The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Evidence for Hydrogen Abstraction from C1 of Taurine by the High-Spin Fe(IV) Intermediate Detected during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase (TauD)
Abstract
The Fe(II)- and alpha-ketoglutarate-dependent dioxygenases catalyze hydroxylation reactions of considerable biomedical and environmental significance. Recently, the first oxidized iron intermediate in the reaction of a member of this family, taurine:alpha-ketoglutarate dioxygenase (TauD), was detected and shown to be a high-spin, formally Fe(IV) complex. The demonstration in this study that decay of the Fe(IV) complex is approximately 30-fold slower when it is formed in the presence of 1-[2H]2-taurine provides evidence that the intermediate abstracts hydrogen from C1, the site of hydroxylation, and suggests that quantum-mechanical tunneling may contribute to C1-H cleavage.
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Cites
Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
Solomon, E. I., Brunold, T. C., Davis, M. I., Kemsley, J. N., Lee, S.-K., Lehnert, N., Neese, F., Skulan, A. J., Yang, Y.-S., & Zhou, J. (2000) · Chemical Reviews · doi:10.1021/cr9900275 · Cited by 1,713
Price, J. C., Barr, E. W., Tirupati, B., Bollinger, & Krebs, C. (2003) · Biochemistry · doi:10.1021/bi030011f · Cited by 737
Self-citation
Cited by
Fe(II)/α-Ketoglutarate-Dependent Hydroxylases and Related Enzymes
Hausinger, R. P. (2004) · Critical Reviews in Biochemistry and Molecular Biology · doi:10.1080/10409230490440541 · Cited by 937
Reactivity of High-Valent Iron–Oxo Species in Enzymes and Synthetic Reagents: A Tale of Many States
Shaik, S., Hirao, H., & Kumar, D. (2007) · Accounts of Chemical Research · doi:10.1021/ar600042c · Cited by 555
2-Oxoglutarate-Dependent Oxygenases
Islam, M. S., Leissing, T. M., Chowdhury, R., Hopkinson, R. J., & Schofield, C. J. (2018) · Annual Review of Biochemistry · doi:10.1146/annurev-biochem-061516-044724 · Cited by 472
Guo, M., Corona, T., Ray, K., & Nam, W. (2019) · ACS Central Science · doi:10.1021/acscentsci.8b00698 · Cited by 401
4-Hydroxyphenylpyruvate dioxygenase
Moran, G. R. (2005) · Archives of Biochemistry and Biophysics · doi:10.1016/j.abb.2004.08.015 · Cited by 306
Metadata
- Authors
- Price, J. C., Barr, E. W., Glass, T. E., Krebs, C., & Bollinger, J. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-10-01
- Volume
- 125
- Issue
- 43
- Pages
- 13008-13009
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2069690105
- Cited by
- 403
- References
- 2
- FWCI
- 10.81
- Type
- journal article
- Language
- en
- Open access
- closed
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