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Cited by 521

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Permanent Microporosity and Enantioselective Sorption in a Chiral Open Framework

Bradshaw, Darren, Prior, Timothy J., Cussen, Edmund J., Claridge, John B., Rosseinsky, Matthew J.·2004·Journal of the American Chemical Society

Abstract

A homochiral microporous material is presented. The phase has 47% permanently porous void volume and is shown to have >1 nm diameter pores with three-dimensional channels using probe molecule sorption. Enantioselective guest sorption is strongly dependent on guest size. The homochiral microporous phase was identified by reactive selection from a first-generation chiral but nonporous framework. Chiral permanent porosity is established by directional noncovalent interactions between framework-forming and nonframework forming components of the stable second-generation material, which become stronger upon loss of the guests from the pore system.

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Crossref · 10.1021/ja0316420

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Metadata

Authors
Bradshaw, D., Prior, T. J., Cussen, E. J., Claridge, J. B., & Rosseinsky, M. J.
Venue
Journal of the American Chemical Society
Published
2004-04-27
Volume
126
Issue
19
Pages
6106-6114
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2086560746
Cited by
521
References
1
FWCI
26.48
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.