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Narrow ( n , m )-Distribution of Single-Walled Carbon Nanotubes Grown Using a Solid Supported Catalyst
Open accessAbstract
Unusually structure-selective growth of single-walled carbon nanotubes (SWNTs) has been attained using a CVD method with a solid supported catalyst. In this method, CO feedstock disproportionates on silica-supported catalytic nanoclusters of Co that are formed in situ from mixed salts of Co and Mo. The nanotube products are analyzed by spectrofluorimetry to reveal distributions resolved at the level of individual (n,m) structures. Two structures, (6,5) and (7,5), together dominate the semiconducting nanotube distribution and comprise more than one-half of that population. The average diameter of produced SWNTs is only 0.81 nm, and a strong propensity is found favoring chiral angles near the armchair limit.
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Cited by
Rao, R., Pint, C. L., Islam, A. E., Weatherup, R. S., Hofmann, S., Meshot, E. R., Wu, F., Zhou, C., Dee, N., Amama, P. B., et al. (2018) · ACS Nano · doi:10.1021/acsnano.8b06511 · Cited by 588
Multimodal optical sensing and analyte specificity using single-walled carbon nanotubes
Heller, D. A., Jin, H., Martinez, B. M., Patel, D., Miller, B. M., Yeung, T.-K., Jena, P. V., Höbartner, C., Ha, T., Silverman, S. K., et al. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2008.369 · Cited by 319
Gilbertson, L. M., Zimmerman, J. B., Plata, D. L., Hutchison, J. E., & Anastas, P. T. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00445k · Cited by 275
Second Near‐Infrared Window Fluorescence Materials for In Vivo Dynamic Multiplexed Imaging
Fan, F., Zeng, K., Zhu, Y., Zhang, Y., Chen, Y., Lv, D., Jia, D., Chai, Y., Chen, X., & Li, Q. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202422693 · Cited by 33
Metadata
- Authors
- Bachilo, S. M., Balzano, L., Herrera, J. E., Pompeo, F., Resasco, D. E., & Weisman, R. B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-08-21
- Volume
- 125
- Issue
- 37
- Pages
- 11186-11187
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2151058832
- Cited by
- 864
- References
- 0
- FWCI
- 19.71
- Type
- journal article
- Language
- en
- Open access
- green
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- Bachilo, S. M., Balzano, L., Herrera, J. E., Pompeo, F., Resasco, D. E., & Weisman, R. B. (2003). Narrow ( n , m )-Distribution of Single-Walled Carbon Nanotubes Grown Using a Solid Supported Catalyst. Journal of the American Chemical Society. https://doi.org/10.1021/ja036622c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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