The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Controlled Electrochemical Synthesis of Conductive Polymer Nanotube Structures
Abstract
We have investigated the electrochemical synthetic mechanism of conductive polymer nanotubes in a porous alumina template using poly(3,4-ethylenedioxythiophene) (PEDOT) as a model compound. As a function of monomer concentration and potential, electropolymerization leads either to solid nanowires or to hollow nanotubes, and it is the purpose of these investigations to uncover the detailed mechanism underlying this morphological transition between nanowire and nanotube. Transmission electron microscopy was used to characterize electrochemically synthesized PEDOT nanostructures and measure the extent of their nanotubular portion quantitatively. The study on potential dependency of nanotubular portion shows that nanotubes are grown at a low oxidation potential (1.2 V vs Ag/AgCl) regardless of monomer concentration. This phenomenon is attributed to the predominance of electrochemically active sites on the annular-shape electrode at the pore bottom of a template. The explanation was supported by a further electrochemical study on a flat-top electrode. We elaborate the mechanism by taking into account the effect of electrolyte concentration, temperature, and template pore diameter on PEDOT nanostructures. This mechanism is further employed to control the nanotube dimensions of other conductive polymers such as polypyrrole and poly(3-hexylthiophene).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electrochemical Methods: Fundamentals and Applications
Bard, A. J., & Faulkner, L. R. (1980) · Cited by 22,435
Nanomaterials: A Membrane-Based Synthetic Approach
Martin, C. R. (1994) · Science · doi:10.1126/science.266.5193.1961 · Cited by 4,060
High-Resolution Inkjet Printing of All-Polymer Transistor Circuits
Sirringhaus, H., Kawase, T., Friend, R. H., Shimoda, T., Inbasekaran, M., Wu, W., & Woo, E. P. (2000) · Science · doi:10.1126/science.290.5499.2123 · Cited by 3,311
Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
Thurn-Albrecht, T., Schotter, J., Kästle, G. A., Emley, N., Shibauchi, T., Krusin-Elbaum, L., Guarini, K., Black, C. T., Tuominen, M. T., & Russell, T. P. (2000) · Science · doi:10.1126/science.290.5499.2126 · Cited by 2,104
Single-crystal gallium nitride nanotubes
Goldberger, J., He, R., Zhang, Y., Lee, S., Yan, H., Choi, H.-J., & Yang, P. (2003) · Nature · doi:10.1038/nature01551 · Cited by 1,247
Self-citationGate Dielectrics for Organic Field‐Effect Transistors: New Opportunities for Organic Electronics
Facchetti, A., Yoon, M. ‐., & Marks, T. J. (2005) · Advanced Materials · doi:10.1002/adma.200500517 · Cited by 1,032
Electrochemistry of Poly(3,4‐alkylenedioxythiophene) Derivatives
Groenendaal, L., Zotti, G., Aubert, P. ‐., Waybright, S. M., & Reynolds, J. R. (2003) · Advanced Materials · doi:10.1002/adma.200300376 · Cited by 944
Template Synthesis of Electronically Conductive Polymer Nanostructures
Martin, C. R. (1995) · Accounts of Chemical Research · doi:10.1021/ar00050a002 · Cited by 924
Conducting‐Polymer Nanotubes for Controlled Drug Release
Abidian, M. R., Kim, D. ‐., & Martin, D. C. (2006) · Advanced Materials · doi:10.1002/adma.200501726 · Cited by 869
Superhydrophobic Aligned Polystyrene Nanotube Films with High Adhesive Force
Jin, M., Feng, X., Feng, L., Sun, T., Zhai, J., Li, T., & Jiang, L. (2005) · Advanced Materials · doi:10.1002/adma.200401726 · Cited by 719
Active Matrix Displays Based on All-Organic Electrochemical Smart Pixels Printed on Paper
Andersson, P., Nilsson, D., Svensson, P.-O., Chen, M., Malmström, A., Remonen, T., Kugler, T., & Berggren, M. (2002) · Advanced Materials · doi:10.1002/1521-4095(20021016)14:20<1460::aid-adma1460>3.0.co;2-s · Cited by 394
Template synthesis of metal microtubules
Brumlik, C. J., & Martin, C. R. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00008a057 · Cited by 251
Reconstitution of Transcription Factor SL1: Exclusive Binding of TBP by SL1 or TFIID Subunits
Comai, L., Zomerdijk, J. C. B. M., Beckmann, H., Zhou, S., Admon, A., & Tjian, R. (1994) · Science · doi:10.1126/science.7801123 · Cited by 247
Template-Grown Metal Nanowires
Kline, T. R., Tian, M., Wang, J., Sen, A., Chan, M. W. H., & Mallouk, T. E. (2006) · Inorganic Chemistry · doi:10.1021/ic0601384 · Cited by 201
Kiely, C. J., Fink, J., Zheng, J. G., Brust, M., Bethell, D., & Schiffrin, D. J. (2000) · Advanced Materials · doi:10.1002/(sici)1521-4095(200005)12:9<640::aid-adma640>3.0.co;2-j · Cited by 172
Template Fabrication of Protein-Functionalized Gold−Polypyrrole−Gold Segmented Nanowires
Hernández, R. M., Richter, L. J., Semancik, S., Stranick, S. J., & Mallouk, T. E. (2004) · Chemistry of Materials · doi:10.1021/cm0496265 · Cited by 112
High‐Strength Apatitic Cement by Modification with α‐Hydroxy Acid Salts
Barralet, J. E., Hofmann, M., Grover, L. M., & Gbureck, U. (2003) · Advanced Materials · doi:10.1002/adma.200305469 · Cited by 98
Frazier, S. E., Bedford, J. A., Hower, J., & Kenney, M. E. (1967) · Inorganic Chemistry · doi:10.1021/ic50055a018 · Cited by 34
Cited by
Design and Preparation of Porous Polymers
Wu, D., Xu, F., Sun, B., Fu, R., He, H., & Matyjaszewski, K. (2012) · Chemical Reviews · doi:10.1021/cr200440z · Cited by 1,748
Electrochemistry of Conducting Polymers—Persistent Models and New Concepts
Heinze, J., Frontana-Uribe, B. A., & Ludwigs, S. (2010) · Chemical Reviews · doi:10.1021/cr900226k · Cited by 1,258
Kim, F. S., Ren, G., & Jenekhe, S. A. (2011) · Chemistry of Materials · doi:10.1021/cm102772x · Cited by 664
High thermal conductivity of chain-oriented amorphous polythiophene
Singh, V., Bougher, T. L., Weathers, A., Cai, Y., Bi, K., Pettes, M. T., McMenamin, S. A., Lv, W., Resler, D. P., Gattuso, T. R., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.44 · Cited by 430
3D nanostructured conductive polymer hydrogels for high-performance electrochemical devices
Zhao, Y., Liu, B., Pan, L., & Yu, G. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40997j · Cited by 396
Metadata
- Authors
- Xiao, R., Cho, S. I., Liu, R., & Lee, S. B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-16
- Volume
- 129
- Issue
- 14
- Pages
- 4483-4489
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1994014103
- Cited by
- 258
- References
- 18
- FWCI
- 22.98
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
