”

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Authors
Giamalva, D. H., Kenion, G. B., Church, D. F., & Pryor, W. A.
Venue
Journal of the American Chemical Society
Published
1987-11
Volume
109
Issue
23
Pages
7059-7063
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W78754257
Cited by
71
References
0
Citations by year
2025: 2 · 2024: 1 · 2023: 1 · 2022: 1 · 2021: 1 · 2019: 3 · 2018: 1 · 2016: 1 · 2015: 4 · 2014: 1 · 2013: 1 · 2012: 3
FWCI
1.08
Type
journal article
Language
en
Open access
closed
Locations
Journal of the American Chemical Society (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
  • Physical Sciences › Chemistry › Organic Chemistry › Organic Chemistry Cycloaddition Reactions
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
Keywords
nitrogen dioxide, alkenes, reaction rate, reaction mechanism, solution-phase reactions, nitrosation, nitration, electrophilic addition

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