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Carbon‐Hydrogen‐Transition Metal Bonds

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Covalent transition metal, lanthanide, and actinide tetrahydroborate complexes

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Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes

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Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins

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Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution

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Directed lithiation of aromatic tertiary amides: an evolving synthetic methodology for polysubstituted aromatics

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Methane exchange reactions of lanthanide and early-transition-metal methyl complexes

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Computer derivation of the symmetry elements implied in a structure description

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Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligands

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Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene

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Highly reactive organolanthanides. A mechanistic study of catalytic olefin hydrogenation by bis(pentamethylcyclopentadienyl) and related 4f complexes

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Recent advances in the chemistry of carborane metal complexes incorporating d- and f-block elements

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MISSYM1.1 – a flexible new release

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Facile C–H activation by lutetium–methyl and lutetium–hydride complexes

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Reactions of yttrium-carbon bonds with active hydrogen-containing molecules. A useful synthetic method for permethylyttrocene derivatives

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Synthesis of monomeric permethylyttrocene derivatives. The crystal structures of Cp2*YN(SiMe3)2 and Cp2*YCH(SiMe3)2

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Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts

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Insertion and C−H Bond Activation of Unsaturated Substrates by Bis(benzamidinato)yttrium Alkyl, [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(SiMe3)2), and Hydrido, {[PhC(NSiMe3)2]2Y(μ-H)}2, Compounds

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Chemistry of cationic zirconium(IV) benzyl complexes. One-electron oxidation of d0 organometallics

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Preparation of N,N,N′-tris(trimethylsilyl)amidines; a convenient route to unsubstituted amidines

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Organolanthanide-catalyzed hydroboration of olefins

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Stereoselection effects in the catalytic hydroamination/cyclization of amino olefins at chiral organolanthanide centers

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Efficient new synthetic route to bidentate, monomeric cyclopentadienyl-amide complexes of Group 4 transition metals: synthesis and characterization of the zirconium and hafnium complexes [[.eta.5:.sigma.-C5H4(CH2)3NMe]MX2(NHMe2)] (X = Cl, I, M = Zr; X = I, M = Hf) and [[.eta.5:.sigma.-C5H4(CH2)3NMe]ZrX2] (X = NMe2, CH2Ph, CH2SiMe3, BH4) and molecular structure of [[.eta.5:.sigma.-C5H4(CH2)3NMe]ZrCl(CH2Ph)]2

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Reactivity of samarium complex [(C5Me5)2Sm(.mu.-H)]2 in ether and arene solvents. X-ray crystal structures of the internally metalated complex (C5Me5)2Sm(.mu.-H)(.mu.-CH2C5Me4)Sm(C5Me5), the benzyl complex (C5Me5)2Sm(CH2C6H5)(THF), and the siloxide complex [(C5Me5)2Sm(THF)]2(.mu.-OSiMe2OSiMe2O)

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Organolanthanide hydride chemistry. 1. Synthesis and x-ray crystallographic characterization of dimeric organolanthanide and organoyttrium hydride complexes

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Manipulation of organolanthanide coordinative unsaturation. Synthesis, structures, structural dynamics, comparative reactivity, and comparative thermochemistry of dinuclear .mu.-hydrides and .mu.-alkyls with [.mu.-R2Si(Me4C5)(C5H4)]2 supporting ligation

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Organometallic Lanthanide Chemistry

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Bis(trimethylsilyl)benzamidinate: a promising spectator ligand in organoyttrium chemistry. Synthesis and reactivity of {[C6H5C(NSiMe3)2]2Y-.mu.-R}2 (R = H, C.tplbond.CH) and x-ray structure of {[C6H5C(NSiMe3)2]2Y-.mu.-C.tplbond.CH}2

Duchateau, R., van Wee, C. T., Meetsma, A., et al. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00064a081 · Cited by 167 · see citing works

Statistics of derived intensities

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Iso-specific Ziegler-Natta polymerization of .alpha.-olefins with a single-component organoyttrium catalyst

Coughlin, E. B., & Bercaw, J. E. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00045a068 · Cited by 155 · see citing works

