The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal−Organic Framework
Abstract
Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at <100 mbar) times the H2 values depending on the pressure, agreeing with the theoretical expectations. Gravimetric adsorption measurements of NO on HKUST-1 at 196 K (1 bar) gives a large adsorption capacity of approximately 9 mmol g(-1), which is significantly greater than any other adsorption capacity reported on a porous solid. At 298 K the adsorption capacity at 1 bar is just over 3 mmol g(-1). Infra red experiments show that the NO binds to the empty copper metal sites in HKUST-1. Chemiluminescence and platelet aggregometry experiments indicate that the amount of NO recovered on exposure of the resulting complex to water is enough to be biologically active, completely inhibiting platelet aggregation in platelet rich plasma.
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Cites
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NO-Releasing Zeolites and Their Antithrombotic Properties
Wheatley, P. S., Butler, A. R., Crane, M. S., Fox, S., Xiao, B., Rossi, A. G., Megson, I. L., & Morris, R. E. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0503579 · Cited by 235
Self-citationZhang, H., Annich, G. M., Miskulin, J., Stankiewicz, K., Osterholzer, K., Merz, S. I., Bartlett, R. H., & Meyerhoff, M. E. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0291538 · Cited by 176
Cited by
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Self-citationDevelopment and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture
Bae, Y., & Snurr, R. Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101891 · Cited by 1,208
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MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
LLABRESIXAMENA, F., ABAD, A., CORMA, A., & GARCIA, H. (2007) · Journal of Catalysis · doi:10.1016/j.jcat.2007.06.004 · Cited by 549
Nitric oxide release: Part I. Macromolecular scaffolds
Riccio, D. A., & Schoenfisch, M. H. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15272j · Cited by 475
Metadata
- Authors
- Xiao, B., Wheatley, P. S., Zhao, X., Fletcher, A. J., Fox, S., Rossi, A. G., Megson, I. L., Bordiga, S., Regli, L., Thomas, K. M., & Morris, R. E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-01-06
- Volume
- 129
- Issue
- 5
- Pages
- 1203-1209
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2086593157
- Cited by
- 612
- References
- 6
- FWCI
- 28.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiao, B., Wheatley, P. S., Zhao, X., Fletcher, A. J., Fox, S., Rossi, A. G., Megson, I. L., Bordiga, S., Regli, L., Thomas, K. M., & Morris, R. E. (2007). High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal−Organic Framework. Journal of the American Chemical Society. https://doi.org/10.1021/ja066098k
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