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New Polyamide Cryptand for Anion Binding
Abstract
An anion receptor derived from a tren-based amide cryptand with pyridine spacers has been synthesized and characterized. Two crystal structures are reported: the hydrochloride salt and the fluoride complex. The cryptand shows extremely high binding with fluoride ion in DMSO-d6. Both the crystal structure and solution 19F NMR data indicate an encapsulated fluoride ion with very high symmetry.
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Citations
Cited by
Recognition and sensing of fluoride anion
Cametti, M., & Rissanen, K. (2009) · Chemical Communications · doi:10.1039/b902069a · Cited by 654
Artificial Receptors for the Recognition of Phosphorylated Molecules
Hargrove, A. E., Nieto, S., Zhang, T., Sessler, J. L., & Anslyn, E. V. (2011) · Chemical Reviews · doi:10.1021/cr100242s · Cited by 649
Fluoride Ion Sensing by an Anion−π Interaction
Guha, S., & Saha, S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja107382x · Cited by 507
Anion coordination and anion-templated assembly: Highlights from 2002 to 2004
Gale, P. A., & Quesada, R. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.05.020 · Cited by 406
Metadata
- Authors
- Kang, S. O., Llinares, J. M., Powell, D., VanderVelde, D., & Bowman-James, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-30
- Volume
- 125
- Issue
- 34
- Pages
- 10152-10153
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1988498954
- Cited by
- 215
- References
- 0
- FWCI
- 7.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kang, S. O., Llinares, J. M., Powell, D., VanderVelde, D., & Bowman-James, K. (2003). New Polyamide Cryptand for Anion Binding. Journal of the American Chemical Society. https://doi.org/10.1021/ja034969%2B
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