Bonding Energetics in Organometallic Compounds

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Carbon-carbon bond activation via .beta.-alkyl elimination. Reversible branching of 1,4-pentadienes catalyzed by scandocene hydride derivatives

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Chiral organolanthanide complexes for enantioselective olefin hydrogenation

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Catalytic oligomerization of terminal alkynes by lanthanide carbyls (.eta.5-C5Me5)2LnCH(SiMe3)2 (Ln = Y, La, Ce)

Heeres, H. J., & Teuben, J. H. (1991) · Organometallics · doi:10.1021/om00052a052 · Cited by 149 · see citing works

Organolanthanide and organoyttrium hydride chemistry. 5. Improved synthesis of [(C5H4R)2YH(THF)]2 complexes and their reactivity with alkenes, alkynes, 1,2-propadiene, nitriles, and pyridine, including structural characterization of an alkylideneamido product

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Carbon-hydrogen activation of arenes and substituted arenes by the yttrium hydride (Cp*2YH)2: competition between Cp* ligand metalation, arene metalation, and hydrogen/deuterium exchange. Molecular structures of Cp*2Y(.mu.-H)(.mu.-.eta.1,.eta.5-CH2C5Me4)YCp* and Cp*2Y(o-C6H4PPh2CH2)

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The preparation of anhydrous inorganic chlorides by dehydration with thionyl chloride

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Quantification of Steric Effects in Organometallic Chemistry

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Competitive Chain Transfer by .beta.-Hydrogen and .beta.-Methyl Elimination for a Model Ziegler-Natta Olefin Polymerization System [Me2Si(.eta.5-C5Me4)2]Sc{CH2CH(CH3)2}(PMe3)

Hajela, S., & Bercaw, J. E. (1994) · Organometallics · doi:10.1021/om00016a018 · Cited by 118 · see citing works

Hydrosilylation catalysed by organoneodymium complexes

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Bis(pentamethylcyclopentadienyl) complexes of cerium(III). Crystal structure of (C5Me5)2CeCH(SiMe3)2

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Chemistry of (octaethylporphyrinato)lutetium and -yttrium complexes: synthesis and reactivity of (OEP)MX derivatives and the selective activation of O2 by (OEP)Y(.mu.-Me)2AlMe2

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Organolanthanide-Catalyzed Carbon-Heteroatom Bond Formation. Observations on the Facile, Regiospecific Cyclization of Aminoalkynes

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Benzamidinatokomplexe mit Haupt‐ und Nebengruppen‐Elementen – Strukturen von PhC(NSiMe3)2TiCl2 und PhC(NSiMe3)2MoO2

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Metallorganische verbindungen der lanthanoide

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Diffractometer software (CAD4F)

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Activation of Ethers and Sulfides by Organolanthanide Hydrides. Molecular Structures of (Cp*2Y)2(.mu.-OCH2CH2O)(THF)2 and (Cp*2Ce)2(.mu.-O)(THF)2

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Organolanthanide and organoyttrium hydride chemistry. 9. Bis(1,3-dimethylcyclopentadienyl)yttrium complexes. Synthesis and x-ray crystallographic characterization of [(1,3-Me2C5H3)2Y(.alpha.-Me)]2, [(1,3-Me2C5H3)2Y(.mu.-H)]3, and [(1,3-Me2C5H3)2(THF)Y(.mu.-H)]2

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Phosphine complexes of yttrium, lanthanum, and lutetium. Synthesis, thermolysis, and fluxional behavior of the hydrocarbyl derivatives MR[N(SiMe2CH2PMe2)2]2. X-ray crystal structure of [cyclic] Y[N(SiMe2CHPMe2)(SiMe2CH2PMe2)][N(SiMe2CH2PMe2)2]

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Reactions of Lewis bases with tetrahydroborate derivatives of the Group IVa elements. Preparation of new zirconium hydride species

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Reactivity of permethylscandocene derivatives with acetylene. Structure of acetylenediylbis(permethylscandocene), (.eta.5-C5Me5)2ScC.tplbond.CSc(.eta.5-C5Me5)2

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Reactions of benzonitrile with lithium amides

