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Rapid Production of Metal−Organic Frameworks via Microwave-Assisted Solvothermal Synthesis
Abstract
This paper describes a very rapid technique for the production of metal-organic frameworks (MOF). The method uses a conventional microwave to nucleate crystal growth. A MOF synthesis that used to take hours or days can now be completed in 30 s to 2 min. The yield goes from approximately 30% to over 90%. Novel MOFs can be made, since the growth process is no longer dependent on the walls or dust particles for nucleation. Particle sizes have a narrower distribution. Further, the particle size can be controlled by varying the precursor concentration.
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Wang, S., McGuirk, C. M., d'Aquino, A., Mason, J. A., & Mirkin, C. A. (2018) · Advanced Materials · doi:10.1002/adma.201800202 · Cited by 833
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Ke, F., Yuan, Y.-P., Qiu, L.-G., Shen, Y.-H., Xie, A.-J., Zhu, J.-F., Tian, X.-Y., & Zhang, L.-D. (2011) · Journal of Materials Chemistry · doi:10.1039/c0jm01770a · Cited by 403
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Large language models for reticular chemistry
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Metadata
- Authors
- Ni, Z., & Masel, R. I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-09-01
- Volume
- 128
- Issue
- 38
- Pages
- 12394-12395
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2045908830
- Cited by
- 778
- References
- 0
- FWCI
- 13.47
- Type
- journal article
- Language
- en
- Open access
- closed
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