The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Catalytic Signal Amplification Using a Heck Reaction. An Example in the Fluorescence Sensing of Cu(II)
Abstract
Catalytic signal enhancement using an organometallic reaction is demonstrated. The reactivity of a Heck cross-coupling reaction that creates a fluorophore is modulated by the addition of a polyazacyclam inhibitor. The inhibitor will complex with Cu(II), which restores the activity of the Pd(II). The addition of Cu(II) therefore leads to the generation of fluorescence, thereby creating a very sensitive assay for Cu(II). The rate of the Heck reaction is followed by monitoring emission as a function of time. The rate is proportional to the Cu(II) concentration and correlates to the affinity of the inhibitor to various metals. This strategy represents a general technique that can be exploited with other catalytic organometallic reactions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Shibata, T., Yamamoto, J., Matsumoto, N., Yonekubo, S., Osanai, S., & Soai, K. (1998) · Journal of the American Chemical Society · doi:10.1021/ja980815w · Cited by 204
Cited by
Zhao, Y., Zhang, X.-B., Han, Z.-X., Qiao, L., Li, C.-Y., Jian, L.-X., Shen, G.-L., & Yu, R.-Q. (2009) · Analytical Chemistry · doi:10.1021/ac901127n · Cited by 455
Signal Amplification by Allosteric Catalysis
Zhu, L., & Anslyn, E. V. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200501476 · Cited by 151
Self-citation
Metadata
- Authors
- Wu, Q., & Anslyn, E. V.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-10-26
- Volume
- 126
- Issue
- 45
- Pages
- 14682-14683
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2078154796
- Cited by
- 253
- References
- 1
- FWCI
- 5.51
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