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Preparation, characterization, and reactivity of scandium octaethylporphyrin complexes. X-ray crystal structures of (OEP)ScCH3, (OEP)ScCH(SiMe3)2, (OEP)Sc(.eta.5-C9H7), and [(OEP)Sc]2(.mu.-OH)2

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Selective hydrogenation of substituted dienes catalyzed by an organoyttrium complex

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Neodym(III)komplexe mit stark raumerfüllenden Cyclopentadienyl- und Benzamidinat-Liganden: Ein Vergleich

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A new ligand environment in organolanthanoid chemistry: sterically hindered, chelating diolato ligands and the X-ray structure of [La{CH(SiMe 3 ) 2 }{1,1′-(2-OC 6 H 2 Bu t 2 -3,5) 2 }(thf) 3 ](thf = tetrahydrofuran)

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Unsolvated lanthanidocene hydrides and borohydrides. X-Ray crystal structure of [(η5-C5H3tBu2)2Ln(μ-H)]2 (Ln = Ce, Sm)

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Organolanthanide and organoyttrium hydride chemistry. 10. Reactivity of trimetallic organoyttrium hydride complexes. Synthesis of the alkoxy hydride anions [[(C5H5)2Y(.mu.-H)]x[(C5H5)2Y(.mu.-OCH3)]3-x(.mu.3-H)]- (x = 0-2), including the x-ray crystal structure of [[(C5H5)2Y(.mu.-OCH3)]3(.mu.3-H)]2[Li(THF)3]2

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Die Kristallstruktur von N,N,N'-tris(trimethylsilyl)benzamidin sowie die Synthese und Kristallstruktur von DichIorantimon-N,N'-bis(trimethylsilyl)benzamidinat

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Intramolecular C-X activation as a synthetic route to bidentate cyclopentadienyl-alkoxide ligands: preparation and molecular structure of [3-(2,3,4,5-tetramethylcyclopentadienyl)propoxy]titanium dichloride

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Preparation of the bis(trimethylsilyl)amido lanthanide chlorides [{Ln[N(SiMe 3 ) 2 ] 2 (µ-Cl)(thf)} 2 ](thf = tetrahydrofuran), and the crystal and molecular structures of the gadolinium and ytterbium complexes

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Synthesis of permethylyttrocene alkyl complexes

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Metallorganische verbindungen der lanthanoide

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N,N'-Bis(trimethylsilyl)benzamidinato-Koniplexe von Titan und Zirkon. Die Kristallstrukturen von [C6H5-C(NSiMe3)2MCl3]2; M = Ti, Zr / N,N'-Bis(trimethylsilyl)benzamidinato Complexes of Titanium and Zirconium. The Crystal Structures of [C6H5-C(NSiMe3)2MCl3 ]2 ; M = Ti, Zr

Fenske, D. (1988) · Zeitschrift für Naturforschung B · doi:10.1515/znb-1988-1213 · Cited by 42 · see citing works

Monocyclopentadienyl yttrium chemistry: incorporation of alkoxides as supporting ligands and synthesis of [Y(C 5 Me 5 )(OC 6 H 3 Bu t 2 )(µ-H)] 2

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Synthesis of new bis(cyclopentadienyl)yttrium complexes with ether functionalized cyclopentadienyl ligands. Crystal structure of [(C5H4CH2CH2OMe)2Y(μ-H)2BH2]

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Phosphine complexes of yttrium(III). Synthesis, reactivity and fluxional behavior of YCl[N(SiMe2CH2PMe2)2]2

Fryzuk, M. D., & Haddad, T. S. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00232a064 · Cited by 39 · see citing works

Ag 2 [Ph – C(NSiMe 3 ) 2 ] 2 und Au 2 [Ph – C(NSiMe 3 ) 2 ] 2 : Amidinatokomplexe mit kurzen Metall–Metall-Abständen / Ag 2 [Ph—C(NSiMe 3 ) 2 ] 2 and Au 2 [Ph—C(NSiMe 3 ) 2 ] 2 : Amidinato Complexes with Short Metal—Metal Distances

