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Silicon Nanowire Array Photoelectrochemical Cells
Abstract
Silicon nanowire arrays were grown by vapor−liquid−solid growth from SiH 4 vapor at 500 °C, and tested as photocathodes in [Ru(bpy) 3 ] 2+ (bpy = 2,2‘-bipyridyl)/acetonitrile solutions. Si nanowires were grown in anodic aluminum oxide membranes by first electroplating 50 μm long Co wires capped with 250 nm gold segments in the pores and then reacting with SiH 4 . The resulting Si nanowires protruded 10−15 μm beyond the top surface of the membrane but were degeneratively doped, most likely by Al from the membrane. Nanowires grown in the same manner on Si(111)/Au substrates could be controllably doped p-type by addition of trimethylboron. These p-Si nanowire arrays gave a photovoltage of 220 mV in [Ru(bpy) 3 ] 2+ solution when illuminated by white light.
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Cites
Growth of nanowire superlattice structures for nanoscale photonics and electronics
Gudiksen, M. S., Lauhon, L. J., Wang, J., Smith, D. C., & Lieber, C. M. (2002) · Nature · doi:10.1038/415617a · Cited by 2,709
Cited by
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors
Youngblood, W. J., Lee, S.-H. A., Maeda, K., & Mallouk, T. E. (2009) · Accounts of Chemical Research · doi:10.1021/ar9002398 · Cited by 1,011
Self-citationSilicon Nanowire Radial p−n Junction Solar Cells
Garnett, E. C., & Yang, P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8032907 · Cited by 907
Baker, D. R., & Kamat, P. V. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200801173 · Cited by 799
Liu, R., & Lee, S. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja7112382 · Cited by 666
Metadata
- Authors
- Goodey, A. P., Eichfeld, S. M., Lew, K.-K., Redwing, J. M., & Mallouk, T. E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-25
- Volume
- 129
- Issue
- 41
- Pages
- 12344-12345
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2076079186
- Cited by
- 226
- References
- 1
- FWCI
- 18.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Goodey, A. P., Eichfeld, S. M., Lew, K.-K., Redwing, J. M., & Mallouk, T. E. (2007). Silicon Nanowire Array Photoelectrochemical Cells. Journal of the American Chemical Society. https://doi.org/10.1021/ja073125d
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