The DOI matches its Crossref record.
Self-Terminating, Oxidative Radical Cyclizations: A Novel Reaction of Acyloxyl Radicals
Abstract
Acyloxyl radicals RC(O)O* (with R = alkyl, aryl) could be trapped through addition to cyclic and open-chain alkynes, where they were found to act as a donor of oxygen atoms. Mechanistically, this radical oxygenation proceeded through a transannular or intramolecular, respectively, radical cyclization cascade, which was finally terminated by release of an acyl radical RC*(O). The reaction led to stereoselective formation of cyclized products, which contained a carbonyl group at the former site of the alkyne triple bond.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis
Nicolaou, K. C., Bulger, P. G., & Sarlah, D. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500368 · Cited by 2,708
Shape Control of Colloidal Metal Nanocrystals
Tao, A. R., Habas, S., & Yang, P. (2008) · Small · doi:10.1002/smll.200701295 · Cited by 2,408
Chemically Functionalized Carbon Nanotubes
Balasubramanian, K., & Burghard, M. (2005) · Small · doi:10.1002/smll.200400118 · Cited by 1,769
Shape‐Controlled Synthesis of Metal Nanostructures: The Case of Silver
Wiley, B., Sun, Y., Mayers, B., & Xia, Y. (2005) · Chemistry – A European Journal · doi:10.1002/chem.200400927 · Cited by 1,643
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154
Metadata
- Authors
- Wille, U.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-12-08
- Volume
- 124
- Issue
- 1
- Pages
- 14-15
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1969449710
- Cited by
- 183
- References
- 0
- FWCI
- 15.51
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Self-Terminating, Oxidative Radical Cyclizations: A Novel Reaction of Acyloxyl Radicals. https://app.cochat.ai/papers/10.1021/ja017006o
- The paper
- Wille, U. (2002). Self-Terminating, Oxidative Radical Cyclizations: A Novel Reaction of Acyloxyl Radicals. Journal of the American Chemical Society. https://doi.org/10.1021/ja017006o
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
