Phosphorus ligand exchange equilibriums on zerovalent nickel. Dominant role for steric effects
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhosphorus ligand exchange equilibriums on zerovalent nickel. Dominant role for steric effectsChadwick A. TolmanCite this: J. Am. Chem. Soc. 1970, 92, 10, 2956–2965Publication Date (Print):May 1, 1970Publication History Published online1 May 2002Published inissue 1 May 1970https://pubs.acs.org/doi/10.1021/ja00713a007https://doi.org/10.1021/ja00713a007research-articleACS PublicationsRequest reuse permissionsArticle Views6526Altmetric-Citations638LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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These include relationships between catalysis or ligand binding and the steric bulk of a ligand.
“These include relationships between catalysis or ligand binding and the steric bulk [e.g., Tolman cone angle (77,78) or buried volume (79)] of a ligand.”
From Machine Learning for the Discovery, Design, and Engineering of Materials. (2022) · cites this paper as [77]
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- Authors
- Tolman, C. A.
- Corresponding author
- Tolman, Chadwick A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1970-05
- Volume
- 92
- Issue
- 10
- Pages
- 2956-2965
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1973723982
- Cited by
- 754
- References
- 0
- Citations by year
- 2026: 13 · 2025: 15 · 2024: 22 · 2023: 28 · 2022: 19 · 2021: 27 · 2020: 24 · 2019: 21 · 2018: 15 · 2017: 27 · 2016: 17 · 2015: 16 · 2014: 18 · 2013: 16 · 2012: 16
- FWCI
- 17.50
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Keywords
- phosphine ligands, ligand exchange, steric effects, nickel phosphine complexes, exchange equilibria, coordination chemistry
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