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Permanent Microporosity and Enantioselective Sorption in a Chiral Open Framework
Abstract
A homochiral microporous material is presented. The phase has 47% permanently porous void volume and is shown to have >1 nm diameter pores with three-dimensional channels using probe molecule sorption. Enantioselective guest sorption is strongly dependent on guest size. The homochiral microporous phase was identified by reactive selection from a first-generation chiral but nonporous framework. Chiral permanent porosity is established by directional noncovalent interactions between framework-forming and nonframework forming components of the stable second-generation material, which become stronger upon loss of the guests from the pore system.
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Metadata
- Authors
- Bradshaw, D., Prior, T. J., Cussen, E. J., Claridge, J. B., & Rosseinsky, M. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-04-27
- Volume
- 126
- Issue
- 19
- Pages
- 6106-6114
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2086560746
- Cited by
- 521
- References
- 9
- FWCI
- 26.48
- Type
- journal article
- Language
- en
- Open access
- closed
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