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Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability
Abstract
A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized. It contains one-dimensional close-packed open channels with a pore diameter of 4.5 A. It demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density (0.054 g/cm3 at 77 K and 1 atm).
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Metadata
- Authors
- Pan, L., Parker, B., Huang, X., Olson, D. H., Lee, & Li, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-03-14
- Volume
- 128
- Issue
- 13
- Pages
- 4180-4181
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2001354180
- Cited by
- 430
- References
- 0
- FWCI
- 33.09
- Type
- journal article
- Language
- en
- Open access
- closed
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