Cited by 457Chemical Reaction MechanismsInorganic and Organometallic ChemistryMetal complexes synthesis and properties

Nucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)

Pearson, Ralph G., Sobel, Harold R., Songstad, Jon·1968·Journal of the American Chemical Society

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)Ralph G. Pearson, Harold R. Sobel, and Jon SongstadCite this: J. Am. Chem. Soc. 1968, 90, 2, 319–326Publication Date (Print):January 1, 1968Publication History Published online1 May 2002Published inissue 1 January 1968https://pubs.acs.org/doi/10.1021/ja01004a021https://doi.org/10.1021/ja01004a021research-articleACS PublicationsRequest reuse permissionsArticle Views2288Altmetric-Citations403LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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  • Nitrite is a weak nucleophile and, in aqueous conditions at biological pH, will not easily react with electrophiles.

    “Nitrite is a weak nucleophile [40], and in aqueous conditions and at biological pH, it will not easily react with electrophiles, also because of the solvation effects of water molecules.”

    From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [40]

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Authors
Pearson, R. G., Sobel, H. R., & Songstad, J.
Venue
Journal of the American Chemical Society
Published
1968-01
Volume
90
Issue
2
Pages
319-326
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2036857388
Cited by
455
References
0
Citations by year
2026: 2 · 2025: 7 · 2024: 3 · 2023: 8 · 2022: 7 · 2021: 7 · 2020: 1 · 2019: 7 · 2018: 7 · 2017: 5 · 2016: 5 · 2015: 8 · 2014: 19 · 2013: 10 · 2012: 13
FWCI
8.21
Type
journal article
Language
en
Open access
closed
Locations
Journal of the American Chemical Society (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
  • Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
  • Health Sciences › Medicine › Oncology › Metal complexes synthesis and properties
Keywords
methyl iodide, nucleophilicity, nucleophilic substitution, platinum(II) complexes, pyridine ligands

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