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Cited by 164

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Conformationally Flexible Dimeric Salphen Complexes for Bifunctional Catalysis

Vagin, Sergei I., Reichardt, Robert, Klaus, Stephan, Rieger, Bernhard·2010·Journal of the American Chemical Society

Abstract

Appropriate modification of the salphen ligand allows an easy modular design of flexibly linked dimeric salphen species and their complexes, which can act as bifunctional catalysts. A series of chromium salphen systems including monomeric compound and dimers with different spacer lengths were tested for their catalytic performance in β-butyrolactone polymerization and CO(2)/propylene oxide copolymerization toward biodegradable materials. The results clearly show an enhancement in activity upon dimerization, thus underlining the role of bifunctional catalysis in the studied processes and extending the possible strategies for improvement of catalysts in these reactions.

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Metadata

Authors
Vagin, S. I., Reichardt, R., Klaus, S., & Rieger, B.
Venue
Journal of the American Chemical Society
Published
2010-09-23
Volume
132
Issue
41
Pages
14367-14369
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2332260988
Cited by
164
References
3
FWCI
4.88
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Conformationally Flexible Dimeric Salphen Complexes for Bifunctional Catalysis. https://app.cochat.ai/papers/10.1021/ja106484t
The paper
Vagin, S. I., Reichardt, R., Klaus, S., & Rieger, B. (2010). Conformationally Flexible Dimeric Salphen Complexes for Bifunctional Catalysis. Journal of the American Chemical Society. https://doi.org/10.1021/ja106484t

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.