The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Selective Solar-Driven Reduction of CO2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell
Abstract
With rising atmospheric CO2 levels, there has been increasing interest in artificial photosynthetic schemes for converting this greenhouse gas into valuable fuels and small organics. Photoelectrochemical schemes for activating the inert CO2 molecule, however, operate at excessive overpotentials and thus do not convert actual light energy to chemical energy. Here we describe the selective conversion of CO2 to methanol at a p-GaP semiconductor electrode with a homogeneous pyridinium ion catalyst, driving the reaction with light energy to yield faradaic efficiencies near 100% at potentials well below the standard potential.
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Citations
Cites
Electrochemical Synthesis of Methanol from CO 2 in High‐Pressure Electrolyte
Li, J., & Prentice, G. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1838179 · Cited by 42
Cited by
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
De Luna, P., Hahn, C., Higgins, D., Jaffer, S. A., Jaramillo, T. F., & Sargent, E. H. (2019) · Science · doi:10.1126/science.aav3506 · Cited by 3,052
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Self-citationKondratenko, E. V., Mul, G., Baltrusaitis, J., Larrazábal, G. O., & Pérez-Ramírez, J. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41272e · Cited by 1,802
Semiconducting materials for photoelectrochemical energy conversion
Sivula, K., & van de Krol, R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2015.10 · Cited by 1,645
Metadata
- Authors
- Barton, E. E., Rampulla, D. M., & Bocarsly, A. B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-04-26
- Volume
- 130
- Issue
- 20
- Pages
- 6342-6344
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2063129680
- Cited by
- 728
- References
- 1
- FWCI
- 8.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- Barton, E. E., Rampulla, D. M., & Bocarsly, A. B. (2008). Selective Solar-Driven Reduction of CO2 to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell. Journal of the American Chemical Society. https://doi.org/10.1021/ja0776327
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