Fenske, D., Baum, G., Zinn, A. A., et al. (1990) · Zeitschrift für Naturforschung B · doi:10.1515/znb-1990-0909 · Cited by 38 · see citing works

Synthesis and crystal structure of a lanthanum complex with a diphenylphosphide ligand

Aspinall, H. C., Moore, S. R., & Smith, A. K. (1992) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/dt9920000153 · Cited by 35 · see citing works

N,N,N′-tris(trimethylsilyl)organoamidine als regeantien in der komplexchemie

Dehnicke, K., Ergezinger, C., Hartmann, E., et al. (1988) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(88)83041-9 · Cited by 34 · see citing works

Cu2[Ph-C(NSiMe3)*]2, ein Amidinatokomplex mit kurzem Cu ··· Cu-Abstand / Cu2[Ph —C(NSiMe3)2]2, an Amidinato Complex with a Short Cu - Cu Distance

Maier, S., Hiller, W., & Strähle, J. (1988) · Zeitschrift für Naturforschung B · doi:10.1515/znb-1988-1216 · Cited by 29 · see citing works

Benzophenone complexes of the lanthanides: Synthesis of [Ln{N(SiMe3)2}3(Ph2CO)] (L = La, Eu, Tb, Yb or Y) and X-ray crystal structure of the terbium complex

Allen, M. B., Aspinall, H. C., Moore, S. R., et al. (1992) · Polyhedron · doi:10.1016/s0277-5387(00)83194-0 · Cited by 27 · see citing works

Synthese und Kristallstruktur von Quecksilber(II)‐N,N′‐bis(trimethylsilyl)benzamidinat, Hg[PhC(NSiMe3)2]2

Zinn, A. A., Denicke, K., Fenske, D., et al. (1991) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.19915960107 · Cited by 23 · see citing works

Studies on organolanthanide complexes. XI. Preparation of dimeric dicyclopentadienyllutetium hydride by reduction of dicyclopentadienyl lutetium chloride with sodium hydride; its X-ray crystal structure and reactivity

Changtao, Q., Daoli, D., Chaozhou, N., et al. (1988) · Inorganica Chimica Acta · doi:10.1016/s0020-1693(00)80039-0 · Cited by 21 · see citing works

Cooling apparatus for a single-crystal X-ray diffractometer

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{Mo2(O2CPh)2[PhC(NSiMe3)2]2}, ein Benzoato‐Amidinato‐Komplex von Molybdän(II)

Zinn, A. A., Weller, F., & Dehnicke, K. (1991) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.19915940112 · Cited by 11 · see citing works

Calculation of 2J(HH) and 1J(CH) for transition metal methyl compounds; evidence for geometric dependence of 2J(HH)

Green, J. C., & Payne, M. P. (1987) · Magnetic Resonance in Chemistry · doi:10.1002/mrc.1260250618 · Cited by 10 · see citing works

Installing a Trigger to Upcycle High-Density Polyethylene

Nan, T., Chen, Q., Zheng, Z., Liang, Y., Qin, Y., Wang, Y., Liu, B., & Cui, D. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c08958 · Cited by 42 · see citing works

Investigation on Hydrogenolysis of Hexabenzylhexaazaisowurtzitane

Chen, B.-R. (2006) · Journal of Beijing Institute of Technology

Hydrogenolysis of Triacetyltribenzylhexaazaisowurtzitane and Tetraacetyldibenzylhexaazaisowurtzitane

Yan-lei, G. (2008) · Chinese Journal of Energetic Materials · Cited by 2 · see citing works

Influence of preparation methods of Cu/Cr catalyst for hydrogenolysis of glycerol

Lanying, O. (2010) · Huagong jinzhan

Heterogeneous catalytic hydrogenolysis of organic compounds

Török, B., Schäfer, C., & Kokel, A. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-817825-6.00006-9

Hydrogenation and Hydrogenolysis. XII. The Hydrogenation of Isomeric Dimethoxybenzenes with Platinum Metal Catalysts

Takagi, Y., Ishii, S., & Nishimura, S. (1970) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.43.917 · Cited by 12 · see citing works