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Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol
Abstract
We report a particle size dependence for the rate of hydrogenation of allyl alcohol using 1.3-1.9 nm Pd dendrimer-encapsulated nanoparticle (DEN) catalysts. For particles with diameters of <1.5 nm and containing <147 Pd atoms, the modulation in catalytic activity is due to the electronic properties of the particle. For the larger particles, 1.5-1.9 nm in diameter and containing an average of 147-250 Pd atoms, the size effect is a result of geometrical constraints. Specifically, the hydrogenation reaction is shown to occur preferentially on the face atoms of the larger nanoparticles.
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Cited by
Ruan, X., Sun, Y., Du, W., Tang, Y., Liu, Q., Zhang, Z., Doherty, W., Frost, R. L., Qian, G., & Tsang, D. C. W. (2019) · Bioresource Technology · doi:10.1016/j.biortech.2019.02.105 · Cited by 402
Semagina, N., & Kiwi‐Minsker, L. (2009) · Catalysis Reviews · doi:10.1080/01614940802480379 · Cited by 181
Facile Aqueous‐Phase Synthesis of Uniform Palladium Nanoparticles of Various Shapes and Sizes
Piao, Y., Jang, Y., Shokouhimehr, M., Lee, I. S., & Hyeon, T. (2007) · Small · doi:10.1002/smll.200600402 · Cited by 173
Metadata
- Authors
- Wilson, O. M., Knecht, M. R., Garcia-Martinez, J. C., & Crooks, R. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-03-17
- Volume
- 128
- Issue
- 14
- Pages
- 4510-4511
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2017462146
- Cited by
- 372
- References
- 0
- FWCI
- 14.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol. https://app.cochat.ai/papers/10.1021/ja058217m
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- Wilson, O. M., Knecht, M. R., Garcia-Martinez, J. C., & Crooks, R. M. (2006). Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol. Journal of the American Chemical Society. https://doi.org/10.1021/ja058217m
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