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Cited by 706

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PbTe Colloidal Nanocrystals: Synthesis, Characterization, and Multiple Exciton Generation

Murphy, James E., Beard, Matthew C., Norman, Andrew G., Ahrenkiel, S. Phillip, Johnson, Justin C., Yu, Pingrong, Mićić, Olga I., Ellingson, Randy J., Nozik, Arthur J.·2006·Journal of the American Chemical Society

Abstract

We report an alternative synthesis and the first optical characterization of colloidal PbTe nanocrystals (NCs). We have synthesized spherical PbTe NCs having a size distribution as low as 7%, ranging in diameter from 2.6 to 8.3 nm, with first exciton transitions tuned from 1009 to 2054 nm. The syntheses of colloidal cubic-like PbSe and PbTe NCs using a PbO "one-pot" approach are also reported. The photoluminescence quantum yield of PbTe spherical NCs was measured to be as high as 52 +/- 2%. We also report the first known observation of efficient multiple exciton generation (MEG) from single photons absorbed in PbTe NCs. Finally, we report calculated longitudinal and transverse Bohr radii for PbS, PbSe, and PbTe NCs to account for electronic band anisotropy. This is followed by a comparison of the differences in the electronic band structure and optical properties of these lead salts.

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Metadata

Authors
Murphy, J. E., Beard, M. C., Norman, A. G., Ahrenkiel, S. P., Johnson, J. C., Yu, P., Mićić, O. I., Ellingson, R. J., & Nozik, A. J.
Venue
Journal of the American Chemical Society
Published
2006-02-16
Volume
128
Issue
10
Pages
3241-3247
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1982102759
Cited by
706
References
22
FWCI
25.39
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: PbTe Colloidal Nanocrystals: Synthesis, Characterization, and Multiple Exciton Generation. https://app.cochat.ai/papers/10.1021/ja0574973
The paper
Murphy, J. E., Beard, M. C., Norman, A. G., Ahrenkiel, S. P., Johnson, J. C., Yu, P., Mićić, O. I., Ellingson, R. J., & Nozik, A. J. (2006). PbTe Colloidal Nanocrystals: Synthesis, Characterization, and Multiple Exciton Generation. Journal of the American Chemical Society. https://doi.org/10.1021/ja0574973

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.