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Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability
Abstract
A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 A. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Self-citationHydrogen storage in metal–organic frameworks
Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532
Industrial applications of metal–organic frameworks
Czaja, A. U., Trukhan, N., & Müller, U. (2009) · Chemical Society Reviews · doi:10.1039/b804680h · Cited by 2,341
Lan, A., Li, K., Wu, H., Olson, D. H., Emge, T. J., Ki, W., Hong, M., & Li, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200804853 · Cited by 1,237
Self-citationSynergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework
Jiang, H.-L., Akita, T., Ishida, T., Haruta, M., & Xu, Q. (2011) · Journal of the American Chemical Society · doi:10.1021/ja1099006 · Cited by 931
Metadata
- Authors
- Pan, L., Parker, B., Huang, X., Olson, D. H., Lee, & Li, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-03-14
- Volume
- 128
- Issue
- 13
- Pages
- 4180-4181
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2001354180
- Cited by
- 430
- References
- 0
- FWCI
- 33.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability. https://app.cochat.ai/papers/10.1021/ja057667b
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- Pan, L., Parker, B., Huang, X., Olson, D. H., Lee, & Li, J. (2006). Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability. Journal of the American Chemical Society. https://doi.org/10.1021/ja057667b
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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