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Cited by 1,238

The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.

Platinum−Gold Nanoparticles: A Highly Active Bifunctional Electrocatalyst for Rechargeable Lithium−Air Batteries

Open access
Lu, Yi-Chun, Xu, Zhichuan, Gasteiger, Hubert A., Chen, Shuo, Hamad-Schifferli, Kimberly, Shao-Horn, Yang·2010·Journal of the American Chemical Society

Abstract

PtAu nanoparticles (NPs) were shown to strongly enhance the kinetics of the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in rechargeable Li-O(2) cells. Li-O(2) cells with PtAu/C were found to exhibit the highest round-trip efficiency reported to date. During ORR via xLi(+) + O(2) + xe(-) --> Li(x)O(2), the discharge voltage with PtAu/C was considerably higher than that of pure carbon and comparable to that of Au/C. During OER via Li(x)O(2) --> xLi(+) + O(2) + xe(-), the charge voltages with PtAu/C fell in the range from 3.4 to 3.8 V(Li), which is slightly lower than obtained with Pt. It is hypothesized that PtAu NPs exhibit bifunctional catalytic activity, having surface Au and Pt atoms primarily responsible for ORR and OER kinetics in Li-O(2) cells, respectively.

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Crossref · 10.1021/ja1036572

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Metadata

Authors
Lu, Y.-C., Xu, Z., Gasteiger, H. A., Chen, S., Hamad-Schifferli, K., & Shao-Horn, Y.
Venue
Journal of the American Chemical Society
Published
2010-06-07
Volume
132
Issue
35
Pages
12170-12171
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2165573056
Cited by
1,238
References
16
FWCI
68.03
Type
journal article
Language
en
Open access
green

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