The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation
Abstract
Intercalation of metal atoms is an established route for tuning the coupling of graphene to a substrate. The extension to reactive species such as oxygen would set the stage for a wide spectrum of interfacial chemistry. Here we demonstrate the controlled modification of a macroscopic graphene-metal interface by oxygen intercalation. The selective oxidation of a ruthenium surface beneath graphene lifts the strong metal-carbon coupling and restores the characteristic Dirac cones of isolated monolayer graphene. Our experiments establish the competition between low-temperature oxygen intercalation and graphene etching at higher temperatures and suggest that small molecules can populate the space between graphene and metals, with the adsorbate-metal interaction being modified significantly by the presence of graphene. These findings open up new avenues for the processing of graphene for device applications and for performing chemical reactions in the confined space between a metal surface and a graphene sheet.
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Citations
Cites
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
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Large-scale pattern growth of graphene films for stretchable transparent electrodes
Kim, K. S., Zhao, Y., Jang, H., Lee, S. Y., Kim, J. M., Kim, K. S., Ahn, J.-H., Kim, P., Choi, J.-Y., & Hong, B. H. (2009) · Nature · doi:10.1038/nature07719 · Cited by 10,452
Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition
Reina, A., Jia, X., Ho, J., Nezich, D., Son, H., Bulovic, V., Dresselhaus, M. S., & Kong, J. (2009) · Nano Letters · doi:10.1021/nl801827v · Cited by 5,881
Ultrafast graphene photodetector
Xia, F., Mueller, T., Lin, Y.-M., Valdes-Garcia, A., & Avouris, P. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.292 · Cited by 3,089
Impermeable Atomic Membranes from Graphene Sheets
Bunch, J. S., Verbridge, S. S., Alden, J. S., van der Zande, A. M., Parpia, J. M., Craighead, H. G., & McEuen, P. L. (2008) · Nano Letters · doi:10.1021/nl801457b · Cited by 2,919
Doping Graphene with Metal Contacts
Giovannetti, G., Khomyakov, P. A., Brocks, G., Karpan, V. M., van den Brink, J., & Kelly, P. J. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.026803 · Cited by 2,605
Electronic spin transport and spin precession in single graphene layers at room temperature
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Epitaxial graphene on ruthenium
Sutter, P. W., Flege, J.-I., & Sutter, E. A. (2008) · Nature Materials · doi:10.1038/nmat2166 · Cited by 2,346
Self-citationOperation of Graphene Transistors at Gigahertz Frequencies
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Cited by
High Efficiency Graphene Solar Cells by Chemical Doping
Miao, X., Tongay, S., Petterson, M. K., Berke, K., Rinzler, A. G., Appleton, B. R., & Hebard, A. F. (2012) · Nano Letters · doi:10.1021/nl204414u · Cited by 935
Surface chemistry and catalysis confined under two-dimensional materials
Fu, Q., & Bao, X. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00424e · Cited by 532
Review of functionalization, structure and properties of graphene/polymer composite fibers
Ji, X., Xu, Y., Zhang, W., Cui, L., & Liu, J. (2016) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2016.04.011 · Cited by 351
Confined catalysis under two-dimensional materials
Li, H., Xiao, J., Fu, Q., & Bao, X. (2017) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1701280114 · Cited by 288
Metadata
- Authors
- Sutter, P., Sadowski, J. T., & Sutter, E. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-05-19
- Volume
- 132
- Issue
- 23
- Pages
- 8175-8179
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1987518463
- Cited by
- 338
- References
- 28
- FWCI
- 10.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sutter, P., Sadowski, J. T., & Sutter, E. A. (2010). Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation. Journal of the American Chemical Society. https://doi.org/10.1021/ja102398n
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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